Greatly Enhanced Hydrolytic Degradation Ability of Poly(L-lactide) Achieved by Adding Poly(ethylene glycol)

Wang Yang-peng; Wei Xiao; Duan Jin; Yang Jing-hui; Zhang Nan; Huang Ting; Wang Yong

doi:10.1007/s10118-017-1904-y

Your Location：

Home >

Browse articles >

Greatly Enhanced Hydrolytic Degradation Ability of Poly(L-lactide) Achieved by Adding Poly(ethylene glycol)

Papers | Updated：2024-11-27

- Greatly Enhanced Hydrolytic Degradation Ability of Poly(L-lactide) Achieved by Adding Poly(ethylene glycol)
- Chinese Journal of Polymer Science Vol. 35, Issue 3, Pages: 386-399(2017)
- Affiliations：
  
  School of Materials Science and Engineering, Southwest Jiaotong University, Key Laboratory of Advanced Technologies of Materials, Ministry of Education of China, Chengdu 610031, China
- Author bio：
  
  Yong Wang(王勇), E-mail:yongwang1976@163.com
- Funds：
- DOI：10.1007/s10118-017-1904-y
  CLC：
- Received：10 August 2016，
  
  Revised：2016-9-20，
  
  Accepted：20 September 2016，
  
  Published：25 March 2017
- Accepted：
Scan QR Code
Wang Yang-peng, Wei Xiao, Duan Jin, et al. Greatly Enhanced Hydrolytic Degradation Ability of Poly(L-lactide) Achieved by Adding Poly(ethylene glycol)[J]. Chinese Journal of Polymer Science, 2017, 35(3): 386-399.
DOI：

Wang Yang-peng, Wei Xiao, Duan Jin, et al. Greatly Enhanced Hydrolytic Degradation Ability of Poly(L-lactide) Achieved by Adding Poly(ethylene glycol)[J]. Chinese Journal of Polymer Science, 2017, 35(3): 386-399. DOI： 10.1007/s10118-017-1904-y.

摘要

Abstract

Plasticized poly(L-lactide) (PLLA) materials have been applied in many fields and the microstructure performance of such materials attracts much attention of researchers. However

few reports declared the hydrolytic degradation ability of the plasticized PLLA materials. In this article

a small quantity of poly(ethylene glycol) (PEG) was introduced into PLLA

which aimed to understand the hydrolytic degradation behavior of the plasticized PLLA materials. The microstructures of the plasticized samples were comparatively investigated using scanning electron microscopy (SEM)

wide angle X-ray diffraction (WAXD)

differential scanning calorimetry (DSC) and Flourier transform infrared spectroscopy (FTIR)

etc

. The results demonstrated that PEG improved the hydrophilicity of sample surface

and the relatively high content of PEG enhanced the crystallization ability of PLLA matrix. The hydrolytic degradation measurement was carried out at 60℃ in an alkaline solution of pH=12. The results demonstrated that the plasticized PLLA samples exhibited accelerated hydrolytic degradation compared with the pure PLLA sample

and the hydrolytic degradation was also dependent on the PEG content. Further results demonstrated that PEG induced the change of hydrolytic degradation mechanism possibly due to the good dissolution ability of PEG in water

which provided more paths for the penetration of water. Furthermore

the microstructure evolution of the plasticized PLLA during the hydrolytic degradation process was also investigated

and the results demonstrated the occurrence of PLLA crystallization

which was possibly contributed to the decreased hydrolytic degradation rate observed at relatively long hydrolytic degradation time. This work is of great significance and may open a new way for promoting the reclamation of PLLA waste material.

关键词

Keywords

references

H. Ye, , C. Owh, , S. Jiang, , C. Ng, . . Wirawan, D, Loh, X.J.Polymers , 2016 . 8 130 .

H Tsuji, , K. Nakahara, . . J. Appl. Polym. Sci. , 2002 . 86 186 DOI: 10.1002/(ISSN)1097-4628 http://doi.org/10.1002/(ISSN)1097-4628 .

K.L.G. Ho, , A.L. Pometto, , A. Gadea, . . Briceno, J.A, Rojas, A.J. Environ. Polym. Degrad. , 1999 . 7 173 .

S.M. Li, , M. Tenon, , H. Garreau, , C Braud, , M. Vert, . . Polym. Degrad. Stab. , 2000 . 67 85 DOI: 10.1016/S0141-3910(99)00091-9 http://doi.org/10.1016/S0141-3910(99)00091-9 .

L. Liu, , S.M. Li, . . Garreau, H, Vert, M.Biomacromolecules , 2000 . 1 350 .

E Takiyama, , T. Fujimaki, . . Plastics , 1994 . 45 71 .

H.B Li, , M.A. Huneault, . . Polymer , 2007 . 48 6855 DOI: 10.1016/j.polymer.2007.09.020 http://doi.org/10.1016/j.polymer.2007.09.020 .

J.M. Raquez, , Y. Habibi, . . Murariu, M, Dubois, P.Prog. Polym. Sci. , 2013 . 38 1504 DOI: 10.1016/j.progpolymsci.2013.05.014 http://doi.org/10.1016/j.progpolymsci.2013.05.014 .

S.D. Park, , M Todo, , K. Arakawa, . . J. Mater. Sci. , 2005 . 40 1055 DOI: 10.1007/s10853-005-6534-z http://doi.org/10.1007/s10853-005-6534-z .

G. Theryo, , F. Jing, . . Pitet, L.M, Hillmyer, M.A.Macromolecules , 2010 . 43 7394 .

D.W. Grijpma, , E. Kroeze, , A.J Nijenhuis, , A.J. Pennings, . . Polymer , 1993 . 34 1496 DOI: 10.1016/0032-3861(93)90868-B http://doi.org/10.1016/0032-3861(93)90868-B .

R.G. Sinclair, . . J. Macromol. Sci. A , 1996 . 33 585 DOI: 10.1080/10601329608010880 http://doi.org/10.1080/10601329608010880 .

L.V. Labrecque, , R.A. Kumar, , V. Davé, . . Gross, R.A, McCarthy, S.P.J. Appl. Polym. Sci. , 1997 . 66 1507 DOI: 10.1002/(ISSN)1097-4628 http://doi.org/10.1002/(ISSN)1097-4628 .

L. Jiang, , J.W Zhang, , M.P. Wolcott, . . Polymer , 2007 . 48 7632 DOI: 10.1016/j.polymer.2007.11.001 http://doi.org/10.1016/j.polymer.2007.11.001 .

C. Thellen, , C. Orroth, , D. Froio, . . Ziegler, D, Lucciarini, J.Polymer , 2005 . 46 11716 .

L. Jiang, , M.P Wolcott, , J. Zhang, . . Biomacromolecules , 2006 . 7 199 DOI: 10.1021/bm050581q http://doi.org/10.1021/bm050581q .

Y Li, , H. Shimizu, . . Eur. Polym. J. , 2009 . 45 738 DOI: 10.1016/j.eurpolymj.2008.12.010 http://doi.org/10.1016/j.eurpolymj.2008.12.010 .

K. Hashima, . . Nishitsuji, S, Inoue, T.Polymer , 2010 . 51 3934 .

S. Ishida, , R. Nagasaki, , K. Chino, , T Dong, , Y. Inoue, . . J. Appl. Polym. Sci. , 2009 . 113 558 DOI: 10.1002/app.v113:1 http://doi.org/10.1002/app.v113:1 .

S.D. Park, , M. Todo, . . Arakawa, K, Koganemaru, M.Polymer , 2006 . 47 1357 .

D.W. Grijpma, , H. Altpeter, , M.J Bevis, , J. Feijen, . . Polym. Int. , 2002 . 51 845 DOI: 10.1002/(ISSN)1097-0126 http://doi.org/10.1002/(ISSN)1097-0126 .

G Ozkoc, , S. kemaloglu, . . J. Appl. Polym. Sci. , 2009 . 114 2481 DOI: 10.1002/app.v114:4 http://doi.org/10.1002/app.v114:4 .

Z Kulinski, , E. Piorkowska, . . Polymer , 2005 . 46 10290 DOI: 10.1016/j.polymer.2005.07.101 http://doi.org/10.1016/j.polymer.2005.07.101 .

K. Mehmet, . . Humeyra, S, Guralp, O.Polym. Eng. Sci. , 2014 . 54 264 DOI: 10.1002/pen.v54.2 http://doi.org/10.1002/pen.v54.2 .

L. Dobircau, , N. Delpouve, , R. Herbinet, , S. Domenek, , L.L. Pluart, , L. Delbreilh, , V Ducruet, , E. Dargent, . . Polym. Eng. Sci. , 2015 . 55 858 DOI: 10.1002/pen.v55.4 http://doi.org/10.1002/pen.v55.4 .

V.P. Martino, . . Ruseckaite, R.A, Jiménez, A.Polym. Int. , 2009 . 58 437 .

Y. Phuphuak, , Y. Miao, , P Zinck, , S. Chirachanchai, . . Polymer , 2013 . 54 7058 DOI: 10.1016/j.polymer.2013.10.006 http://doi.org/10.1016/j.polymer.2013.10.006 .

L. Yu, , H.S. Liu, , K Dean, , L. Chen, . . J. Polym. Sci.Part B: Polym. Phys. , 2008 . 46 2630 DOI: 10.1002/polb.v46:23 http://doi.org/10.1002/polb.v46:23 .

O Martin, , L. Avérous, . . Polymer , 2001 . 42 6209 DOI: 10.1016/S0032-3861(01)00086-6 http://doi.org/10.1016/S0032-3861(01)00086-6 .

H.W. Xiao, . . Lu, W, Yeh, J.T.J. Appl. Polym. Sci. , 2009 . 133 112 .

H.W. Xiao, , F. Liu, , T Jiang, , J.T. Yeh, . . J. Appl. Polym. Sci. , 2010 . 117 2980 .

J.T. Yeh, , C.Y. Huang, . . Chai, W.L, Chen, K.N.J. Appl. Polym. Sci. , 2009 . 112 2757 .

W.C. Lai, , W.B Liau, , T.T. Lin, . . Polymer , 2004 . 45 3073 DOI: 10.1016/j.polymer.2004.03.003 http://doi.org/10.1016/j.polymer.2004.03.003 .

J.Z. Xu, , Z.J. Zhang, , H. Xu, , J.B. Chen, . . Ran, R, Li, Z.M.Macromolecules , 2015 . 48 4891 .

S.K Saha, , H. Tsuji, . . Polym. Degrad. Stab. , 2006 . 91 1665 DOI: 10.1016/j.polymdegradstab.2005.12.009 http://doi.org/10.1016/j.polymdegradstab.2005.12.009 .

S.S Ray, , M. Bousmina, . . Prog. Mater. Sci. , 2005 . 50 962 DOI: 10.1016/j.pmatsci.2005.05.002 http://doi.org/10.1016/j.pmatsci.2005.05.002 .

H. Fukuzaki, , M. Yoshida, . . Asano, M, Kumakura, M.Eur. Polym. J. , 1989 . 25 1019 DOI: 10.1016/0014-3057(89)90131-6 http://doi.org/10.1016/0014-3057(89)90131-6 .

Q Zhou, , M. Xanthos, . . Polym. Degrad. Stab. , 2008 . 93 1450 DOI: 10.1016/j.polymdegradstab.2008.05.014 http://doi.org/10.1016/j.polymdegradstab.2008.05.014 .

G Gorrasi, , R. Pantani, . . Polym. Degrad. Stab. , 2013 . 98 1006 DOI: 10.1016/j.polymdegradstab.2013.02.005 http://doi.org/10.1016/j.polymdegradstab.2013.02.005 .

R Pantani, , A. Sorrentino, . . Polym. Degrad. Stab. , 2013 . 98 1089 DOI: 10.1016/j.polymdegradstab.2013.01.005 http://doi.org/10.1016/j.polymdegradstab.2013.01.005 .

S.M. Li, . . Garreau, H, Vert, M.J. Mater. Sci. Mater. Med. , 1990 . 1 198 DOI: 10.1007/BF00701077 http://doi.org/10.1007/BF00701077 .

M. Vert, , S.M Li, , H. Garreau, . . J. Biomat. Sci, Polym. E. , 1994 . 6 639 .

H Tsuji, , Y. Ikada, . . J. Polym. Sci.Part A: Polym. Chem. , 1998 . 36 59 DOI: 10.1002/(ISSN)1099-0518 http://doi.org/10.1002/(ISSN)1099-0518 .

H. Tsuji, , A Mizuno, , Y. Ikada, . . J. Appl. Polym. Sci. , 2000 . 77 1452 DOI: 10.1002/(ISSN)1097-4628 http://doi.org/10.1002/(ISSN)1097-4628 .

H. Tsuji, . . Nakahara, K, Ikarashi, K.Macromol. Mater. Eng. , 2001 . 286 398 DOI: 10.1002/(ISSN)1439-2054 http://doi.org/10.1002/(ISSN)1439-2054 .

S.R. Andersson, , M Hakkarainen, , S. Inkinen, . . Biomacromolecules , 2010 . 13 1212 .

S. Chung, . . J. Control. Release , 1995 . 34 9 DOI: 10.1016/0168-3659(94)00100-9 http://doi.org/10.1016/0168-3659(94)00100-9 .

L. Xu, . . Crawford, K, Gorman, C.Macromolecules , 2011 . 44 4777 .

K. Fukushima, , D. Tabuani, , M. Dottori, , I. Armentano, , J.M Kenny, , G. Gamino, . . Polym. Degrad. Stab. , 2011 . 96 2120 DOI: 10.1016/j.polymdegradstab.2011.09.018 http://doi.org/10.1016/j.polymdegradstab.2011.09.018 .

H Tsuji, , K. Nakahara, . . J. Appl. Polym. Sci. , 2002 . 86 186 DOI: 10.1002/(ISSN)1097-4628 http://doi.org/10.1002/(ISSN)1097-4628 .

H Tsuji, , K. Ikarashi, . . Polym. Degrad. Stab. , 2004 . 85 647 DOI: 10.1016/j.polymdegradstab.2004.03.004 http://doi.org/10.1016/j.polymdegradstab.2004.03.004 .

H. Tsuji, . . Shimizu, K, Sato, Y.J. Appl. Polym. Sci. , 2012 . 125 2394 DOI: 10.1002/app.36498 http://doi.org/10.1002/app.36498 .

M. Qu, , H.L. Tu, , M. Amarante, , Y.Q Song, , S.S. Zhu, . . J. Appl. Polym. Sci. , 2014 . 131 40287 .

H.M. Chen, , Y.P. Wang, , J. Chen, , J.H. Yang, , N. Zhang, . . Huang, T, Wang, Y.Polym. Degrad. Stab. , 2013 . 98 2672 DOI: 10.1016/j.polymdegradstab.2013.09.033 http://doi.org/10.1016/j.polymdegradstab.2013.09.033 .

H.M. Chen, , C.X. Feng, , W.B. Zhang, , J.H. Yang, , T. Huang, , N Zhang, , Y. Wang, . . Polym. Degrad. Stab. , 2013 . 98 198 DOI: 10.1016/j.polymdegradstab.2012.10.009 http://doi.org/10.1016/j.polymdegradstab.2012.10.009 .

H.M. Chen, , J.W. Chen, , J. Chen, , J.H. Yang, , T. Huang, . . Zhang, N, Wang, Y.Polym. Degrad. Stab. , 2012 . 97 2273 DOI: 10.1016/j.polymdegradstab.2012.07.037 http://doi.org/10.1016/j.polymdegradstab.2012.07.037 .

M. Eili, , K. Shameli, , N.A Ibrahim, , W.M.Z.W. Yunus, . . Int. J. Mol. Sci. , 2012 . 13 7938 DOI: 10.3390/ijms13077938 http://doi.org/10.3390/ijms13077938 .

Y. Hu, , M. Rogunovaa, , V. Topolkaraevb, . . Hiltnera, A, Baer, E.Polymer , 2003 . 44 5701 .

Y. Hu, , Y.S. Hua, , V. Topolkaraevb, , A Hiltnera, , E. Baer, . . Polymer , 2003 . 44 5711 DOI: 10.1016/S0032-3861(03)00615-3 http://doi.org/10.1016/S0032-3861(03)00615-3 .

Y. Lemmoupchi, , M. Murariu, , A.M.D. Santos, , A.J. Amass, . . Schacht, E, Dubois, P.Eur. Polym. J. , 2009 . 45 2839 DOI: 10.1016/j.eurpolymj.2009.07.006 http://doi.org/10.1016/j.eurpolymj.2009.07.006 .

X.J. Loh, , Y.X. Tan, , Z. Li, , L.S. Teo, , S.H Goh, , J. Li, . . Biomaterials , 2008 . 29 2164 DOI: 10.1016/j.biomaterials.2008.01.016 http://doi.org/10.1016/j.biomaterials.2008.01.016 .

E.W. Fischer, , H.J Sterzel, , G. Wegber, . . Kolloid, Z.Z.Polymer , 1973 . 251 980 DOI: 10.1007/BF01498927 http://doi.org/10.1007/BF01498927 .

J.M. Zhang, , K. Tashiro, , H Tsuji, , A.J. Domb, . . Macromolecules , 2008 . 41 1352 DOI: 10.1021/ma0706071 http://doi.org/10.1021/ma0706071 .

Y.T Shieh, , G.L. Liu, . . J. Polym. Sci.Part B: Polym. Phys. , 2007 . 45 1870 DOI: 10.1002/(ISSN)1099-0488 http://doi.org/10.1002/(ISSN)1099-0488 .

P.J. Pan, , Z.C. Liang, , B. Zhu, , T Dong, , Y. Inoue, . . Macromolecules , 2008 . 41 8011 DOI: 10.1021/ma801436f http://doi.org/10.1021/ma801436f .

B. Na, , R.H. Lv, , S.F. Zou, , Z.J. Li, . . Tian, N.N, Fu, Q.Macromolecules , 2010 . 43 1702 .

C.H. Yan, , J. Wu, , J.M. Zhang, , J.S He, , J. Zhang, . . Polym. Degrad. Stab. , 2015 . 118 130 DOI: 10.1016/j.polymdegradstab.2015.04.019 http://doi.org/10.1016/j.polymdegradstab.2015.04.019 .

Y. Huang, , C. Zhang, , Y. Pan, , Y. Zhou, . . Jiang, L, Dan, Y.Polym. Degrad. Stab. , 2013 . 98 943 DOI: 10.1016/j.polymdegradstab.2013.02.018 http://doi.org/10.1016/j.polymdegradstab.2013.02.018 .

S.Y. Lee, , I.J Chin, , J.S. Jung, . . Eur. Polym. J. , 1999 . 35 2147 DOI: 10.1016/S0014-3057(99)00024-5 http://doi.org/10.1016/S0014-3057(99)00024-5 .

Y.B. Luo, . . Wang, X.L, Wang, Y.Z.Polym. Degrad. Stab. , 2012 . 97 721 DOI: 10.1016/j.polymdegradstab.2012.02.011 http://doi.org/10.1016/j.polymdegradstab.2012.02.011 .

H.M. Chen, , Y. Shen, , J.H. Yang, , T. Huang, , N. Zhang, , Y Wang, , Z.W. Zhou, . . Polymer , 2013 . 54 6644 DOI: 10.1016/j.polymer.2013.09.059 http://doi.org/10.1016/j.polymer.2013.09.059 .

P.J. Pan, , B. Zhu, , W.H. Kai, . . Dong, T, Inoue, Y.Macromolecules , 2008 . 41 4296 .

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Poly(methyl methacrylate)-induced Microstructure and Hydrolysis Behavior Changes of Poly(L-lactic acid)/Carbon Nanotubes Composites

Readily Degradable and Recyclable High Molecular Weight Thiosalicylic Acid-based Copolyesters

Preparation of High-performance Polyimide Fibers with Wholly Rigid Structures Containing Benzobisoxazole Moieties

Synergistic Effects of Solvent Vapor Assisted Spin-coating and Thermal Annealing on Enhancing the Carrier Mobility of Poly(3-hexylthiophene) Field-effect Transistors

An Ultrasensitive, Durable and Stretchable Strain Sensor with Crack-wrinkle Structure for Human Motion Monitoring

Related Author

Xin-Zheng Jin

Ting Huang

Nan Zhang

Xiao-Yu Li

Yong Wang

Xu Yu

Jin-Cai Wu

Hong-Zhang Cao

Related Institution

College of Polymer Science and Engineering, Sichuan University

School of Materials Science & Engineering, Key Laboratory of Advanced Technologies of Materials (Ministry of Education), Southwest Jiaotong University

State Key Laboratory of Baiyunobo Rare Earth Resource Researches and Comprehensive Utilization, Baotou Research Institute of Rare Earths

State Key Laboratory of Applied Organic Chemistry, Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, College of Chemistry and Chemical Engineering, Lanzhou University

School of Textile Materials and Engineering, Wuyi University

⁰