Enhanced Electron Transfer Ability <italic style="font-style: italic">via</italic> Coordination in Block Copolymer/Porphyrin/Fullerene Micelle

Ruo-lin Wang; Rui Qu; Yan Zhai; Chen Jing; Ang Li; Ying-li An; Lin-qi Shi

doi:10.1007/s10118-017-1973-y

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Enhanced Electron Transfer Ability via Coordination in Block Copolymer/Porphyrin/Fullerene Micelle

Papers | Updated：2021-02-18

- Enhanced Electron Transfer Ability via Coordination in Block Copolymer/Porphyrin/Fullerene Micelle
- Chinese Journal of Polymer Science Vol. 35, Issue 11, Pages: 1328-1341(2017)
- Affiliations：
  
  State Key Laboratory of Medicinal Chemical Biology, Key Laboratory of Functional Polymer Materials, Ministry of Education, Collaborative Innovation Center of Chemical Science and Engineering(Tianjin), Institute of Polymer Chemistry, Nankai University, Tianjin 300071, China
- Author bio：
  
  Lin-qi Shi(史林启), E-mail:shilinqi@nankai.edu.cn
- Funds：
- DOI：10.1007/s10118-017-1973-y
  CLC：
- Received：14 April 2017，
  
  Revised：2017-5-2，
  
  Accepted：08 May 2017，
  
  Published：05 November 2017
- Accepted：
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Ruo-lin Wang, Rui Qu, Yan Zhai, et al. Enhanced Electron Transfer Ability via Coordination in Block Copolymer/Porphyrin/Fullerene Micelle[J]. Chinese Journal of Polymer Science, 2017, 35(11): 1328-1341. DOI: 10.1007/s10118-017-1973-y.
DOI：

Ruo-lin Wang, Rui Qu, Yan Zhai, et al. Enhanced Electron Transfer Ability via Coordination in Block Copolymer/Porphyrin/Fullerene Micelle[J]. Chinese Journal of Polymer Science, 2017, 35(11): 1328-1341. DOI: 10.1007/s10118-017-1973-y. DOI：

摘要

Abstract

Inspired by structures of antenna-reaction centers in photosynthesis

the complex micelle was prepared from zinc tetra-phenyl porphyrin (ZnTPP)

fullerene derivative (PyC

) and poly(ethylene glycol)-block-poly(

-caprolactone) (PEG-

-PCL). The core-shell structure made the hydrophobic donor-acceptor system work in aqueous. In micellar core

coordination interaction occurred between ZnTPP and PyC

molecules which ensured the enhanced energy migration from the donor to the acceptor. The enhanced interaction between porphyrin and fullerene was confirmed by absorption

steady-state fluorescence and transient fluorescence. The generation of singlet oxygen and superoxide radical was detected by iodide method and reduction of nitro blue tetrazolium

respectively

which confirmed that electron transfer reaction in the complex micellar core occurred. Moreover

the complex micelle exhibited effective electron transfer performance in photodebromination of 2

3-dibromo-3-phenylpropionic acid. The complex micellar structure endowed the donor-acceptor system with improved stability under irradiation. This strategy could be helpful for designing new electron transfer platform and artificial photosynthetic system.

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references

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⁰

Enhanced Electron Transfer Ability via Coordination in Block Copolymer/Porphyrin/Fullerene Micelle

DOI：10.1007/s10118-017-1973-y

摘要

Abstract

关键词

Keywords

references