

FOLLOWUS
Faculty of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, China
Jun-peng Zhao (赵俊鹏), E-mail:msjpzhao@scut.edu.cn
Received:15 December 2016,
Revised:2017-1-3,
Accepted:03 January 2017,
Published:05 May 2017
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Qi-lei Song, Shuang-yan Hu, Jun-peng Zhao, et al. Organocatalytic Copolymerization of Mixed Type Monomers[J]. Chinese Journal of Polymer Science, 2017, 35(5): 581-601.
Qi-lei Song, Shuang-yan Hu, Jun-peng Zhao, et al. Organocatalytic Copolymerization of Mixed Type Monomers[J]. Chinese Journal of Polymer Science, 2017, 35(5): 581-601. DOI: 10.1007/s10118-017-1925-6.
Triggered by environmental concerns and the rising demands for metal-free polymers in e.g. bio-related and microelectronic applications
studies on organocatalytic polymerization have been launched and developed unprecedentedly during the last 15 years. A wide range of organic molecules are now available in polymer chemists' toolbox to choose from as catalysts for polymerization of (hetero) cyclic and polar vinyl monomers. Apart from the intrinsic merits such as lower toxicity and better solubility compared with (transition) metal catalysts/initiators
organocatalysts have also shown
in many cases
excellence to achieve high polymerization rates and/or good control (selectivity). In addition
particular natures and catalytic/activating mechanisms of organocatalysts have led to new opportunities for rational design and efficient synthesis of macromolecular architectures
i.e. chain structures
topological structures and functionalities. This mini-review is specially themed on pathways to construct copolymer chain structures by organocatalytic copolymerization of mixed type monomers (comonomers bearing different polymerizing moieties) and will be sectioned by different comonomer combinations
including cyclic monoesters of different sizes
cyclic monoesters and lactides
cyclic esters and cyclic carbonates or epoxides
heterocycles and vinyl monomers.
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