Aqueous RAFT Polymerization of Acrylamide: A Convenient Method for Polyacrylamide with Narrow Molecular Weight Distribution

Jun Liang; Guo-rong Shan; Peng-ju Pan

doi:10.1007/s10118-017-1874-0

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Aqueous RAFT Polymerization of Acrylamide: A Convenient Method for Polyacrylamide with Narrow Molecular Weight Distribution

PAPERS | Updated：2021-02-18

- Aqueous RAFT Polymerization of Acrylamide: A Convenient Method for Polyacrylamide with Narrow Molecular Weight Distribution
- Chinese Journal of Polymer Science Vol. 35, Issue 1, Pages: 123-129(2017)
- Affiliations：
  
  State Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China
- Author bio：
  
  Guo-rong Shan, E-mail:shangr@zju.edu.cn
- Funds：
- DOI：10.1007/s10118-017-1874-0
  CLC：
- Received：25 July 2016，
  
  Revised：2016-8-25，
  
  Accepted：28 August 2016，
  
  Published：2017-01
- Accepted：
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Jun Liang, Guo-rong Shan, Peng-ju Pan. Aqueous RAFT Polymerization of Acrylamide: A Convenient Method for Polyacrylamide with Narrow Molecular Weight Distribution[J]. Chinese Journal of Polymer Science, 2017, 35(1): 123-129.
DOI：

Jun Liang, Guo-rong Shan, Peng-ju Pan. Aqueous RAFT Polymerization of Acrylamide: A Convenient Method for Polyacrylamide with Narrow Molecular Weight Distribution[J]. Chinese Journal of Polymer Science, 2017, 35(1): 123-129. DOI： 10.1007/s10118-017-1874-0.

摘要

Abstract

Controlled and homogeneous free-radical polymerization of acrylamide (AM) in aqueous phase was realized by using

'-bis(

'-dimethyl-

''-acetic acid)-trithiocarbonate as a reversible addition-fragmentation transfer (RAFT) agent. Linear increases in molecular weight with conversion and narrow molecular weight distribution were observed for polyacrylamide (PAM) throughout the polymerization. By this method

PAMs with controlled molecular weight (up to 1.0×10

) and narrow molecular weight distribution (

1.2) were prepared. This study provides an effective method for synthesis of PAMs with narrow molecular weight distribution under environmentally friendly conditions.

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Keywords

references

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