Design, Synthesis, and Optical/Electronic Properties of a Series of Sphere-Rod Shape Amphiphiles Based on the C<sub>60</sub>-oligofluorene Conjugates

Fu-ai Teng; Feng-li Liu; Lu Han; Zheng-ju Zhu; Yi-fang Zhang; Zhi-jin Wu; Zhe-wen Han; Wen-bin Zhang; Hui Li

doi:10.1007/s10118-017-1899-4

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Design, Synthesis, and Optical/Electronic Properties of a Series of Sphere-Rod Shape Amphiphiles Based on the C₆₀-oligofluorene Conjugates

Papers | Updated：2021-02-18

- Design, Synthesis, and Optical/Electronic Properties of a Series of Sphere-Rod Shape Amphiphiles Based on the C₆₀-oligofluorene Conjugates
- Chinese Journal of Polymer Science Vol. 35, Issue 4, Pages: 503-514(2017)
- Affiliations：
  
  a.School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237, China
  b.Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, College of Chemistry and Molecular Engineering, Center for Soft Matter Science and Engineering, Peking University, Beijing 100871, China
- Author bio：
  
  Zhe-wen Han (韩哲文), E-mail: zwhan@ecust.edu.cn
  Wen-bin Zhang (张文彬), E-mail: wenbin@pku.edu.cn
  Hui Li (李慧), E-mail: lihui@ecust.edu.cn
- Funds：
- DOI：10.1007/s10118-017-1899-4
  CLC：
- Received：06 September 2016，
  
  Revised：2016-10-11，
  
  Accepted：12 October 2016，
  
  Published：2017-04
- Accepted：
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Fu-ai Teng, Feng-li Liu, Lu Han, et al. Design, Synthesis, and Optical/Electronic Properties of a Series of Sphere-Rod Shape Amphiphiles Based on the C₆₀-oligofluorene Conjugates[J]. Chinese Journal of Polymer Science, 2017, 35(4): 503-514. DOI: 10.1007/s10118-017-1899-4.
DOI：

Fu-ai Teng, Feng-li Liu, Lu Han, et al. Design, Synthesis, and Optical/Electronic Properties of a Series of Sphere-Rod Shape Amphiphiles Based on the C₆₀-oligofluorene Conjugates[J]. Chinese Journal of Polymer Science, 2017, 35(4): 503-514. DOI: 10.1007/s10118-017-1899-4. DOI：

摘要

Abstract

A series of sphere-rod shape amphiphiles were designed and synthesized by connecting the rod-like oligofluorenes with different lengths (OF

) to the different positions of the spherical[60]fullerene (C

) through a rigid linkage. The conjugates were characterized by

H-NMR

C-NMR

FTIR

EA and MALDI-TOF mass spectrometry. The optical and electronic properties of the conjugates were studied by UV-Vis absorption spectroscopy

fluorescence spectrometry

and cyclic voltammetry. The results from UV-Vis absorption spectroscopy and cyclic voltammetry indicated that the energy profiles of C

and OF

remained unchanged when different lengths of OF

were attached to C

. The electron affinities of the OF

-C

conjugates were close to that of C

while slight electronic interaction was found between the two individual chromophores (C

and OF

) in their ground states. The fluorescence spectra exhibited a complete fluorescence quenching in the toluene solution

suggesting an effective energy transfer from OF

to C

. It presents a systematic study on the self-assembly

structure-property relationship

and potential technical applications of the conjugates.

关键词

Keywords

references

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⁰

Design, Synthesis, and Optical/Electronic Properties of a Series of Sphere-Rod Shape Amphiphiles Based on the C60-oligofluorene Conjugates

DOI：10.1007/s10118-017-1899-4

摘要

Abstract

关键词

Keywords

references

Design, Synthesis, and Optical/Electronic Properties of a Series of Sphere-Rod Shape Amphiphiles Based on the C₆₀-oligofluorene Conjugates