Fabrication of Electrospun PVDF Nanofibers with Higher Content of Polar <italic style="font-style: italic">β</italic> Phase and Smaller Diameter by Adding a Small Amount of Dioctadecyl Dimethyl Ammonium Chloride

Xue Wei; Cong Lv; Yao Jing; Feng Chen; Qiang Fu

doi:10.1007/s10118-017-1937-2

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Fabrication of Electrospun PVDF Nanofibers with Higher Content of Polar β Phase and Smaller Diameter by Adding a Small Amount of Dioctadecyl Dimethyl Ammonium Chloride

Papers | Updated：2021-02-18

- Fabrication of Electrospun PVDF Nanofibers with Higher Content of Polar β Phase and Smaller Diameter by Adding a Small Amount of Dioctadecyl Dimethyl Ammonium Chloride
- Chinese Journal of Polymer Science Vol. 35, Issue 8, Pages: 992-1000(2017)
- Affiliations：
  
  College of Polymer Science and Engineering, State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu 610065, China
- Author bio：
  
  Feng Chen (陈枫), E-mail: fengchen@scu.edu.cn
  Qiang Fu (傅强), E-mail: qiangfu@scu.edu.cn
- Funds：
- DOI：10.1007/s10118-017-1937-2
  CLC：
- Received：27 December 2016，
  
  Revised：2017-1-23，
  
  Accepted：02 February 2017，
  
  Published：2017-08
- Accepted：
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Xue Wei, Cong Lv, Yao Jing, et al. Fabrication of Electrospun PVDF Nanofibers with Higher Content of Polar β Phase and Smaller Diameter by Adding a Small Amount of Dioctadecyl Dimethyl Ammonium Chloride[J]. Chinese Journal of Polymer Science, 2017, 35(8): 992-1000. DOI: 10.1007/s10118-017-1937-2.
DOI：

Xue Wei, Cong Lv, Yao Jing, et al. Fabrication of Electrospun PVDF Nanofibers with Higher Content of Polar β Phase and Smaller Diameter by Adding a Small Amount of Dioctadecyl Dimethyl Ammonium Chloride[J]. Chinese Journal of Polymer Science, 2017, 35(8): 992-1000. DOI: 10.1007/s10118-017-1937-2. DOI：

摘要

Abstract

In this work

the effect of dioctadecyl dimethyl ammonium chloride (DDAC

a kind of alkyl ammonium salt) on polar

phase content and the diameter of electrospun PVDF nanofibers was investigated for the first time. Our experimental results show that the diameter of the electrospun PVDF nanofiber could be largely reduced and the content of polar

phase also become dominant immediately by just adding a little amount of DDAC. When the mass fraction of DDAC reached 4%

the content of polar

phase increased by about 39.1% compared with PVDF nanofibers without DDAC. Besides

the crystallinity of PVDF nanofibers also increased with the addition of DDAC. Based on the results

the possible mechanism of cooperative effect between electrospinning and DDAC on fiber diameter and formation of

phase in PVDF was discussed.

关键词

Keywords

references

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Fabrication of Electrospun PVDF Nanofibers with Higher Content of Polar β Phase and Smaller Diameter by Adding a Small Amount of Dioctadecyl Dimethyl Ammonium Chloride

DOI：10.1007/s10118-017-1937-2

摘要

Abstract

关键词

Keywords

references