Structure and Properties of Gel-spun Ultra-high Molecular Weight Polyethylene Fibers with High Gel Solution Concentration

Min-fang An; You Lv; Hao-jun Xu; Qun Gu; Zong-bao Wang

doi:10.1007/s10118-017-1883-z

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Structure and Properties of Gel-spun Ultra-high Molecular Weight Polyethylene Fibers with High Gel Solution Concentration

Papers | Updated：2021-02-18

- Structure and Properties of Gel-spun Ultra-high Molecular Weight Polyethylene Fibers with High Gel Solution Concentration
- Chinese Journal of Polymer Science Vol. 35, Issue 4, Pages: 524-533(2017)
- Affiliations：
  
  a.Ningbo Key Laboratory of Specialty Polymers, Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, China
  b.College of Material Engineering, Ningbo University of Technology, Ningbo 315211, China
- Author bio：
  
  Zong-bao Wang (王宗宝), E-mail:wangzongbao@nbu.edu.cn
- Funds：
- DOI：10.1007/s10118-017-1883-z
  CLC：
- Received：31 July 2016，
  
  Revised：2016-8-30，
  
  Accepted：22 September 2016，
  
  Published：2017-04
- Accepted：
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Min-fang An, You Lv, Hao-jun Xu, et al. Structure and Properties of Gel-spun Ultra-high Molecular Weight Polyethylene Fibers with High Gel Solution Concentration[J]. Chinese Journal of Polymer Science, 2017, 35(4): 524-533.
DOI：

Min-fang An, You Lv, Hao-jun Xu, et al. Structure and Properties of Gel-spun Ultra-high Molecular Weight Polyethylene Fibers with High Gel Solution Concentration[J]. Chinese Journal of Polymer Science, 2017, 35(4): 524-533. DOI： 10.1007/s10118-017-1883-z.

摘要

Abstract

The gel-spun ultra-high molecular weight polyethylene (UHMWPE) fibers were prepared at the industrial production line with different gel solution concentrations of 15 wt%

18 wt% and 24 wt%. The difference in ultimate structure and mechanical properties of UHMWPE fibers for different gel solution concentrations were analyzed by tensile testing

differential scanning calorimetry (DSC)

wide angle X-ray diffraction (WAXD) and small angle X-ray scattering (SAXS). With the increase of gel solution concentration

the ultimate mechanical properties of UHMWPE fibers were decreased and the crystallization and orientation of UHMWPE fibers became inferior. Besides

both the average shish length (

shish

) and shish misorientation (

) of UHMWPE fibers were decreased with the increase of gel solution concentration. In addition

the appropriate increase of spinning temperature led to the further optimization of the ultimate structure and mechanical properties of UHMWPE fibers.

关键词

Keywords

references

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