Synthesis, Self-assembly and pH Sensitivity of a Novel Fluorinated Triphilic Block Copolymer

Xin-xin Li; Xiao Huo; Hui-jiao Han; Shao-liang Lin

doi:10.1007/s10118-017-1963-0

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Synthesis, Self-assembly and pH Sensitivity of a Novel Fluorinated Triphilic Block Copolymer

Papers | Updated：2021-02-18

- Synthesis, Self-assembly and pH Sensitivity of a Novel Fluorinated Triphilic Block Copolymer
- Chinese Journal of Polymer Science Vol. 35, Issue 11, Pages: 1363-1372(2017)
- Affiliations：
  
  a.Key Laboratory of Specially Functional Polymeric Materials and Related Technology of the Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237, China
  b.Key Laboratory of Advanced Polymeric Materials, East China University of Science and Technology, Shanghai 200237, China
- Author bio：
  
  Xin-xin Li(李欣欣), E-mail:xinxinli@ecust.edu.cn
  Shao-liang Lin(林绍梁), E-mail:slin@ecust.edu.cn
- Funds：
- DOI：10.1007/s10118-017-1963-0
  CLC：
- Received：12 March 2017，
  
  Revised：2017-4-7，
  
  Accepted：11 April 2017，
  
  Published：05 November 2017
- Accepted：
Scan QR Code
Xin-xin Li, Xiao Huo, Hui-jiao Han, et al. Synthesis, Self-assembly and pH Sensitivity of a Novel Fluorinated Triphilic Block Copolymer[J]. Chinese Journal of Polymer Science, 2017, 35(11): 1363-1372.
DOI：

Xin-xin Li, Xiao Huo, Hui-jiao Han, et al. Synthesis, Self-assembly and pH Sensitivity of a Novel Fluorinated Triphilic Block Copolymer[J]. Chinese Journal of Polymer Science, 2017, 35(11): 1363-1372. DOI： 10.1007/s10118-017-1963-0.

摘要

Abstract

A novel fluorinated triblock copolymer incorporating 2-ethylhexyl methacrylate (EHMA)

tert

-butyl methacrylate (tBMA) and 1

-perfluorodecyl acrylate (FA) (PEHMA-

-P

BMA-

-PFA) was first synthesized using three successive reversible addition fragmentation chain transfer (RAFT) polymerization and the subsequent hydrolyzing at acidic condition. The as-fabricated triblock copolymer exhibited an interesting morphology evolution from the multi-compartment rod-like structure to spherical structure along with the addition of a selective solution. At the same time

a visible phase separation domain could be seen in the core area due to the existence of fluorocarbon segments. Furthermore

the self-assembly behavior of the triphilic copolymer at different pH was also verified by transmission electron microscopy

as well as the dynamic light scattering. These stimuli-responsive multi-compartment nanostructures may have potential applications in drug delivery.

关键词

Keywords

references

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