Effect of Star-shaped Chain Architectures on the Polylactide Stereocomplex Crystallization Behaviors

Ke-yu Zhou; Jian-bo Li; Han-xuan Wang; Jie Ren

doi:10.1007/s10118-017-1935-4

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Effect of Star-shaped Chain Architectures on the Polylactide Stereocomplex Crystallization Behaviors

Papers | Updated：2021-02-18

- Effect of Star-shaped Chain Architectures on the Polylactide Stereocomplex Crystallization Behaviors
- Chinese Journal of Polymer Science Vol. 35, Issue 8, Pages: 974-991(2017)
- Affiliations：
  
  a.Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, School of Materials Science and Engineering, Tongji University, Shanghai 200092, China
  b.Institute of Nano and Bio-Polymeric Materials, School of Material Science and Engineering, Tongji University, Shanghai 201804, China
- Author bio：
  
  Jian-bo Li (李建波), E-mail: lijianbo@tongji.edu.cn
  Jie Ren (任杰), E-mail: renjie6598@163.com
- Funds：
- DOI：10.1007/s10118-017-1935-4
  CLC：
- Received：19 December 2016，
  
  Revised：2017-1-16，
  
  Accepted：23 January 2017，
  
  Published：2017-08
- Accepted：
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Ke-yu Zhou, Jian-bo Li, Han-xuan Wang, et al. Effect of Star-shaped Chain Architectures on the Polylactide Stereocomplex Crystallization Behaviors[J]. Chinese Journal of Polymer Science, 2017, 35(8): 974-991.
DOI：

Ke-yu Zhou, Jian-bo Li, Han-xuan Wang, et al. Effect of Star-shaped Chain Architectures on the Polylactide Stereocomplex Crystallization Behaviors[J]. Chinese Journal of Polymer Science, 2017, 35(8): 974-991. DOI： 10.1007/s10118-017-1935-4.

摘要

Abstract

Linear and star-shaped polylactides (PLA) with similar molecular weights of each arm are synthesized

via

ring-opening polymerization of LA with 3-butyn-1-ol and pentaerythritol as initiators

respectively. By solution blending of equivalent mass of poly(L-lactic acid)s (PLLAs) and poly(D-lactic acid)s (PDLAs)

perfect PLA stereocomplexes (scPLAs) are prepared and confirmed by WAXD and FTIR analysis. Effect of chain architectures on stereocomplex crystallization is investigated by studying the non-isothermal and isothermal crystallization of linear and star-shaped polylactide stereocomplexes. In dynamic DSC and POM test

star-shaped PLLA (4sPLLA)/PDLA and PLLA/star-shaped PDLA (4sPDLA) stereocomplexes reach rapid crystallization and higher crystallinity due to larger spherulite density of star-shaped chain and excellent chain mobility of linear chain. In isothermal crystallization test

much faster crystallization and less crystallization half-time is obtained with the increase of star-shaped chain. Meanwhile

4sPLLA/PDLA and PLLA/4sPDLA are found to have the highest crystallinity

suggesting limitation of too much star-shaped chain for 4sPLLA/4sPDLA and restriction of linear chain in nucleation capacity for PLLA/PDLA. The results reveal that star-shaped chain has an important influence on the crystallization of scPLAs.

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