Polysulfone Membranes <italic style="font-style: italic">via</italic> Thermally Induced Phase Separation

Hong-qing Liang; Hao-nan Li; Hao-hao Yu; Yong-ting Zhou; Zhi-kang Xu

doi:10.1007/s10118-017-1943-4

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Polysulfone Membranes via Thermally Induced Phase Separation

Papers | Updated：2021-02-18

- Polysulfone Membranes via Thermally Induced Phase Separation
- Chinese Journal of Polymer Science Vol. 35, Issue 7, Pages: 846-856(2017)
- Affiliations：
  
  a.Key Laboratory of Macromolecular Synthesis and Functionalization of the Ministry of Education, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China
  b.Key Laboratory of Adsorption and Separation Materials & Technologies of Zhejiang Province, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China
- Author bio：
  
  Zhi-kang Xu (徐志康), E-mail:xuzk@zju.edu.cn
- Funds：
- DOI：10.1007/s10118-017-1943-4
  CLC：
- Received：17 January 2017，
  
  Revised：2017-2-26，
  
  Accepted：28 February 2017，
  
  Published：05 July 2017
- Accepted：
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Hong-qing Liang, Hao-nan Li, Hao-hao Yu, et al. Polysulfone Membranes via Thermally Induced Phase Separation[J]. Chinese Journal of Polymer Science, 2017, 35(7): 846-856. DOI: 10.1007/s10118-017-1943-4.
DOI：

Hong-qing Liang, Hao-nan Li, Hao-hao Yu, et al. Polysulfone Membranes via Thermally Induced Phase Separation[J]. Chinese Journal of Polymer Science, 2017, 35(7): 846-856. DOI: 10.1007/s10118-017-1943-4. DOI：

摘要

Abstract

Polysulfone (PSF) membranes have gained great attention in the fields of ultrafiltration

microfiltration

and thin film composite membranes for nanofiltration or reverse osmosis. For the first time

it is proposed to fabricate PSF membranes

via

thermally induced phase separation (TIPS) process using diphenyl sulfone (DPSO2) and polyethylene glycol (PEG) as mixed diluent. DPSO2 is chosen as a crystallizable diluent

while PEG is considered in terms of molecular weight (

) and dosage. We systematically investigate the interactions between PSF

DPSO2 and PEG based on the simulation calculations and solubility parameter theory. It is inferred that DPSO2 has an excellent compatibility with PSF

and the addition of PEG results in the ternary system thermodynamically less stable and then facilitates its liquid-liquid (L-L) phase separation. SEM images indicate that cellular-like pores are obvious throughout the membrane when the PEG content in the mixed diluent is 25 wt%-35 wt%. We can facilely manipulate the pore size

water flux and mechanical properties of PSF membranes with the dosage of PEG-200

the

of PEG or the cooling rate. The successful application of TIPS can provide a new approach for structure manipulation and performance enhancement of PSF membranes.

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references

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⁰

Polysulfone Membranes via Thermally Induced Phase Separation

DOI：10.1007/s10118-017-1943-4

摘要

Abstract

关键词

Keywords

references