

FOLLOWUS
College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, China
Ning Ma (马宁), E-mail:nma@hrbeu.edu.cn
Hao Wei (魏浩), E-mail:weihao@hrbeu.edu.cn
Received:22 September 2016,
Revised:2016-11-9,
Accepted:18 November 2016,
Published:2017-05
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Lei Kan, Xiao Ouyang, Shan Gao, et al. High Damping and Mechanical Properties of Hydrogen-bonded Polyethylene Materials with Variable Contents of Hydroxyls: Effect of Hydrogen Bonding Density[J]. Chinese Journal of Polymer Science, 2017, 35(5): 649-658.
Lei Kan, Xiao Ouyang, Shan Gao, et al. High Damping and Mechanical Properties of Hydrogen-bonded Polyethylene Materials with Variable Contents of Hydroxyls: Effect of Hydrogen Bonding Density[J]. Chinese Journal of Polymer Science, 2017, 35(5): 649-658. DOI: 10.1007/s10118-017-1918-5.
Hydrogen bonding is considered to have significant effect on the interaction between polymeric chains and on the viscoelasticity of the polymeric materials. In this paper
we attempt to discuss the relationship between hydrogen bonding density and damping behavior and mechanical properties of polyethylene-based polymeric materials. For this reason
a series of pendant chain hydrogen bonding polymers (
PCHBP
) with different hydrogen bonding density (HBD) were prepared by quantitatively changing the content of pendent hydroxyl groups on the main chain of polyethylene. It was found that
PCHBP
with low HBD showed similar properties to polyethylene
indicating that the property of the materials was dependent mainly on the structure of the main chain. However
PCHBP
with high HBD exhibited two tan
δ
peaks and a platform of loss modulus as well as a high storage modulus (about 400 MPa) at the second tan
δ
peak temperature
demonstrating that a polymeric material with high strength and damping properties was obtained. More importantly
the maximum of loss modulus showed a linear increase with the HBD
indicating that a higher HBD greatly improved the damping properties of the polymeric materials.
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