Specific Thermoresponsive Behaviours Exhibited by Optically Active and Inactive Phenylalanine Modified Hyperbranched Polyethylenimines in Water

Wu-cheng Fang; Ran Zhang; Ye-feng Yao; Hua-ji Liu; Yu Chen

doi:10.1007/s10118-017-1950-5

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Specific Thermoresponsive Behaviours Exhibited by Optically Active and Inactive Phenylalanine Modified Hyperbranched Polyethylenimines in Water

Papers | Updated：2021-02-18

- Specific Thermoresponsive Behaviours Exhibited by Optically Active and Inactive Phenylalanine Modified Hyperbranched Polyethylenimines in Water
- Chinese Journal of Polymer Science Vol. 35, Issue 8, Pages: 1035-1042(2017)
- Affiliations：
  
  a.Tianjin Key Laboratory of Molecular Optoelectronic Science, Department of Chemistry, School of Sciences, Tianjin University, and Collaborative Innovation Center of Chemical Science and Engineering(Tianjin), Tianjin 300354, China
  b.Department of Physics & Shanghai Key Laboratory of Magnetic Resonance, East China Normal University, Shanghai 200062, China
- Author bio：
  
  Hua-ji Liu (刘华姬), E-mail: liuhuaji@tju.edu.cn
  Yu Chen (陈宇), E-mail: chenyu@tju.edu.cn
- Funds：
- DOI：10.1007/s10118-017-1950-5
  CLC：
- Received：14 February 2017，
  
  Revised：2017-3-22，
  
  Accepted：27 March 2017，
  
  Published：2017-08
- Accepted：
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Wu-cheng Fang, Ran Zhang, Ye-feng Yao, et al. Specific Thermoresponsive Behaviours Exhibited by Optically Active and Inactive Phenylalanine Modified Hyperbranched Polyethylenimines in Water[J]. Chinese Journal of Polymer Science, 2017, 35(8): 1035-1042.
DOI：

Wu-cheng Fang, Ran Zhang, Ye-feng Yao, et al. Specific Thermoresponsive Behaviours Exhibited by Optically Active and Inactive Phenylalanine Modified Hyperbranched Polyethylenimines in Water[J]. Chinese Journal of Polymer Science, 2017, 35(8): 1035-1042. DOI： 10.1007/s10118-017-1950-5.

摘要

Abstract

Optically active and inactive hyperbranched polymers with specific thermoresponsive behaviours in water were reported. Through two steps hyperbranched polyethylenimine (HPEI) polymers terminated with different amount of D-phenylalanine (D-Phe)

L-phenylalanine (L-Phe) or DL-phenylalanine (DL-Phe) were prepared and characterized. The analyses on the solution properties by turbidimetry

dynamic light scattering

fluorescence probe and

H-NMR demonstrated that all the polymers exhibited specific thermoresponsive behaviours in water

including:(1) In the dilute polymer concentration region

increasing the polymer concentration led to the increase of phase transition temperature; (2) The optically inactive thermoresponsive hyperbranched polymers showed a higher cloud-point temperature (

) than their corresponding optically active ones in a relatively higher polymer concentration; (3) At the same polymer concentration the hydrophobic groups of the optically inactive HPEI-DL-Phe formed more perfect hydrophobic domain than those of the optically active HPEI-L-Phe and HPEI-D-Phe.

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references

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