Stabilities of Flexible Electrochemical Capacitors Based on Polypyrrole/Carbon Fibers in Different Gel Electrolytes

Ya-hui Chang; Wen Zhou; Gao-yi Han; Yun-zhen Chang; Yao-ming Xiao; Wen-hui Ma

doi:10.1007/s10118-017-1957-y

Your Location：

Home >

Browse articles >

Stabilities of Flexible Electrochemical Capacitors Based on Polypyrrole/Carbon Fibers in Different Gel Electrolytes

Papers | Updated：2021-02-18

- Stabilities of Flexible Electrochemical Capacitors Based on Polypyrrole/Carbon Fibers in Different Gel Electrolytes
- Chinese Journal of Polymer Science Vol. 35, Issue 8, Pages: 961-973(2017)
- Affiliations：
  
  The Institute of Molecular Science, Key Laboratory of Materials for Energy Conversion and Storage of Shanxi Province, Shanxi University, Taiyuan 030006, China
- Author bio：
  
  Gao-yi Han (韩高义), E-mail:han_gaoyis@sxu.edu.cn
  Yao-ming Xiao (肖尧明), E-mail:ymxiao@sxu.edu.cn
- Funds：
- DOI：10.1007/s10118-017-1957-y
  CLC：
- Received：12 January 2017，
  
  Revised：2017-3-28，
  
  Accepted：29 March 2017，
  
  Published：2017-08
- Accepted：
Scan QR Code
Ya-hui Chang, Wen Zhou, Gao-yi Han, et al. Stabilities of Flexible Electrochemical Capacitors Based on Polypyrrole/Carbon Fibers in Different Gel Electrolytes[J]. Chinese Journal of Polymer Science, 2017, 35(8): 961-973.
DOI：

Ya-hui Chang, Wen Zhou, Gao-yi Han, et al. Stabilities of Flexible Electrochemical Capacitors Based on Polypyrrole/Carbon Fibers in Different Gel Electrolytes[J]. Chinese Journal of Polymer Science, 2017, 35(8): 961-973. DOI： 10.1007/s10118-017-1957-y.

摘要

Abstract

Flexible electrochemical capacitors (ECs) are vitally important as the emerging flexible electronics. We have prepared polypyrrole doped with counter ion of Cl

on carbon fibers (PPy-Cl/CFs)

via

the simple electrochemical deposition method. The flexible ECs based on PPy-Cl/CFs electrodes have been assembled by using H

/poly(vinyl alcohol) (PVA)

/PVA

LiClO

/PVA

KCl/PVA and LiCl/PVA as gel electrolytes. The capacitive properties of ECs have been systematically evaluated with electrochemical methods. The results show that the cells with H

/PVA electrolyte exhibit good cyclic stability (91.5% retention after 15000 cycles) although PPy-Cl/CFs has moderate specific capacitance in H

/PVA (41.6 mF·cm

-1

or 52.0 F·cm

-3

). However

the ECs in other electrolytes have poor cyclic stability. Further electrochemical analysis reveals that the doping/dedoping processes of PPy-Cl/CFs are different in the five electrolytes

and X-ray photoelectron spectra demonstrate that the ratios of counter anions in PPy's oxidized states to those in reduced states are obviously different when PPy-Cl/CFs are kept in reduced or oxidized states in the five electrolytes. The results also illustrate why the capacitors using H

/PVA as electrolyte exhibit good cyclic stability. Furthermore

a light emitting diode (LED) with a threshold voltage of 2.5 V can be lighted by three ECs connected in series.

关键词

Keywords

references

D. Yu , Q. Qian , L. Wei , W. Jiang , K. Goh , J. Wei , J. Zhang , Y. Chen . . Chem. Soc. Rev. , 2015 . 44 ( 3 ): 647 DOI: 10.1039/C4CS00286E http://doi.org/10.1039/C4CS00286E .

M. Beidaghi , Y. Gogotsi . . Energy Environ. Sci. , 2014 . 7 ( 3 ): 867 DOI: 10.1039/c3ee43526a http://doi.org/10.1039/c3ee43526a .

P. Tang , L. Han , L. Zhang , S. Wang , W. Feng , G. Xu , L. Zhang . . ChemElectroChem , 2015 . 2 ( 7 ): 949 DOI: 10.1002/celc.v2.7 http://doi.org/10.1002/celc.v2.7 .

J.S. Shayeh , A. Ehsani , M.R. Ganjali , P. Norouzi , B. Jaleh . . Appl. Surf. Sci. , 2015 . 353 594 DOI: 10.1016/j.apsusc.2015.06.066 http://doi.org/10.1016/j.apsusc.2015.06.066 .

Y.Z. Chang , G.Y. Han , J.P. Yuan , D.Y. Fu , F.F. Liu , S.D. Li . . J. Power Sources , 2013 . 238 ( 28 ): 492 .

H.H. Zhou , G.Y. Han , Y.M. Xiao , Y.Z. Chang , H.J. Zhai . . Synthetic Met. , 2015 . 209 405 DOI: 10.1016/j.synthmet.2015.08.014 http://doi.org/10.1016/j.synthmet.2015.08.014 .

Z. Zhang , K. Chi , F. Xiao , S. Wang . . J. Mater. Chem. A , 2015 . 3 ( 24 ): 12828 DOI: 10.1039/C5TA02685G http://doi.org/10.1039/C5TA02685G .

T.H. Zia , A.N. Khan , M. Hussain , I. Hassan , I.H. Gul . . Chinese J. Polym. Sci. , 2016 . 34 ( 12 ): 1500 DOI: 10.1007/s10118-016-1867-4 http://doi.org/10.1007/s10118-016-1867-4 .

S. Stankovich , D.A. Dikin , G.H.B. Dommett , K.M. Kohlhaas , E.J. Zimney , E.A. Stach , R.D. Piner , S.B.T. Nguyen , R.D. Ruoff . . Nature , 2006 . 442 ( 2 ): 282 .

G. Snook , P. Kao , A. Best . . J. Power Sources , 2011 . 196 ( 1 ): 1 DOI: 10.1016/j.jpowsour.2010.06.084 http://doi.org/10.1016/j.jpowsour.2010.06.084 .

Z.X. Dong , T. Feng , C. Zheng , G.M. Li , F.F. Liu , X.P. Qiu . . Chinese J. Polym. Sci. , 2016 . 34 ( 11 ): 1386 DOI: 10.1007/s10118-016-1841-1 http://doi.org/10.1007/s10118-016-1841-1 .

M. Chakrabarti , C. Low , N. Brandon , V. Yufit , M. Hashim , M. Irfan , J. Akhtar , E.R. Trejo , M. Hussain . . Electrochim. Acta , 2013 . 107 ( 10 ): 425 .

M. Liu , Y. Miao , C. Zhang , W.W. Tjiu , Z.B. Yang , H.S. Peng , T.X. Liu . . Nanoscale , 2013 . 5 ( 16 ): 7312 DOI: 10.1039/c3nr01442h http://doi.org/10.1039/c3nr01442h .

Q.Q. Zhou , Y.R. Li , L. Huang , C. Li , G.Q. Shi . . J. Mater. Chem. A , 2014 . 2 ( 41 ): 17489 DOI: 10.1039/C4TA03639E http://doi.org/10.1039/C4TA03639E .

S. Paul , K.S. Choi , D.J. Lee , P. Sudhagar , Y.S. Kang . . Electrochim. Acta , 2012 . 78 ( 9 ): 649 .

K. Liang , T.L. Gu , Z.Y. Cao , X.Z. Tang , W.C. Hu , B.Q. Wei . . Nano Energy , 2014 . 9 245 DOI: 10.1016/j.nanoen.2014.07.017 http://doi.org/10.1016/j.nanoen.2014.07.017 .

H. Sun , B.Y. Lu , D.F. Hu , X.M. Duan , J.K. Xu , S.J. Zhen , K.X. Zhang , X.F. Zhu , L.Q. Dong , D.Z. Mo . . Chinese J. Polym. Sci. , 2015 . 33 ( 11 ): 1527 DOI: 10.1007/s10118-015-1693-0 http://doi.org/10.1007/s10118-015-1693-0 .

Z.T. Zhang , Y. Zhang , Y.M. Li , H.S. Peng . . Acta Polymerica Sinica (in Chinese) , 2016 . ( 10 ): 1284 .

Z. Wang , D. Carlsson , P. Tammela , K. Hua , P. Zhang , L. Nyholm , M. Strømme . . ACS Nano , 2015 . 9 ( 7 ): 7563 DOI: 10.1021/acsnano.5b02846 http://doi.org/10.1021/acsnano.5b02846 .

X.L. Chen , H.J. Lin , J. Deng , Y. Zhang , X.M. Sun , P.N. Chen , X. Fang , Z.T. Zhang , G.Z. Guan , H.S. Peng . . Adv. Mater. , 2014 . 26 ( 48 ): 8126 DOI: 10.1002/adma.201403243 http://doi.org/10.1002/adma.201403243 .

X.L. Chen , H.J. Lin , P.N. Chen , G.Z. Guan , J. Deng , H.S. Peng . . Adv. Mater. , 2014 . 26 ( 26 ): 4444 DOI: 10.1002/adma.v26.26 http://doi.org/10.1002/adma.v26.26 .

Z. Wang , P. Tammela , M. Strømme , L. Nyholm . . Nanoscale , 2015 . 7 ( 8 ): 3418 DOI: 10.1039/C4NR07251K http://doi.org/10.1039/C4NR07251K .

I.M.D.l.F. Salas , Y.N. Sudhakar , M. Selvakumar . . Appl. Surf. Sci. , 2014 . 296 ( 8 ): 195 .

X. Wang , T.M. Wang , C. Yang , H.D. Li , P. Liu . . Appl. Surf. Sci. , 2013 . 287 ( 11 ): 242 .

L. Yuan , B. Yao , B. Hu , K. Huo , W. Chen , J. Zhou . . Energy Environ. Sci. , 2013 . 6 ( 2 ): 470 DOI: 10.1039/c2ee23977a http://doi.org/10.1039/c2ee23977a .

M. Beidaghi , Y. Gogotsi . . Energy Environ. Sci. , 2014 . 7 ( 3 ): 867 DOI: 10.1039/c3ee43526a http://doi.org/10.1039/c3ee43526a .

K. Jost , G. Dion , Y. Gogotsi . . J. Mater. Chem. A , 2014 . 2 ( 28 ): 10776 DOI: 10.1039/c4ta00203b http://doi.org/10.1039/c4ta00203b .

L. Fan , G. Liu , J. Wu , L. Liu , J. Lin , Y. Wei . . Electrochim. Acta , 2014 . 137 ( 8 ): 26 .

C. Yu , P. Ma , X. Zhou , A. Wang , T. Qian , S. Wu , Q. Chen . . ACS Appl. Mater. Interfaces , 2014 . 6 ( 20 ): 17937 DOI: 10.1021/am5059603 http://doi.org/10.1021/am5059603 .

H.H. Zhou , G.Y. Han , Y.M. Xiao , Y.Z. Chang , H.J. Zhai . . J. Power Sources , 2014 . 263 259 DOI: 10.1016/j.jpowsour.2014.04.039 http://doi.org/10.1016/j.jpowsour.2014.04.039 .

X. Zhang , S. Wang , S. Lu , J. Su , T. He . . J. Power Sources , 2014 . 246 ( 1 ): 491 .

M.A. Careem , Y. Velmurugu , S. Skaarup , K. West . . J. Power Sources , 2006 . 159 ( 1 ): 210 DOI: 10.1016/j.jpowsour.2006.04.026 http://doi.org/10.1016/j.jpowsour.2006.04.026 .

Z.H. Huang , Y. Song , X.X. Xu , X.X. Liu . . ACS Appl. Mater. Interfaces , 2015 . 7 25506 DOI: 10.1021/acsami.5b08830 http://doi.org/10.1021/acsami.5b08830 .

D.Y. Feng , Y. Song , Z.H. Huang , X.X. Xu , X.X. Liu . . J. Power Sources , 2016 . 324 788 DOI: 10.1016/j.jpowsour.2016.05.112 http://doi.org/10.1016/j.jpowsour.2016.05.112 .

C.H. Liu , Z.S. Cai , Y.P. Zhao , H. Zhao , F.Y. Ge . . Cellulose , 2016 . 23 637 DOI: 10.1007/s10570-015-0795-8 http://doi.org/10.1007/s10570-015-0795-8 .

F.F. Liu , S.W. Wang , G.Y. Han , R.Q. Liu , Y.Z. Chang , Y.M. Xiao . . J. Appl. Polym. Sci. , 2014 . 131 ( 21 ): 41023 .

L. Liu , Y. Yu , C. Yan , K. Li , Z. Zheng . . Nat. Commun. , 2015 . 6 7260 DOI: 10.1038/ncomms8260 http://doi.org/10.1038/ncomms8260 .

H. Bi , T. Lin , F. Xu , Y. Tang , Z. Liu , F. Huang . . Nano Lett. , 2016 . 16 349 DOI: 10.1021/acs.nanolett.5b03923 http://doi.org/10.1021/acs.nanolett.5b03923 .

J. Zhong , L. Fan , X. Wu , J. Wu , G. Liu , J. Lin , M. Huang , Y. Wei . . Electrochim. Acta , 2015 . 166 150 DOI: 10.1016/j.electacta.2015.03.114 http://doi.org/10.1016/j.electacta.2015.03.114 .

M. Jin , Y.Y. Liu , Y.L. Li , Y.Z. Chang , D.Y. Fu , H. Zhao , G.Y. Han . . J. Appl. Polym. Sci. , 2011 . 122 ( 5 ): 3415 DOI: 10.1002/app.34438 http://doi.org/10.1002/app.34438 .

Z. Yu , J. Thomas . . Adv. Mater. , 2014 . 26 ( 25 ): 4279 DOI: 10.1002/adma.v26.25 http://doi.org/10.1002/adma.v26.25 .

L.Y. Yuan , X.H. Lu , X. Xiao , T. Zhai , J.J. Dai , F.C. Zhang , B. Hu , X. Wang , L. Gong , J. Chen , C.G. Hu , Y.X. Tong , J. Zhou , Z.L. Wang . . ACS Nano , 2012 . 6 ( 1 ): 656 DOI: 10.1021/nn2041279 http://doi.org/10.1021/nn2041279 .

M. Jin , G.Y. Han , Y.Z. Chang , H. Zhao , H.Y. Zhang . . Electrochim. Acta , 2011 . 56 ( 27 ): 9838 DOI: 10.1016/j.electacta.2011.08.079 http://doi.org/10.1016/j.electacta.2011.08.079 .

G. Nyström , M. Strømme , M. Sjödin , L. Nyholm . . Electrochim. Acta , 2012 . 70 ( 70 ): 91 .

A. García-Gómez , S. Eugénio , R.G. Duarte , T.M. Silva , M.J. Carmezim , M.F. Montemor . . Appl. Surf. Sci. , 2016 . 382 34 DOI: 10.1016/j.apsusc.2016.04.113 http://doi.org/10.1016/j.apsusc.2016.04.113 .

G.Y. Han , G.Q. Shi . . Sen. Actuators B , 2006 . 113 ( 1 ): 259 DOI: 10.1016/j.snb.2005.02.055 http://doi.org/10.1016/j.snb.2005.02.055 .

S. Li , C. Zhao , K. Shu , C. Wang , Z. Guo , G. Wallace , H. Liu . . Carbon , 2014 . 79 ( 1 ): 554 .

C. Zhao , C. Wang , Z. Yue , K. Shu , G. Wallace . . ACS Appl. Mater. Interfaces , 2013 . 5 ( 18 ): 9008 DOI: 10.1021/am402130j http://doi.org/10.1021/am402130j .

D. Yang , A. Velamakanni , G. Bozoklu , S. Park , M. Stoller , R.D. Piner , S. Stankovich , I. Jung , D.A. Field , Jr. Ventrice , A. C. , R. Ruoff . . Carbon , 2009 . 47 ( 1 ): 145 DOI: 10.1016/j.carbon.2008.09.045 http://doi.org/10.1016/j.carbon.2008.09.045 .

J. Tabaciarova , M. Micusík , P. Fedorko , M. Omastova . . Polym. Degrad. Stab. , 2015 . 120 392 DOI: 10.1016/j.polymdegradstab.2015.07.021 http://doi.org/10.1016/j.polymdegradstab.2015.07.021 .

S. Shimoda , E. Smela . . Electrochim. Acta , 1998 . 44 ( 2-3 ): 219 DOI: 10.1016/S0013-4686(98)00048-6 http://doi.org/10.1016/S0013-4686(98)00048-6 .

K. Jost , C. Perez , J. McDonough , V. Presser , M. Heon , G. Dion , Y. Gogotsi . . Energy Environ. Sci. , 2011 . 4 ( 12 ): 5060 DOI: 10.1039/c1ee02421c http://doi.org/10.1039/c1ee02421c .

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Anti-freezing Conductive Gelatin Hydrogel Reinforced with Polypyrrole-decorated Cellulose Nanofibers for Strain Sensors and Triboelectric Nanogenerators

Simplified p-i-n Perovskite Solar Cells with a Multifunctional Polyfullerene Electron Transporter

Hyper-crosslinked Conjugated Microporous Polymers with Increased Micropores Promotes Confining Polymerization for Electromagnetic Absorption Application

Manipulating Hierarchical Aggregation Structure via Film-forming Kinetics Enables Organic Photovoltaics over 20% Efficiency

Sequence-encoded Conformation Pathways in Viscoelastic Microphase Separation of Multiblock Copolymers

Related Author

Chang-Ning Hu

Jie He

Yu-Ting He

Yin-Jie Peng

Fei-Fei Wang

Tian-Xiao Liu

Ze-Wei Cui

Ling-Yuan Wang

Related Institution

School of Physics and Astronomy, China West Normal University, Nanchong

State Key Laboratory of Coordination Chemistry, MOE Key Laboratory of High Performance Polymer Materials & Technology, School of Chemistry and Chemical Engineering, Nanjing University

School of Chemistry and Chemical Engineering, Nanjing University of Science & Technology

State Key Laboratory for Marine Corrosion and Protection, Luoyang Ship Material Research Institute (LSMRI)

School of Mechanical Engineering, Nanjing University of Science & Technology

⁰