Plasticized Polymer Electrolyte Membranes Based on PEO/PVdF-HFP for Use as an Effective Electrolyte in Lithium-ion Batteries

Prabakaran Pradeepa; Prabhu Manimuthu Ramesh; Gurusamy Sowmya; Sebasthiyan Edwinraj

doi:10.1007/s10118-017-1906-9

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Plasticized Polymer Electrolyte Membranes Based on PEO/PVdF-HFP for Use as an Effective Electrolyte in Lithium-ion Batteries

Papers | Updated：2024-11-27

- Plasticized Polymer Electrolyte Membranes Based on PEO/PVdF-HFP for Use as an Effective Electrolyte in Lithium-ion Batteries
- Chinese Journal of Polymer Science Vol. 35, Issue 3, Pages: 407-421(2017)
- Affiliations：
  
  School of Physics, Alagappa University, Karaikudi-630 004, Tamil Nadu, India
- Author bio：
  
  Ramesh Prabhu Manimuthu, E-mail:mkram83@gmail.com
- Funds：
- DOI：10.1007/s10118-017-1906-9
  CLC：
- Received：05 July 2016，
  
  Revised：2016-10-14，
  
  Accepted：18 October 2016，
  
  Published：25 March 2017
- Accepted：
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Prabakaran Pradeepa, Prabhu Manimuthu Ramesh, Gurusamy Sowmya, et al. Plasticized Polymer Electrolyte Membranes Based on PEO/PVdF-HFP for Use as an Effective Electrolyte in Lithium-ion Batteries[J]. Chinese Journal of Polymer Science, 2017, 35(3): 407-421.
DOI：

Prabakaran Pradeepa, Prabhu Manimuthu Ramesh, Gurusamy Sowmya, et al. Plasticized Polymer Electrolyte Membranes Based on PEO/PVdF-HFP for Use as an Effective Electrolyte in Lithium-ion Batteries[J]. Chinese Journal of Polymer Science, 2017, 35(3): 407-421. DOI： 10.1007/s10118-017-1906-9.

摘要

Abstract

Plasticized polymer electrolytes were prepared using poly(ethylene oxide) (PEO)/poly(vinylidene fluoridehexafluoro propylene) (PVdF-HFP) with lithium perchlorate (LiClO

) and different plasticizers. XRD and FTIR spectroscopic techniques were used to characterize the structure and the complexation of plasticizer with the host polymer matrix. The role of interaction between polymer hosts and plasticizer on conductivity is discussed using the results of alternating current (a.c.) impedance studies. TG-DTA and SEM were used for thermal and physical characterizations. Maximum ionic conductivity (3.26×10

-4

S·cm

-1

) has been observed for ethylene carbonate (EC)-based polymer electrolytes. Electrochemical performance of the plasticized polymer electrolyte is evaluated in LiFePO

/plasticized polymer electrolytes (PPEs)/Li coin cell. Good performance with low capacity fading on charge discharge cycling is demonstrated.

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references

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