Synthesis of Isotactic Polystyrene-block-Polyethylene by the Combination of Sequential Monomer Addition and Hydrogenation of 1, 4-<italic style="font-style: italic">Trans</italic>-polybutadiene Block

Hua-qing Liang; Qi-hua Zhou; Yong-jiang Long; Wan-chu Wei; Guo-dong Liang; Qing Wu; Hai-yang Gao; Fang-ming Zhu

doi:10.1007/s10118-017-1933-6

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Synthesis of Isotactic Polystyrene-block-Polyethylene by the Combination of Sequential Monomer Addition and Hydrogenation of 1, 4-Trans-polybutadiene Block

Papers | Updated：2021-02-18

- Synthesis of Isotactic Polystyrene-block-Polyethylene by the Combination of Sequential Monomer Addition and Hydrogenation of 1, 4-Trans-polybutadiene Block
- Chinese Journal of Polymer Science Vol. 35, Issue 7, Pages: 866-873(2017)
- Affiliations：
  
  a.Guangdong Provincial Key Laboratory for High Performance Polymeric Composites, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China
  b.Key Laboratory for Polymer Composite and Functional Materials of Ministry of Education, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China
- Author bio：
  
  Fang-ming Zhu (祝方明), E-mail:ceszfm@mail.sysu.edu.cn
- Funds：
- DOI：10.1007/s10118-017-1933-6
  CLC：
- Received：07 December 2016，
  
  Revised：2017-1-3，
  
  Accepted：14 January 2017，
  
  Published：05 July 2017
- Accepted：
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Hua-qing Liang, Qi-hua Zhou, Yong-jiang Long, et al. Synthesis of Isotactic Polystyrene-block-Polyethylene by the Combination of Sequential Monomer Addition and Hydrogenation of 1, 4-Trans-polybutadiene Block[J]. Chinese Journal of Polymer Science, 2017, 35(7): 866-873. DOI: 10.1007/s10118-017-1933-6.
DOI：

Hua-qing Liang, Qi-hua Zhou, Yong-jiang Long, et al. Synthesis of Isotactic Polystyrene-block-Polyethylene by the Combination of Sequential Monomer Addition and Hydrogenation of 1, 4-Trans-polybutadiene Block[J]. Chinese Journal of Polymer Science, 2017, 35(7): 866-873. DOI: 10.1007/s10118-017-1933-6. DOI：

摘要

Abstract

Herein

we demonstrate the synthesis of a well-defined diblock copolymer consisting of isotactic polystyrene (

PS) and linear polyethylene

isotactic polystyrene-block-polyethylene (

PS-

-PE)

by the combination of sequential monomer addition and hydrogenation. Isospecific living polymerization of styrene and living

trans

-1

4-polymerization of 1

3-butadiene were catalyzed by 1

4-dithiabutandiyl-2

2′-bis(6-cumenyl-4-methylphenoxy) titanium dichloride (complex 1) activated by triisobutyl aluminum modified methylaluminoxane (MMAO) at room temperature to provide highly isotactic polystyrene (

PS) and 1

trans

-polybutadiene (1

trans

-PBD) with narrow molecular weight distribution. Furthermore

the

PS-

-1

trans

-PBD was synthesized

via

sequential monomer addition in the presence of complex 1 and MMAO. The hydrogenation of the 1

trans

-PBD block was promoted by RuCl

(PPh

)

used as a catalyst to produce

PS-

-PE.

关键词

Keywords

references

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⁰

Synthesis of Isotactic Polystyrene-block-Polyethylene by the Combination of Sequential Monomer Addition and Hydrogenation of 1, 4-Trans-polybutadiene Block

DOI：10.1007/s10118-017-1933-6

摘要

Abstract

关键词

Keywords

references