Tough and Multi-responsive Hydrogels Based on Core-Shell Structured Macro-crosslinkers

Gao-lai Du; Yang Cong; Long Chen; Jing Chen; Jun Fu

doi:10.1007/s10118-017-1979-5

Your Location：

Home >

Browse articles >

Tough and Multi-responsive Hydrogels Based on Core-Shell Structured Macro-crosslinkers

Papers | Updated：2021-02-18

- Tough and Multi-responsive Hydrogels Based on Core-Shell Structured Macro-crosslinkers
- Chinese Journal of Polymer Science Vol. 35, Issue 10, Pages: 1286-1296(2017)
- Affiliations：
  
  a.Polymers and Composites Division & Cixi Institute of Biomedical Engineering, Ningbo Institution of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China
  b.School of Chemical Engineering, Ningbo University of Technology, Ningbo 315201, China
- Author bio：
  
  Jun Fu (付俊), E-mail:fujun@nimte.ac.cn
- Funds：
- DOI：10.1007/s10118-017-1979-5
  CLC：
- Received：23 April 2017，
  
  Revised：2017-5-11，
  
  Accepted：17 May 2017，
  
  Published：05 October 2017
- Accepted：
Scan QR Code
Gao-lai Du, Yang Cong, Long Chen, et al. Tough and Multi-responsive Hydrogels Based on Core-Shell Structured Macro-crosslinkers[J]. Chinese Journal of Polymer Science, 2017, 35(10): 1286-1296.
DOI：

Gao-lai Du, Yang Cong, Long Chen, et al. Tough and Multi-responsive Hydrogels Based on Core-Shell Structured Macro-crosslinkers[J]. Chinese Journal of Polymer Science, 2017, 35(10): 1286-1296. DOI： 10.1007/s10118-017-1979-5.

摘要

Abstract

Novel hydrogels based on core-shell structured macro-crosslinkers were synthesized

which exhibited high toughness and multiple responsiveness. Sodium dodecyl sulfate (SDS) micelles mediated by NaCl were used to encapsulate hydrophobic stearyl methacrylate (C18) in the core

and hydrophilic 2-acrylamido-2-methyl-1-propanesulfonic (AMPS) monomers in the corona. Such core-shell micelles were simultaneously copolymerized with acrylamide monomers through free radical polymerization. As a result

hydrogels crosslinked by amphiphilic "poly(C18)-PAMPS" macro-crosslinkers were obtained. These hydrogels showed excellent tensile and compression strength and toughness. Cyclic compression loading-unloading tests demonstrated that the hydrogels were of outstanding fatigue resistance

and showed partial damage of energy dissipation mechanism. The damaged energy dissipation mechanism could be recovered at room temperature and the recovery could be accelerated at elevated temperatures. The hydrogels were sensitive to the change in pH and ion strength

showing reversible swelling/deswelling behaviors.

关键词

Keywords

references

A. Harada , Y. Takashima , M. Nakahata . Acc. Chem. Res. , 2014 . 47 ( 7 ): 2128 DOI: 10.1021/ar500109h http://doi.org/10.1021/ar500109h .

P. Calvert . Adv. Mater. , 2009 . 21 ( 7 ): 743 DOI: 10.1002/adma.v21:7 http://doi.org/10.1002/adma.v21:7 .

T. Wang , J. Huang , Y. Yang , E. Zhang , W. Sun , Z. Tong . ACS Appl. Mater. Interfaces , 2015 . 7 ( 42 ): 23423 DOI: 10.1021/acsami.5b08248 http://doi.org/10.1021/acsami.5b08248 .

C. Li , M.J. Rowland , Y. Shao , T. Cao , C. Chen , H. Jia , X. Zhou , Z. Yang , O.A. Scherman , D. Liu . Adv. Mater. , 2015 . 27 ( 21 ): 3298 DOI: 10.1002/adma.v27.21 http://doi.org/10.1002/adma.v27.21 .

F. Luo , T.L. Sun , T. Nakajima , T. Kurokawa , Y. Zhao , K. Sato , A.B. Ihsan , X. Li , H. Guo , J.P. Gong . Adv. Mater. , 2015 . 27 ( 17 ): 2722 DOI: 10.1002/adma.v27.17 http://doi.org/10.1002/adma.v27.17 .

Y.X. Xu , Q.O. Wu , Y.Q. Sun , H. Bai , G.Q. Shi . ACS Nano , 2010 . 4 ( 12 ): 7358 DOI: 10.1021/nn1027104 http://doi.org/10.1021/nn1027104 .

L.Q. Zhang , L.W. Chen , M. Zhong , F.K. Shi , X.Y. Liu , X.M. Xie . Chinese J. Polym. Sci. , 2016 . 34 ( 10 ): 1261 DOI: 10.1007/s10118-016-1848-7 http://doi.org/10.1007/s10118-016-1848-7 .

X. Hu , M. Vatankhah-Varnoosfaderani , J. Zhou , Q. Li , S.S. Sheiko . Adv. Mater. , 2015 . 27 6899 DOI: 10.1002/adma.201503724 http://doi.org/10.1002/adma.201503724 .

T.L. Sun , T. Kurokawa , S. Kuroda , A.B. Ihsan , T. Akasaki , K. Sato , M.A. Haque , T. Nakajima , J.P. Gong . Nat. Mater. , 2013 . 12 ( 10 ): 932 DOI: 10.1038/nmat3713 http://doi.org/10.1038/nmat3713 .

L.W. Xia , R. Xie , X.J. Ju , W. Wang , Q. Chen , L.Y. Chu . Nat. Commun. , 2013 . 4 2226 http://pubmedcentralcanada.ca/pmcc/articles/PMC3731657/ http://pubmedcentralcanada.ca/pmcc/articles/PMC3731657/ , .

U. Gulyuz , O. Okay . Macromolecules , 2014 . 47 ( 19 ): 6889 DOI: 10.1021/ma5015116 http://doi.org/10.1021/ma5015116 .

D.C. Tuncaboylu , M. Sari , W. Oppermann , O. Okay . Macromolecules , 2011 . 44 ( 12 ): 4997 DOI: 10.1021/ma200579v http://doi.org/10.1021/ma200579v .

Y.N. Sun , S. Liu , G.L. Du , G.R. Gao , J. Fu . Chem. Commun. , 2015 . 51 ( 40 ): 8512 DOI: 10.1039/C4CC10094H http://doi.org/10.1039/C4CC10094H .

H. Chen , C. Zhao , M. Zhang , Q. Chen , J. Ma , J. Zheng . Langmuir , 2016 . 32 ( 14 ): 3315 DOI: 10.1021/acs.langmuir.6b00386 http://doi.org/10.1021/acs.langmuir.6b00386 .

L. Xiao , J. Zhu , D.J. Londono , D.J. Pochan , X. Jia . Soft Matter , 2012 . 8 ( 40 ): 10233 DOI: 10.1039/c2sm26566d http://doi.org/10.1039/c2sm26566d .

C. He , K. Jiao , X. Zhang , M. Xiang , Z. Li , H. Wang . Soft Matter , 2011 . 7 ( 6 ): 2943 DOI: 10.1039/c0sm01149e http://doi.org/10.1039/c0sm01149e .

Y.N. Sun , G.R. Gao , G.L. Du , Y.J. Cheng , J. Fu . ACS Macro Lett. , 2014 . 3 ( 5 ): 496 DOI: 10.1021/mz500221j http://doi.org/10.1021/mz500221j .

G. Akay , A. Hassan-Raeisi , D.C. Tuncaboylu , N. Orakdogen , S. Abdurrahmanoglu , W. Oppermann , O. Okay . Soft Matter , 2013 . 9 ( 7 ): 2254 DOI: 10.1039/c2sm27515e http://doi.org/10.1039/c2sm27515e .

V. Can , Z. Kochovski , V. Reiter , N. Severin , M. Siebenbürger , B. Kent , J. Just , J.P. Rabe , M. Ballauff , O. Okay . Macromolecules , 2016 . 49 ( 6 ): 2281 DOI: 10.1021/acs.macromol.6b00156 http://doi.org/10.1021/acs.macromol.6b00156 .

T. Huang , H.G. Xu , K.X. Jiao , L.P. Zhu , H.R. Brown , H.L. Wang . Adv. Mater. , 2007 . 19 ( 12 ): 1622 DOI: 10.1002/(ISSN)1521-4095 http://doi.org/10.1002/(ISSN)1521-4095 .

D.C. Tuncaboylu , M. Sahin , A. Argun , W. Oppermann , O. Okay . Macromolecules , 2012 . 45 ( 4 ): 1991 DOI: 10.1021/ma202672y http://doi.org/10.1021/ma202672y .

J. Hu , K. Hiwatashi , T. Kurokawa , S.M. Liang , Z.L. Wu , J.P. Gong . Macromolecules , 2011 . 44 ( 19 ): 7775 DOI: 10.1021/ma2016248 http://doi.org/10.1021/ma2016248 .

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Multifunctional Polyurethane with High Strength, Toughness, and Self-healing Capacity via Tannic Acid-modified Cellulose Nanocrystals

Green Fabrication of High-strength Silk Fibroin Hydrogels via Thermal Oscillation in All-aqueous Media

Polyoxometalate-doped Chitosan Quaternary Ammonium/Polyacrylamide Interpenetrating Hydrogels with Enhanced Mechanical and Tribological Properties

Phase Structure Formed by Rubber and Rigid Particles in a Polymer and Its Effect on the Composite Rigidity and Toughness

Direct Ink Writing 3D Printing of Hydrogel Bioelectronics

Related Author

Dan-Min Wu

Chao-Qun Wu

De-Xiang Sun

Xiao-Dong Qi

Jing-Hui Yang

Yong Wang

Yu-Si Long

Mei-Yi Lu

Related Institution

Key Laboratory of Advanced Technologies of Materials (Ministry of Education), School of Chemistry, Southwest Jiaotong University

State Key Laboratory of Integrated Optoelectronics, Key Laboratory of UV Light-Emitting Materials and Technology of Ministry of Education, School of Physics, Northeast Normal University

School of Life Science and Technology, Changchun University of Science and Technology

Changchun SinoBiomaterials Co., Ltd.

State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences

⁰