Multi-bond Network Hydrogels with Robust Mechanical and Self-healable Properties

Xiao-ying Liu; Ming Zhong; Fu-kuan Shi; Hao Xu; Xu-ming Xie

doi:10.1007/s10118-017-1971-0

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Multi-bond Network Hydrogels with Robust Mechanical and Self-healable Properties

Papers | Updated：2021-02-18

- Multi-bond Network Hydrogels with Robust Mechanical and Self-healable Properties
- Chinese Journal of Polymer Science Vol. 35, Issue 10, Pages: 1253-1267(2017)
- Affiliations：
  
  Laboratory of Advanced Materials (Ministry of Education), Department of Chemical Engineering, Tsinghua University, Beijing 100084, China
- Author bio：
  
  Xu-ming Xie (谢续明), E-mail:xxm-dce@mail.tsinghua.edu.cn
- Funds：
- DOI：10.1007/s10118-017-1971-0
  CLC：
- Received：09 April 2017，
  
  Revised：2017-5-5，
  
  Accepted：08 May 2017，
  
  Published：05 October 2017
- Accepted：
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Xiao-ying Liu, Ming Zhong, Fu-kuan Shi, et al. Multi-bond Network Hydrogels with Robust Mechanical and Self-healable Properties[J]. Chinese Journal of Polymer Science, 2017, 35(10): 1253-1267.
DOI：

Xiao-ying Liu, Ming Zhong, Fu-kuan Shi, et al. Multi-bond Network Hydrogels with Robust Mechanical and Self-healable Properties[J]. Chinese Journal of Polymer Science, 2017, 35(10): 1253-1267. DOI： 10.1007/s10118-017-1971-0.

摘要

Abstract

Multi-bond network (MBN) which contains a single network with hierarchical cross-links is a suggested way to fabricate robust hydrogels. In order to reveal the roles of different cross-links with hierarchical bond energy in the MBN

here we fabricate poly(acrylic acid) physical hydrogels with dual bond network composed of ionic cross-links between carboxyl-Fe

interactions and hydrogen bonds

and compare these dually cross-linked hydrogels with singly and ternarily cross-linked hydrogels. Simple models are employed to predict the tensile property

and the results confirm that the multi-bond network with hierarchical distribution in the bond energy of cross-links endows hydrogel with effective energy-dissipating mechanism. Moreover

the dually cross-linked MBN gels exhibit excellent mechanical properties (tensile strength up to 500 kPa

elongation at break~2400%) and complete self-healing after being kept at 50℃ for 48 h. The factors on promoting self-healing are deeply explored and the dynamic multi-bonds are regarded to trigger the self-healing along with the mutual diffusion of long polymer chains and ferric ions.

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references

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