Recent Advances of CuAAC Click Reaction in Building Cyclic Polymer

Huang Zhi-hao; Zhou Yan-yan; Wang Zi-mu; Li Ying; Zhang Wei; Zhou Nian-chen; Zhang Zheng-biao; Zhu Xiu-lin

doi:10.1007/s10118-017-1902-0

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Recent Advances of CuAAC Click Reaction in Building Cyclic Polymer

Reviews | Updated：2024-11-27

- Recent Advances of CuAAC Click Reaction in Building Cyclic Polymer
- Chinese Journal of Polymer Science Vol. 35, Issue 3, Pages: 317-341(2017)
- Affiliations：
  
  State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China
- Author bio：
  
  Zheng-biao Zhang(张正彪), E-mail:zhangzhengbiao@suda.edu.cn
  Xiu-lin Zhu(朱秀林), E-mail:xlzhu@suda.edu.cn
- Funds：
- DOI：10.1007/s10118-017-1902-0
  CLC：
- Received：05 September 2016，
  
  Revised：2016-9-28，
  
  Accepted：28 September 2016，
  
  Published：25 March 2017
- Accepted：
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Huang Zhi-hao, Zhou Yan-yan, Wang Zi-mu, et al. Recent Advances of CuAAC Click Reaction in Building Cyclic Polymer[J]. Chinese Journal of Polymer Science, 2017, 35(3): 317-341.
DOI：

Huang Zhi-hao, Zhou Yan-yan, Wang Zi-mu, et al. Recent Advances of CuAAC Click Reaction in Building Cyclic Polymer[J]. Chinese Journal of Polymer Science, 2017, 35(3): 317-341. DOI： 10.1007/s10118-017-1902-0.

摘要

Abstract

Cyclic polymers have attracted more and more attentions in recent years because of their unique topological structures and characteristic properties in both solution and bulk state. There are relatively few reports on cyclic polymers

partly because of the more demanding synthetic procedures. In recent years

"click" reaction

especially Cu(I)-catalyzed azide-alkyne cycloaddition (CuAAC)

has been widely utilized in the synthesis of cyclic polymer materials because of its high efficiency and low susceptibility to side reactions. In this review

we will focus on three aspects:(1) Constructions of monocyclic polymer using CuAAC "click" chemistry; (2) Formation of complex cyclic polymer topologies through CuAAC reactions; (3) Using CuAAC "click" reaction in the precise synthesis of molecularly defined macrocycles. We believe that the CuAAC click reaction is playing an important role in the design and synthesis of functional cyclic polymers.

关键词

Keywords

references

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