Synthesis of Cyclic Oligo(ethylene adipate)s and Their Melt Polymerization to Poly(ethylene adipate)

Min Lu; Xiang Zhu; Xiao-hong Li; Xiao-ming Yang; Ying-feng Tu

doi:10.1007/s10118-017-1951-4

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Synthesis of Cyclic Oligo(ethylene adipate)s and Their Melt Polymerization to Poly(ethylene adipate)

Papers | Updated：2021-02-18

- Synthesis of Cyclic Oligo(ethylene adipate)s and Their Melt Polymerization to Poly(ethylene adipate)
- Chinese Journal of Polymer Science Vol. 35, Issue 9, Pages: 1051-1060(2017)
- Affiliations：
  
  Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China
- Author bio：
  
  Ying-feng Tu (屠迎锋), E-mail:tuyingfeng@suda.edu.cn
- Funds：
- DOI：10.1007/s10118-017-1951-4
  CLC：
- Received：08 March 2017，
  
  Revised：2017-4-5，
  
  Accepted：06 April 2017，
  
  Published：05 September 2017
- Accepted：
Scan QR Code
Min Lu, Xiang Zhu, Xiao-hong Li, et al. Synthesis of Cyclic Oligo(ethylene adipate)s and Their Melt Polymerization to Poly(ethylene adipate)[J]. Chinese Journal of Polymer Science, 2017, 35(9): 1051-1060.
DOI：

Min Lu, Xiang Zhu, Xiao-hong Li, et al. Synthesis of Cyclic Oligo(ethylene adipate)s and Their Melt Polymerization to Poly(ethylene adipate)[J]. Chinese Journal of Polymer Science, 2017, 35(9): 1051-1060. DOI： 10.1007/s10118-017-1951-4.

摘要

Abstract

We present here the first synthesis of cyclic oligo(ethylene adipate)s (COEAs)

via

pseudo-high dilution condensation reaction of adipoyl chloride with ethylene glycol

and the synthesis of corresponding poly(ethylene adipate) (PEA)

via

the melt polymerization of COEAs. The structure of COEAs was characterized and proved by

H-NMR and MALDI-TOF mass measurements. The effects of organic base

reaction temperature and the ratio of adipoyl chloride to ethylene glycol on the yield of COEAs were studied

and the optimum reaction condition was revealed. PEA

a diacid and diol based semi-crystalline green aliphatic polyester

was synthesized by the melt polymerization of COEAs using Ti(

-C

as catalyst and 1

10-decanediol as initiator at 200℃

which follows the polycondensation-coupling ring-opening polymerization method. Our strategy should be applicable to the synthesis of versatile aliphatic polyesters based on diacid and diol monomers

which have potential applications as biocompatible and biodegradable materials.

关键词

Keywords

references

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