Structure-Activity Correlations of Calcined Mg-Al Hydrocalcites for Aliphatic Polycarbonate Synthesis <italic style="font-style: italic">via</italic> Transesterification Process

Zi-qing Wang; Yuan-sheng Bai; Wei Jiang; Xian-gui Yang; Shao-ying Liu; Gong-ying Wang

doi:10.1007/s10118-017-1887-8

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Structure-Activity Correlations of Calcined Mg-Al Hydrocalcites for Aliphatic Polycarbonate Synthesis via Transesterification Process

PAPERS | Updated：2021-02-18

- Structure-Activity Correlations of Calcined Mg-Al Hydrocalcites for Aliphatic Polycarbonate Synthesis via Transesterification Process
- Chinese Journal of Polymer Science Vol. 35, Issue 1, Pages: 130-140(2017)
- Affiliations：
  
  a.Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041, China
  b.University of Chinese Academy of Sciences, Beijing 100049, China
  c.Changzhou Institute of Chemistry, Changzhou 213164, China
- Author bio：
  
  Gong-ying Wang, E-mail:gywang@cioc.ac.cn, wanggongying1102@126.com
- Funds：
- DOI：10.1007/s10118-017-1887-8
  CLC：
- Received：19 August 2016，
  
  Revised：2016-9-5，
  
  Accepted：11 September 2016，
  
  Published：2017-01
- Accepted：
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Zi-qing Wang, Yuan-sheng Bai, Wei Jiang, et al. Structure-Activity Correlations of Calcined Mg-Al Hydrocalcites for Aliphatic Polycarbonate Synthesis via Transesterification Process[J]. Chinese Journal of Polymer Science, 2017, 35(1): 130-140. DOI: 10.1007/s10118-017-1887-8.
DOI：

Zi-qing Wang, Yuan-sheng Bai, Wei Jiang, et al. Structure-Activity Correlations of Calcined Mg-Al Hydrocalcites for Aliphatic Polycarbonate Synthesis via Transesterification Process[J]. Chinese Journal of Polymer Science, 2017, 35(1): 130-140. DOI: 10.1007/s10118-017-1887-8. DOI：

摘要

Abstract

Mg-Al mixed oxides with different Mg/Al molar ratio were prepared by thermal decomposition of hydrotalcite-like precursors at 500℃ for 5.0 h and used as catalysts for the transesterification of diphenyl carbonate with 1

4-butanediol to synthesize high-molecular-weight poly(butylene carbonate) (PBC). The structure-activity correlations of these catalysts in this transesterification process were discussed by means of various characterization techniques. It was found that the chain growth for the formation of PBC can only be obtained through connecting-OH and-OC(C) OC

end-group upon removing the generated phenol

and the sample with Mg/Al molar ratio of 4.0 exhibited the best catalytic performance

giving PBC with

of 1.64×10

g/mol at 210℃ for 3.0 h. This excellent activity depended mainly on the specific surface area and basicity rather than pore structure or crystallite size of MgO.

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Structure-Activity Correlations of Calcined Mg-Al Hydrocalcites for Aliphatic Polycarbonate Synthesis via Transesterification Process

DOI：10.1007/s10118-017-1887-8

摘要

Abstract

关键词

Keywords

references