Molecular Dynamics and Phase Behavior of Polystyrene/Poly(vinyl methyl ether) Blend in the Presence of Nanosilica

Qi Chen; Min Zuo; Yi-Hu Song; Qiang Zheng

doi:10.1007/s10118-017-1980-z

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Molecular Dynamics and Phase Behavior of Polystyrene/Poly(vinyl methyl ether) Blend in the Presence of Nanosilica

Papers | Updated：2021-02-18

- Molecular Dynamics and Phase Behavior of Polystyrene/Poly(vinyl methyl ether) Blend in the Presence of Nanosilica
- Chinese Journal of Polymer Science Vol. 35, Issue 12, Pages: 1524-1539(2017)
- Affiliations：
  
  Ministry of Education Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China
- Author bio：
  
  Min Zuo (左敏), E-mail:kezuomin@zju.edu.cn
- Funds：
- DOI：10.1007/s10118-017-1980-z
  CLC：
- Received：20 March 2017，
  
  Revised：2017-04-30，
  
  Accepted：17 May 2017，
  
  Published：05 December 2017
- Accepted：
Scan QR Code
Qi Chen, Min Zuo, Yi-Hu Song, et al. Molecular Dynamics and Phase Behavior of Polystyrene/Poly(vinyl methyl ether) Blend in the Presence of Nanosilica[J]. Chinese Journal of Polymer Science, 2017, 35(12): 1524-1539.
DOI：

Qi Chen, Min Zuo, Yi-Hu Song, et al. Molecular Dynamics and Phase Behavior of Polystyrene/Poly(vinyl methyl ether) Blend in the Presence of Nanosilica[J]. Chinese Journal of Polymer Science, 2017, 35(12): 1524-1539. DOI： 10.1007/s10118-017-1980-z.

摘要

Abstract

The variation of phase morphology

critical temperature of demixing

and molecular dynamics for polystyrene/poly(vinyl methyl ether) (PS/PVME) blends induced by hydrophilic nanosilica (A200) or hydrophobic nanosilica (R974) was investigated. With the phase separation of blend matrix

A200 migrated into PVME-rich phase due to strong interaction between A200 and PVME

while R974 moved into PS-rich phase. The thermodynamic miscibility and concentration fluctuation during phase separation of blend matrix were remarkably retarded by A200 nanoparticles due to the surface adsorption of PVME on A200

verified by the correlation length

near the critical region from rheological measurement and the weakened increment of reversing heat capacity (Δ

) during glass transition

via

modulated differential scanning calorimetry (MDSC). The restricted chain diffusion induced by nanosilica still occurred despite no influence of A200 and R974 on the segmental dynamics of homogenous blend matrix. The interactions between nanosilica and polymer components could restrict the terminal relaxation of blend matrix and further manipulate their phase behavior.

关键词

Keywords

references

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