A Novel Regenerated Silk Fibroin-based Hydrogels with Magnetic and Catalytic Activities

Kun-yuan Luo; Zheng-zhong Shao

doi:10.1007/s10118-017-1910-0

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A Novel Regenerated Silk Fibroin-based Hydrogels with Magnetic and Catalytic Activities

Papers | Updated：2021-02-18

- A Novel Regenerated Silk Fibroin-based Hydrogels with Magnetic and Catalytic Activities
- Chinese Journal of Polymer Science Vol. 35, Issue 4, Pages: 515-523(2017)
- Affiliations：
  
  State Key Laboratory of Molecular Engineering of Polymers, Laboratory of Advanced Materials and Department of Macromolecular Science, Fudan University, Shanghai 200433, China
- Author bio：
  
  Zheng-zhong Shao (邵正中), E-mail: zzshao@fudan.edu.cn
- Funds：
- DOI：10.1007/s10118-017-1910-0
  CLC：
- Received：07 September 2016，
  
  Revised：2016-10-10，
  
  Accepted：11 October 2016，
  
  Published：2017-04
- Accepted：
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Kun-yuan Luo, Zheng-zhong Shao. A Novel Regenerated Silk Fibroin-based Hydrogels with Magnetic and Catalytic Activities[J]. Chinese Journal of Polymer Science, 2017, 35(4): 515-523.
DOI：

Kun-yuan Luo, Zheng-zhong Shao. A Novel Regenerated Silk Fibroin-based Hydrogels with Magnetic and Catalytic Activities[J]. Chinese Journal of Polymer Science, 2017, 35(4): 515-523. DOI： 10.1007/s10118-017-1910-0.

摘要

Abstract

A simple and facile synthetic methodology for fabricating the regenerated silk fibroin (RSF)-based hydrogel which consisted of the

in situ

generated magnetic ferriferous oxide (Fe

) was developed. Using the co-precipitation of Fe

and Fe

within the RSF-based hydrogel with 90% RSF and 10% HPMC (hydroxypropyl methyl cellulose)

the as-prepared RSF/Fe

hydrogel not only showed high strength of saturation magnetization

but also exhibited excellent catalytic activities. For example

with the assistant of 3

5'-tetramethylbenzidine (TMB)

the RSF/Fe

hydrogel could detect H

at a concentration as low as 1×10

-6

mol·L

-1

. In addition

the catalytic activities were able to be maintained for a long term under various conditions. These findings suggest that the RSF-based materials can be endowed with interesting properties

and have great potential for the applications in the fields of biotechnology and environmental chemistry.

关键词

Keywords

references

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