Isothermal-crystallization Kinetics and Spherulite Growth of Aliphatic Polyketone/Polyamide-6 Blends

He-xin Zhang; Seong-Rok Huh; Eun-Bin Ko; Byung-Sik Park; Keun-Byoung Yoon

doi:10.1007/s10118-017-1936-3

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Isothermal-crystallization Kinetics and Spherulite Growth of Aliphatic Polyketone/Polyamide-6 Blends

Papers | Updated：2021-02-18

- Isothermal-crystallization Kinetics and Spherulite Growth of Aliphatic Polyketone/Polyamide-6 Blends
- Chinese Journal of Polymer Science Vol. 35, Issue 6, Pages: 782-792(2017)
- Affiliations：
  
  a.Department of Polymer Science and Engineering, Kyungpook National University, Korea
  b.Key Laboratory of Synthetic Rubber, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
  c.Department of Pharmaceutical Engineering, International University of Korea, Jinju, Korea
- Author bio：
  
  Keun-Byoung Yoon, E-mail: kbyoon@knu.ac.kr
- Funds：
- DOI：10.1007/s10118-017-1936-3
  CLC：
- Received：17 December 2016，
  
  Revised：2016-12-28，
  
  Accepted：23 January 2017，
  
  Published：05 June 2017
- Accepted：
Scan QR Code
He-xin Zhang, Seong-Rok Huh, Eun-Bin Ko, et al. Isothermal-crystallization Kinetics and Spherulite Growth of Aliphatic Polyketone/Polyamide-6 Blends[J]. Chinese Journal of Polymer Science, 2017, 35(6): 782-792.
DOI：

He-xin Zhang, Seong-Rok Huh, Eun-Bin Ko, et al. Isothermal-crystallization Kinetics and Spherulite Growth of Aliphatic Polyketone/Polyamide-6 Blends[J]. Chinese Journal of Polymer Science, 2017, 35(6): 782-792. DOI： 10.1007/s10118-017-1936-3.

摘要

Abstract

In this research

the morphologies

isothermal-crystallization kinetics

and spherulite growth of aliphatic polyketone/polyamide-6 blends were studied. A single glass-transition temperature (

) was determined

and the composition dependence of

for these blends was well described by the Kwei equation. The strong intermolecular interaction between the two polymer components was confirmed by melting-point depression. The isothermal-crystallization kinetics were analyzed on the basis of the Avrami approach. A linear increase in the radii of the spherulites with time was observed for all compositions. All the spherulites continued to grow at nearly identical growth rates. With increasing polyamide-6 content

the size of the spherulites in the polyketone/polyamide-6 blends gradually decreased

and the number of spherulites in the blends increased.

关键词

Keywords

references

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