Effect of Sequence Structure on Wetting Behaviors of Fluorinated Methacrylate Polymers Based on Perfluorohexylethyl Methacrylate and Stearyl Acrylate

Zi-xu Gu; Jun Cheng; Ming-zu Zhang; Jin-lin He; Pei-hong Ni

doi:10.1007/s10118-017-1966-x

Your Location：

Home >

Browse articles >

Effect of Sequence Structure on Wetting Behaviors of Fluorinated Methacrylate Polymers Based on Perfluorohexylethyl Methacrylate and Stearyl Acrylate

Papers | Updated：2021-02-18

- Effect of Sequence Structure on Wetting Behaviors of Fluorinated Methacrylate Polymers Based on Perfluorohexylethyl Methacrylate and Stearyl Acrylate
- Chinese Journal of Polymer Science Vol. 35, Issue 9, Pages: 1061-1072(2017)
- Affiliations：
  
  College of Chemistry, Chemical Engineering and Materials Science, State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Suzhou Key Laboratory of Macromolecular Design and Precision Synthesis, Soochow University, Suzhou 215123, China
- Author bio：
  
  Pei-hong Ni (倪沛红), E-mail:phni@suda.edu.cn
- Funds：
- DOI：10.1007/s10118-017-1966-x
  CLC：
- Received：08 March 2017，
  
  Revised：2017-4-18，
  
  Accepted：20 April 2017，
  
  Published：05 September 2017
- Accepted：
Scan QR Code
Zi-xu Gu, Jun Cheng, Ming-zu Zhang, et al. Effect of Sequence Structure on Wetting Behaviors of Fluorinated Methacrylate Polymers Based on Perfluorohexylethyl Methacrylate and Stearyl Acrylate[J]. Chinese Journal of Polymer Science, 2017, 35(9): 1061-1072.
DOI：

Zi-xu Gu, Jun Cheng, Ming-zu Zhang, et al. Effect of Sequence Structure on Wetting Behaviors of Fluorinated Methacrylate Polymers Based on Perfluorohexylethyl Methacrylate and Stearyl Acrylate[J]. Chinese Journal of Polymer Science, 2017, 35(9): 1061-1072. DOI： 10.1007/s10118-017-1966-x.

摘要

Abstract

Due to the non-crystalline properties of short chain perfluoroalkyl groups

using short chain perfluoroalkyl to stabilize low surface free energy polymers has been a challenging task. In this study

we prepare a series of random copolymers poly(perfluorohexylethyl methacrylate)-

-poly(stearyl acrylate) (P13FMA-

-PSA) and block copolymers poly(perfluorohexylethyl methacrylate)-

-poly(stearyl acrylate) (P13FMA-

-PSA)

and systematically investigate the effects of the sequence structure and the content of 13FMA of the fluorinated copolymers on surface free energy and surface reorganization. Static/dynamic contact angle goniometry and water/oil repellency analyses demonstrate that the random polymer P13FMA-

-PSA could not achieve low surface free energy and low surface reorganization at the same time. In contrast

for the block copolymer P13FMA-

-PSA

both low surface free energy and low surface reorganization are acquired simultaneously. The results of X-ray photoelectron spectroscopy (XPS)

dynamic contact angle goniometry and differential scanning calorimetry (DSC) reveal the above-mentioned properties. The consecutive 13FMA segments improve the surface fluorine density

while the consecutive SA chains enhance the crystallinity of the SA segments

and further hinder the surface reorganization of the perfluoroalkyl groups. Therefore

P13FMA-

-PSA exhibits a higher utilization efficiency of fluorine atoms and a better structural stability than P13FMA-

-PSA.

关键词

Keywords

references

T. Nishino , M. Meguro , K. Nakamae , M. Matsushita , Y. Ueda . Langmuir , 1999 . 15 4321 DOI: 10.1021/la981727s http://doi.org/10.1021/la981727s .

K. Honda , M. Morita , O. Sakata , S. Sasaki , A. Takahara . Macromolecules , 2010 . 43 454 DOI: 10.1021/ma901973t http://doi.org/10.1021/ma901973t .

L.P. Sung , X.H. Gu , D.L. Ho , F.A. Landis , D. Nguyen . Chinese J. Polym. Sci. , 2009 . 27 ( 1 ): 59 DOI: 10.1142/S0256767909003650 http://doi.org/10.1142/S0256767909003650 .

M.F. Liu , Y.L. Chen , C. Zhang , Z.S. Bo . Chinese J. Polym. Sci. , 2012 . 30 ( 2 ): 308 DOI: 10.1007/s10118-012-1127-1 http://doi.org/10.1007/s10118-012-1127-1 .

E. Martinelli , I. del Moro , G. Galli , M. Barbaglia , C. Bibbiani , E. Mennillo , M. Oliva , C. Pretti , D. Antonioli , M. Laus . ACS Appl. Mater. Interfaces , 2015 . 7 8293 DOI: 10.1021/acsami.5b01522 http://doi.org/10.1021/acsami.5b01522 .

Smith, D. W. , Iacono, S. T. and Iyer, S. S. , "Handbook of fluoropolymer science and technology", John Wiley & Sons, New Jersey, 2014

J.L. Yagüe , K.K. Gleason . Macromolecules , 2013 . 46 6548 DOI: 10.1021/ma4010633 http://doi.org/10.1021/ma4010633 .

T. Yamashita , I. Yamamoto , M. Morita . J. Photopolym. Sci. Technol. , 2012 . 25 207 DOI: 10.2494/photopolymer.25.207 http://doi.org/10.2494/photopolymer.25.207 .

T. Dikić , W. Ming , R.A.T.M. van Benthem , A.C.C. Esteves , G. de With . Adv. Mater. , 2012 . 24 3701 DOI: 10.1002/adma.v24.27 http://doi.org/10.1002/adma.v24.27 .

M. Morita , Y. Kinoshita , Y. Adachi , T. Yamashita , I. Yamamoto . J. Photopolym. Sci. Technol. , 2011 . 24 401 DOI: 10.2494/photopolymer.24.401 http://doi.org/10.2494/photopolymer.24.401 .

P.Y. Huang , Y.C. Chao , Y.T. Liao . J. Appl. Polym. Sci. , 2007 . 104 2451 DOI: 10.1002/(ISSN)1097-4628 http://doi.org/10.1002/(ISSN)1097-4628 .

D. Anton . Adv. Mater. , 1998 . 10 1197 DOI: 10.1002/(ISSN)1521-4095 http://doi.org/10.1002/(ISSN)1521-4095 .

Shimizu, T. , "Fluorinated acrylic ester polymers", in "Modern fluoropolymers: High performance polymers for diverse applications", Ed. by Scheirs, J. , John Wiley & Sons, New York, 1997, p. 516

Q.H. Zhang , Q.Y. Wang , J.X. Jiang , X.L. Zhan , F.Q. Chen . Langmuir , 2015 . 31 4752 DOI: 10.1021/la504467m http://doi.org/10.1021/la504467m .

S. Ozbay , H.Y. Erbil , Surf. Colloids . A , 2014 . 52 9 .

L. Valtola , S. Hietala , H. Tenhu , P. Denifl , C.E. Wilen . Polym. Adv. Technol. , 2009 . 20 225 DOI: 10.1002/pat.v20:3 http://doi.org/10.1002/pat.v20:3 .

S. Saïdi , F. Guittard , C. Guimon , S. Géribaldi . Eur. Polym. J. , 2006 . 42 702 DOI: 10.1016/j.eurpolymj.2005.09.012 http://doi.org/10.1016/j.eurpolymj.2005.09.012 .

P.Y. Huang , Y.C. Chao , Y.T. Liao . J. Appl. Polym. Sci. , 2006 . 100 4711 DOI: 10.1002/(ISSN)1097-4628 http://doi.org/10.1002/(ISSN)1097-4628 .

S. Saïdi , F. Guittard , C. Guimon , S. Géribaldi . Macromol. Chem. Phys. , 2005 . 206 1098 DOI: 10.1002/(ISSN)1521-3935 http://doi.org/10.1002/(ISSN)1521-3935 .

J.W. Ha , I.J. Park , S.B. Lee . Macromolecules , 2005 . 38 736 DOI: 10.1021/ma0488764 http://doi.org/10.1021/ma0488764 .

P.Y. Huang , Y.C. Chao , Y.T. Liao . J. Appl. Polym. Sci. , 2004 . 94 1466 DOI: 10.1002/(ISSN)1097-4628 http://doi.org/10.1002/(ISSN)1097-4628 .

R.R. Thomas , D.R. Anton , W.F. Graham , M.J. Darmon , B.B. Sauer , K.M. Stika , D.G. Swartzfager . Macromolecules , 1997 . 30 2883 DOI: 10.1021/ma9618686 http://doi.org/10.1021/ma9618686 .

Z.X. Gu , M.Z. Zhang , J.L. He , P.H. Ni . Colloids Surf. A: Physicochem. Eng. Aspects , 2016 . 502 159 DOI: 10.1016/j.colsurfa.2016.05.016 http://doi.org/10.1016/j.colsurfa.2016.05.016 .

S. Prasad , L. Hanne , A. Dhinojwala . Macromolecules , 2005 . 38 2541 DOI: 10.1021/ma047599y http://doi.org/10.1021/ma047599y .

Q.H. Zhang , Q.Y. Wang , X.L. Zhan , F.Q. Chen . Ind. Eng. Chem. Res. , 2014 . 53 8026 DOI: 10.1021/ie404217d http://doi.org/10.1021/ie404217d .

A. Fujimori , H. Hoshizawa , S. Kobayashi , K. Kanai , Y. Ouchi , K. Seki . J.Polym. Sci., Part B: Polym. Phys. , 2008 . 46 534 DOI: 10.1002/(ISSN)1099-0488 http://doi.org/10.1002/(ISSN)1099-0488 .

J.Q. Huang , W.D. Meng , F.L. Qing . J. Fluorine Chem. , 2007 . 128 1469 DOI: 10.1016/j.jfluchem.2007.08.005 http://doi.org/10.1016/j.jfluchem.2007.08.005 .

P. Hartmann , A. Collet , M. Viguier . Macromolecules , 2006 . 39 6975 DOI: 10.1021/ma060894t http://doi.org/10.1021/ma060894t .

A. Fujimori , R. Masuya , T. Masuko , E. Ito , M. Hara , K. Kanai , Y. Ouchi , K. Seki , H. Nakahara . Polym. Adv. Technol. , 2006 . 17 653 DOI: 10.1002/(ISSN)1099-1581 http://doi.org/10.1002/(ISSN)1099-1581 .

J.W. Ha , I.J. Park , D.K. Kim , J.H. Kim , S.B. Lee . Surf. Sci. , 2003 . 532-535 328 DOI: 10.1016/S0039-6028(03)00463-1 http://doi.org/10.1016/S0039-6028(03)00463-1 .

G. de Crevoisier , P. Fabre , L. Leibler , S. Tencé-Girault , J.M. Corpart . Macromolecules , 2002 . 35 3880 DOI: 10.1021/ma010459t http://doi.org/10.1021/ma010459t .

M. Morita , H. Ogisu , M. Kubo . J. Appl. Polym. Sci. , 1999 . 73 1741 DOI: 10.1002/(ISSN)1097-4628 http://doi.org/10.1002/(ISSN)1097-4628 .

I. Alig , M. Jarek , G.P. Hellmann . Macromolecules , 1998 . 31 2245 DOI: 10.1021/ma9712615 http://doi.org/10.1021/ma9712615 .

F. Pérez , M. Nadal , A. Navarro-Ortega , F. Fàbrega , J.L. Domingo , D. Barceló , M. Farré . Environ. Int. , 2013 . 59 354 DOI: 10.1016/j.envint.2013.06.004 http://doi.org/10.1016/j.envint.2013.06.004 .

Frömel, T. and Knepper, T. P. , "Biodegradation of fluorinated alkyl substances", in "Reviews of environmental contamination and toxicology", Ed. by de Voogt, P. , Springer, New York, 2010, p. 161

C.P. Chengelis , J.B. Kirkpatrick , N.R. Myers , M. Shinohara , P.L. Stetson , D.W. Sved . Reprod. Toxicol. , 2009 . 27 400 DOI: 10.1016/j.reprotox.2009.01.013 http://doi.org/10.1016/j.reprotox.2009.01.013 .

X.F. Wen , C. Ye , Z.Q. Cai , S.P. Xu , P.H. Pi , J. Cheng , L.J. Zhang , Y. Qian . Appl. Surf. Sci. , 2015 . 339 109 DOI: 10.1016/j.apsusc.2015.02.077 http://doi.org/10.1016/j.apsusc.2015.02.077 .

D.K. Owens , R.C. Wendt . J. Appl. Polym. Sci. , 1969 . 13 1741 DOI: 10.1002/app.1969.070130815 http://doi.org/10.1002/app.1969.070130815 .

F.M. Fowkes . Ind. Eng. Chem. , 1964 . 56 40 .

H. Bellanger , T. Darmanin , T.E. de Givenchy , F. Guittard . Chem. Rev. , 2014 . 114 2694 DOI: 10.1021/cr400169m http://doi.org/10.1021/cr400169m .

H.J. Busscher , A.W.J. van Pelt , P. de Boer , H.P. de Jong , J. Arends . Colloids Surf. , 1984 . 9 319 DOI: 10.1016/0166-6622(84)80175-4 http://doi.org/10.1016/0166-6622(84)80175-4 .

Y. Urushihara , T. Nishino . Langmuir , 2005 . 21 2614 DOI: 10.1021/la047317n http://doi.org/10.1021/la047317n .

T. Nishino , Y. Urushihara , M. Meguro , K. Nakamae . J. Colloid Interf. Sci. , 2004 . 279 364 DOI: 10.1016/j.jcis.2004.06.082 http://doi.org/10.1016/j.jcis.2004.06.082 .

M. Hikita , K. Tanaka , T. Nakamura , T. Kajiyama , A. Takahara . Langmuir , 2004 . 20 5304 DOI: 10.1021/la049556g http://doi.org/10.1021/la049556g .

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Surface Properties and Hydrogen Bonds of Mono-functional Polybenzoxazines with Different N-substituents

Durable Anti-fogging and Abrasion-resistant Coatings Based on Polyoxometalates-Hydrophilic Resin Composites with Enhanced Cohesion and Adhesion

Bioinspired Zinc-doped Nano Hydroxyapatite Reinforced Poly(lactic acid) Composites for Bone Repair

Epoxy-functionalized Cyclohexane-based Ricinoleate Plasticizer: Synthesis, Performance Evaluation, and Plasticizing Mechanism

Porous Organic Polymers for Photocatalytic Hydrogen Peroxide Production: Recent Advances and Future Perspectives

Related Author

Juan Liu

Xin Lu

Zhong Xin

Chang-lu Zhou

Related Institution

School of Chemical Engineering, East China University of Science and Technology

⁰