Effects of Zinc Oxide Nanoparticles on the Morphology and Viscoelastic Properties of Polyamide 6/Poly(butylene terephthalate) Blends

Wang Li; Guo Zhao-xia; Yu Jian

doi:10.1007/s10118-017-1905-x

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Effects of Zinc Oxide Nanoparticles on the Morphology and Viscoelastic Properties of Polyamide 6/Poly(butylene terephthalate) Blends

Papers | Updated：2024-11-27

- Effects of Zinc Oxide Nanoparticles on the Morphology and Viscoelastic Properties of Polyamide 6/Poly(butylene terephthalate) Blends
- Chinese Journal of Polymer Science Vol. 35, Issue 3, Pages: 434-445(2017)
- Affiliations：
  
  a. The State Key Laboratory of Chemical Resource Engineering, Beijing 100029, China
  b. College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China
  c. Key Laboratory of Advanced Materials, Ministry of Education, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China
- Author bio：
  
  Zhao-xia Guo(郭朝霞), E-mail:guozx@mail.tsinghua.edu.cn
  Jian Yu(于建), E-mail:yuj@mail.tsinghua.edu.cn
- Funds：
- DOI：10.1007/s10118-017-1905-x
  CLC：
- Received：25 August 2016，
  
  Revised：2016-10-6，
  
  Accepted：13 June 2017，
  
  Published：25 March 2017
- Accepted：
Scan QR Code
Wang Li, Guo Zhao-xia, Yu Jian. Effects of Zinc Oxide Nanoparticles on the Morphology and Viscoelastic Properties of Polyamide 6/Poly(butylene terephthalate) Blends[J]. Chinese Journal of Polymer Science, 2017, 35(3): 434-445.
DOI：

Wang Li, Guo Zhao-xia, Yu Jian. Effects of Zinc Oxide Nanoparticles on the Morphology and Viscoelastic Properties of Polyamide 6/Poly(butylene terephthalate) Blends[J]. Chinese Journal of Polymer Science, 2017, 35(3): 434-445. DOI： 10.1007/s10118-017-1905-x.

摘要

Abstract

The morphology of polyamide 6/poly(butylene terephthalate) (PA6/PBT

70/30

W/W

) blends filled with pristine Zinc oxide (ZnO) nanoparticles and ZnO surface-modified by

-glycidoxypropyltrimethoxysilane (K-ZnO) was investigated. The incorporation of ZnO and K-ZnO by one-step compounding both resulted in a smaller size and narrower distribution of PBT domains and the effect of ZnO was greater than K-ZnO. To reveal the underlying mechanism

two-step compounding in which ZnO or K-ZnO was premixed with PA6 or PBT was conducted and the finest morphology was achieved when mixing PA6 with premixed PBT/ZnO. Transmission electron microscopy (TEM) demonstrated that ZnO was distributed in PBT in all cases and K-ZnO was enriched at the interface except when K-ZnO was premixed with PBT. ZnO and K-ZnO caused a deterioration in the melt rheological properties of PBT

which played a dominating role in the morphological changes. In addition

the interfacial localization of K-ZnO enhanced the dynamic rheological properties of PA6/PBT blends substantially.

关键词

Keywords

references

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