Crystallization Behavior of Biodegradable Poly (ethylene adipate) Modulated by a Benign Nucleating Agent: Zinc Phenylphosphonate

Rong Liang; Yi-chun Chen; Chun-qiu Zhang; Jing Yin; Xue-lei Liu; Lu-kai Wang; Rui Kong; Xin Feng; Jin-jun Yang

doi:10.1007/s10118-017-1917-6

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Crystallization Behavior of Biodegradable Poly (ethylene adipate) Modulated by a Benign Nucleating Agent: Zinc Phenylphosphonate

Papers | Updated：2021-02-18

- Crystallization Behavior of Biodegradable Poly (ethylene adipate) Modulated by a Benign Nucleating Agent: Zinc Phenylphosphonate
- Chinese Journal of Polymer Science Vol. 35, Issue 4, Pages: 558-568(2017)
- Affiliations：
  
  a.School of Environmental Science and Safety Engineering, Tianjin University of Technology, Tianjin 300384, China
  b.School of Mechanical Engineering, Tianjin University of Technology, Tianjin 300384, China
- Author bio：
  
  Jin-jun Yang (杨进军), E-mail:tjyjj_2014@tjut.edu.cn
- Funds：
- DOI：10.1007/s10118-017-1917-6
  CLC：
- Received：03 September 2016，
  
  Revised：2016-10-9，
  
  Accepted：11 October 2016，
  
  Published：2017-04
- Accepted：
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Rong Liang, Yi-chun Chen, Chun-qiu Zhang, et al. Crystallization Behavior of Biodegradable Poly (ethylene adipate) Modulated by a Benign Nucleating Agent: Zinc Phenylphosphonate[J]. Chinese Journal of Polymer Science, 2017, 35(4): 558-568.
DOI：

Rong Liang, Yi-chun Chen, Chun-qiu Zhang, et al. Crystallization Behavior of Biodegradable Poly (ethylene adipate) Modulated by a Benign Nucleating Agent: Zinc Phenylphosphonate[J]. Chinese Journal of Polymer Science, 2017, 35(4): 558-568. DOI： 10.1007/s10118-017-1917-6.

摘要

Abstract

Zinc phenylphosphonate (PPZn)

a benign and biocompatible nucleating agent

was prepared and incorporated into the biodegradable poly (ethylene adipate) (PEA) to investigate its effect on the crystallization behavior

crystallization kinetics and spherulite morphology of PEA. Upon addition of PPZn

the crystallization temperature and crystallinity of PEA in the non-isothermal crystallization process increased significantly. Analysis of crystallization kinetics by Avrami equation suggests that the crystallization time shortened greatly and crystallization rate increased markedly after addition of PPZn. In the presence of PPZn

the spherulite size decreased and spherulite density increased significantly. It suggests that PPZn is an efficient nucleating agent for the crystallization of PEA. The accelerated crystallization in the presence of PPZn is mainly attributed to the epitaxial nucleation of PEA crystals on the surface of PPZn crystals

that is

a perfect lattice matching between PEA crystal and PPZn crystal occurs.

关键词

Keywords

references

J. Yang , P. Pan , T. Dong , Y. Inoue . . Polymer , 2010 . 51 807 DOI: 10.1016/j.polymer.2009.11.065 http://doi.org/10.1016/j.polymer.2009.11.065 .

P. Pan , Y. Inoue . . Prog. Polym. Sci. , 2009 . 34 605 DOI: 10.1016/j.progpolymsci.2009.01.003 http://doi.org/10.1016/j.progpolymsci.2009.01.003 .

Y. Han , J. Um , S. Im , B. Kim . . J. Polym. Sci., Part A:Polym. Chem. , 2001 . 39 2143 DOI: 10.1002/(ISSN)1099-0518 http://doi.org/10.1002/(ISSN)1099-0518 .

P. Siriphannon , P. Monvisade . . J. Biomater. Sci. Polymer Ed. , 2008 . 19 925 DOI: 10.1163/156856208784613569 http://doi.org/10.1163/156856208784613569 .

C.S. Fuller , C.L. Erickson . . J. Am. Chem. Soc. , 1937 . 59 344 DOI: 10.1021/ja01281a037 http://doi.org/10.1021/ja01281a037 .

C.S. Fuller , C.J. Frosch . . J. Phys. Chem. , 1939 . 43 323 DOI: 10.1021/j150390a005 http://doi.org/10.1021/j150390a005 .

C.S. Fuller . . Chem. Rev. , 1940 . 26 .

A. Turner-Jones , C.W. Bunn . . Acta Crystallogr. , 1962 . 15 105 DOI: 10.1107/S0365110X62000316 http://doi.org/10.1107/S0365110X62000316 .

S.Y. Hobbs , F.W. Billmeyer . . J. Polym. Sci. Part A-2, Polym. Phys. , 1969 . 7 1119 DOI: 10.1002/pol.1969.160070613 http://doi.org/10.1002/pol.1969.160070613 .

B.Y. Teitel'Baum , N.A. Palikhov , L.I. Maklakov , N.P. Anoshina , I.O. Murtazina , V.I. Kovalenko . . Polym. Sci. USSR , 1967 . 9 1880 DOI: 10.1016/0032-3950(67)90435-2 http://doi.org/10.1016/0032-3950(67)90435-2 .

M.C. Popescu , C. Vasile . . Spectrochim. Acta A , 2011 . 79 45 DOI: 10.1016/j.saa.2011.01.042 http://doi.org/10.1016/j.saa.2011.01.042 .

M. Takayanagi , T. Yamashita . . J. Polym. Sci. , 1956 . 22 552 DOI: 10.1002/pol.1956.1202210223 http://doi.org/10.1002/pol.1956.1202210223 .

H.D. Keith , F.J. Padden . . J. Polym. Sci. , 1959 . 39 123 DOI: 10.1002/pol.1959.1203913510 http://doi.org/10.1002/pol.1959.1203913510 .

E. Murayama . . Polym. Preprints JPN. , 2002 . 51 460 https://www.mysciencework.com/publication/show/1c0217af70c962ae58d083f6379f89a9 https://www.mysciencework.com/publication/show/1c0217af70c962ae58d083f6379f89a9 , .

T. Wang , H. Wang , H. Li , Z. Gan , S. Yan . . Phys. Chem. Chem. Phys. , 2009 . 11 1619 DOI: 10.1039/b817597g http://doi.org/10.1039/b817597g .

A. Meyer , K.C. Yen , S.H. Li , S. Förster , E.M. Woo . . Ind. Eng. Chem. Res. , 2010 . 49 12084 DOI: 10.1021/ie901356q http://doi.org/10.1021/ie901356q .

Y. Li , H. Huang , T. He , Z. Wang . . ACS Macro Lett. , 2011 . 1 154 http://pubs.acs.org/doi/abs/10.1021/mz2000785?journalCode=amlccd http://pubs.acs.org/doi/abs/10.1021/mz2000785?journalCode=amlccd , .

E.M. Woo , L.Y. Wang , S. Nurkhamidah . . Macromolecules , 2012 . 45 1375 DOI: 10.1021/ma202222e http://doi.org/10.1021/ma202222e .

G. Lugito , E.M. Woo . . Colloid Polym. Sci. , 2013 . 291 817 DOI: 10.1007/s00396-012-2793-9 http://doi.org/10.1007/s00396-012-2793-9 .

Y. Li , H. Huang , Z. Wang , T. He . . Macromolecules , 2014 . 47 1783 DOI: 10.1021/ma402579d http://doi.org/10.1021/ma402579d .

G. Lugito , E.M. Woo . . Cryst. Growth Des. , 2014 . 14 4929 DOI: 10.1021/cg5002539 http://doi.org/10.1021/cg5002539 .

G. Lugito , E.M. Woo . . Soft Matter , 2015 . 11 908 DOI: 10.1039/C4SM02489C http://doi.org/10.1039/C4SM02489C .

S.Y. Hobbs , F.W. Billmeyer . . J. Polym. Sci. Part A-2, Polym. Phys. , 1970 . 8 1387 DOI: 10.1002/pol.1970.160080810 http://doi.org/10.1002/pol.1970.160080810 .

S.Y. Hobbs , F.W. Billmeyer . . J. Polym. Sci. Part A-2, Polym. Phys. , 1970 . 8 1395 DOI: 10.1002/pol.1970.160080811 http://doi.org/10.1002/pol.1970.160080811 .

V.P. Privalko . . Polym. Sci. USSR , 1972 . 14 1381 DOI: 10.1016/0032-3950(72)90113-X http://doi.org/10.1016/0032-3950(72)90113-X .

M. Varma-Nair , R. Pan , B. Wunderlich . . J. Polym. Sci., Part B:Polym. Phys. , 1991 . 29 1107 DOI: 10.1002/polb.1991.090290909 http://doi.org/10.1002/polb.1991.090290909 .

E.M. Woo , P.L. Wu , M.C. Wu , K.C. Yan . . Macromol. Chem. Phys. , 2006 . 207 2232 DOI: 10.1002/(ISSN)1521-3935 http://doi.org/10.1002/(ISSN)1521-3935 .

T. Zorba , K. Chrissafis , K.M. Paraskevopoulos , D.N. Bikiaris . . Polym. Degrad. Stab. , 2007 . 92 22 http://www.sciencedirect.com/science/article/pii/S0141391007000444 http://www.sciencedirect.com/science/article/pii/S0141391007000444 , .

J. Yang , P. Pan , T. Dong , L. Hua , Y. Inoue . . Macromolecules , 2010 . 3 8610 http://pubs.acs.org/doi/abs/10.1021/ma1000546 http://pubs.acs.org/doi/abs/10.1021/ma1000546 , .

J. Yang , P. Pan , L. Hua , Y. Xie , T. Dong , B. Zhu , Y. Inoue , X. Feng . . Polymer , 2011 . 52 3460 DOI: 10.1016/j.polymer.2011.05.041 http://doi.org/10.1016/j.polymer.2011.05.041 .

J. Yang , P. Pan , L. Hua , X. Feng , J. Yue , Y. Ge , Y. Inoue . . J. Phys. Chem. B , 2012 . 116 1265 DOI: 10.1021/jp209626x http://doi.org/10.1021/jp209626x .

J.T. Haponiuk , J. Foks . . J. Therm. Anal. Calori. , 1990 . 36 2253 DOI: 10.1007/BF01914163 http://doi.org/10.1007/BF01914163 .

J. Foks , M. Luszczek . . J. Cryst. Growth , 1993 . 134 347 DOI: 10.1016/0022-0248(93)90145-M http://doi.org/10.1016/0022-0248(93)90145-M .

J. Foks , J.T. Haponiuk , M. Luszczek . . J. Therm. Anal. Calori. , 1995 . 43 309 DOI: 10.1007/BF02635999 http://doi.org/10.1007/BF02635999 .

C. Nakafuku . . Polym. J. , 1998 . 30 761 DOI: 10.1295/polymj.30.761 http://doi.org/10.1295/polymj.30.761 .

H. Wu , Z. Qiu . . Ind. Eng. Chem. Res. , 2012 . 51 13323 DOI: 10.1021/ie301968f http://doi.org/10.1021/ie301968f .

C.Z. Yan , L. Guo , H.B. Chang , S.K. Yan . . Chinese J. Polym. Sci. , 2013 . 31 1173 DOI: 10.1007/s10118-013-1292-x http://doi.org/10.1007/s10118-013-1292-x .

H.J. Wang , H.P. Feng , X.C. Wang , Q.C. Du , C. Yan . . Chinese J. Polym. Sci. , 2015 . 33 823 DOI: 10.1007/s10118-015-1627-x http://doi.org/10.1007/s10118-015-1627-x .

Z. Jiang , Z. Qiu . . RSC Adv. , 2015 . 5 55486 DOI: 10.1039/C5RA10332K http://doi.org/10.1039/C5RA10332K .

L.Y. Sun , W.J. Boo , D. Sun , A. Clearfield , H.J. Sue . . Chem. Mater. , 2007 . 19 1749 DOI: 10.1021/cm062993r http://doi.org/10.1021/cm062993r .

W.J. Boo , L.Y. Sun , J. Liu , A. Clearfield , H.J. Sue , M.J. Mullins , H. Pham . . Compos. Sci. Technol. , 2007 . 67 262 DOI: 10.1016/j.compscitech.2006.08.012 http://doi.org/10.1016/j.compscitech.2006.08.012 .

R. Zhang , Y. Hu , B. Li , Z. Chen , W. Fan . . J. Mater. Sci. , 2007 . 42 5641 DOI: 10.1007/s10853-006-0629-z http://doi.org/10.1007/s10853-006-0629-z .

L.S. Brandao , L.C. Mendes , M.E. Medeiros , L. Sirelli , M.L. Dias . . J. Appl. Polym. Sci. , 2006 . 102 3868 DOI: 10.1002/(ISSN)1097-4628 http://doi.org/10.1002/(ISSN)1097-4628 .

P.A. Wright , R.H. Jones , S. Natarajan , R.G. Bell , J. Chen , M.B. Hursthouse , J.M. Thomas . . J. Chem. Soc. Chem. Commun. , 1993 . 7 633 http://pubs.rsc.org/EN/content/articlelanding/1993/c3/c39930000633#!divAbstract http://pubs.rsc.org/EN/content/articlelanding/1993/c3/c39930000633#!divAbstract , .

M. Jaber , O. Larlus , J. Miehe-Brendlé . . Solid State Sci. , 2007 . 9 144 DOI: 10.1016/j.solidstatesciences.2006.11.007 http://doi.org/10.1016/j.solidstatesciences.2006.11.007 .

B. Zhang , A. Clearfield . . J. Am. Chem. Soc. , 1997 . 119 2751 DOI: 10.1021/ja9634583 http://doi.org/10.1021/ja9634583 .

G. Alberti , Y. Costantino , F. Marmottini , R. Vivani , P. Zappelli . . Angew. Chem. Int. Ed. En. , 1993 . 32 1357 DOI: 10.1002/(ISSN)1521-3773 http://doi.org/10.1002/(ISSN)1521-3773 .

S.V. Dorozhkin , M. Epple . . Angew. Chem. Int. Ed. , 2002 . 41 3130 DOI: 10.1002/1521-3773(20020902)41:17<>1.0.CO;2-C http://doi.org/10.1002/1521-3773(20020902)41:17<>1.0.CO;2-C .

B. Bujoli , S.M. Lane , G. Nonglaton , M. Pipelier , J. Léger , D.R. Talham , C. Tellier . . Chem-Eur. J. , 2005 . 11 1980 DOI: 10.1002/chem.200400960 http://doi.org/10.1002/chem.200400960 .

L. Herschke , I. Lieberwirth , G. Wegner . . J. Mater. Sci. Mater. Med. , 2006 . 17 95 DOI: 10.1007/s10856-006-6333-3 http://doi.org/10.1007/s10856-006-6333-3 .

P. Pan , Z. Liang , A. Cao , Y. Inoue . . ACS Appl. Mater. Inter. , 2009 . 1 402 DOI: 10.1021/am800106f http://doi.org/10.1021/am800106f .

Y. Chen , S. Wang , Q. Chen , Z. Xi , C. Wang , X. Chen , X. Feng , R. Liang , J. Yang . . Eur. Polym. J. , 2015 . 72 222 DOI: 10.1016/j.eurpolymj.2015.09.020 http://doi.org/10.1016/j.eurpolymj.2015.09.020 .

G. Cao , H. Lee , V.M. Lynch , T.E. Mallouk . . Inorg. Chem. , 1988 . 27 2781 DOI: 10.1021/ic00289a008 http://doi.org/10.1021/ic00289a008 .

K.J. Frink , R.C. Wang , J.L. Colón , A. Clearfield . . Inorg. Chem. , 1991 . 30 1438 DOI: 10.1021/ic00007a004 http://doi.org/10.1021/ic00007a004 .

U.W. Gedde . "Polymer physics" , : London Chapman & Hall , 1995 .

P. Pan , Z. Liang , N. Nakamura , T. Miyagawa , Y. Inoue . . Macromol. Biosci. , 2009 . 9 585 DOI: 10.1002/mabi.v9:6 http://doi.org/10.1002/mabi.v9:6 .

J. Yang , Y. Chen , S. Qin , J. Liu , C. Bi , R. Liang , T. Dong , Feng , Xin. . . Ind. Eng. Chem. Res. , 2015 . 54 8048 DOI: 10.1021/acs.iecr.5b02150 http://doi.org/10.1021/acs.iecr.5b02150 .

J. Yang , Y. Chen , L. Hua , R. Liang , D. Zhu . . J. Appl. Polym. Sci. , 2016 . 133 42957 http://onlinelibrary.wiley.com/doi/10.1002/app.42957/full http://onlinelibrary.wiley.com/doi/10.1002/app.42957/full , .

J. Jia , J. Yang , Y. Zhao , H. Liang , M. Chen . . RSC Adv. , 2016 . 6 43855 DOI: 10.1039/C6RA05514A http://doi.org/10.1039/C6RA05514A .

R. Legras , J.P. Mercier , E. Nield . . Nature , 1983 . 304 432 DOI: 10.1038/304432a0 http://doi.org/10.1038/304432a0 .

D. Libster , A. Aserin , N. Garti . . Polym. Adv. Technol. , 2007 . 18 685 DOI: 10.1002/pat.v18:9 http://doi.org/10.1002/pat.v18:9 .

Y. Sun , H. Li , Y. Huang , E. Chen , L. Zhao , Z. Gan , S. Yan . . Macromolecules , 2005 . 38 2739 DOI: 10.1021/ma0474269 http://doi.org/10.1021/ma0474269 .

Y. Sun , H. Li , Y. Huang , E. Chen , Z. Gan , S. Yan . . Polymer , 2006 . 47 2455 DOI: 10.1016/j.polymer.2006.02.002 http://doi.org/10.1016/j.polymer.2006.02.002 .

C. Mathieu , A. Thierry , J.C. Wittmann , B. Lotz . . J. Polym. Sci., Part B:Polym. Phys. , 2002 . 40 2504 DOI: 10.1002/(ISSN)1099-0488 http://doi.org/10.1002/(ISSN)1099-0488 .

H.G. Haubruge , R. Daussin , A.M. Jonas , R. Legras , J.C. Wittmann , B. Lotz . . Macromolecules , 2003 . 36 4452 DOI: 10.1021/ma0341723 http://doi.org/10.1021/ma0341723 .

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