Spectral Insights into Microdynamics of Thermoresponsive Polymers from the Perspective of Two-dimensional Correlation Spectroscopy

Sheng-tong Sun; Pei-yi Wu

doi:10.1007/s10118-017-1938-1

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Spectral Insights into Microdynamics of Thermoresponsive Polymers from the Perspective of Two-dimensional Correlation Spectroscopy

Feature Articles | Updated：2021-02-18

- Spectral Insights into Microdynamics of Thermoresponsive Polymers from the Perspective of Two-dimensional Correlation Spectroscopy
- Chinese Journal of Polymer Science Vol. 35, Issue 6, Pages: 700-712(2017)
- Affiliations：
  
  a.State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Chemistry, Chemical Engineering and Biotechnology, Center for Advanced Low-Dimension Materials, Donghua University, Shanghai 201620, China
  b.State Key Laboratory of Molecular Engineering of Polymers, Collaborative Innovation Center of Polymers and Polymer Composite Materials, Department of Macromolecular Science and Laboratory for Advanced Materials, Fudan University, Shanghai 200433, China
- Author bio：
  
  Sheng-tong Sun (孙胜童), E-mail: shengtongsun@gmail.com
  Pei-yi Wu (武培怡), E-mail: peiyiwu@fudan.edu.cn
- Funds：
- DOI：10.1007/s10118-017-1938-1
  CLC：
- Received：16 December 2016，
  
  Revised：2017-2-9，
  
  Accepted：17 February 2017，
  
  Published：05 June 2017
- Accepted：
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Sheng-tong Sun, Pei-yi Wu. Spectral Insights into Microdynamics of Thermoresponsive Polymers from the Perspective of Two-dimensional Correlation Spectroscopy[J]. Chinese Journal of Polymer Science, 2017, 35(6): 700-712.
DOI：

Sheng-tong Sun, Pei-yi Wu. Spectral Insights into Microdynamics of Thermoresponsive Polymers from the Perspective of Two-dimensional Correlation Spectroscopy[J]. Chinese Journal of Polymer Science, 2017, 35(6): 700-712. DOI： 10.1007/s10118-017-1938-1.

摘要

Abstract

Generalized two-dimensional correlation spectroscopy (2DCOS) and its derivate technique

perturbation correlation moving window (PCMW)

have found great potential in studying a series of physico-chemical phenomena in stimuli-responsive polymeric systems. By spreading peaks along a second dimension

2DCOS can significantly enhance spectral resolution and discern the sequence of group dynamics applicable to various external perturbation-induced spectroscopic changes

especially in infrared (IR)

near-infrared (NIR) and Raman spectroscopy. On the basis of 2DCOS synchronous power spectra changing

PCMW proves to be a powerful tool to monitor complicated spectral variations and to find transition points and ranges. This article reviews the recent work of our research group in the application of 2DCOS and PCMW in thermoresponsive polymers

mainly focused on liquid crystalline polymers and lower critical solution temperature (LCST)-type polymers. Details of group motions and chain conformational changes upon temperature perturbation can thus be elucidated at the molecular level

which contribute to the understanding of their phase transition nature.

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