Ring-opening Metathesis Polymerization of Cis-5-norbornene-<italic style="font-style: italic">endo</italic>-2,3-dicarboxylic Anhydride Derivatives Using the Grubbs Third Generation Catalyst

Ji-xing Yang; Li-xia Ren; Yue-sheng Li

doi:10.1007/s10118-017-1873-1

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Ring-opening Metathesis Polymerization of Cis-5-norbornene-endo-2,3-dicarboxylic Anhydride Derivatives Using the Grubbs Third Generation Catalyst

PAPERS | Updated：2021-02-18

- Ring-opening Metathesis Polymerization of Cis-5-norbornene-endo-2,3-dicarboxylic Anhydride Derivatives Using the Grubbs Third Generation Catalyst
- Chinese Journal of Polymer Science Vol. 35, Issue 1, Pages: 36-45(2017)
- Affiliations：
  
  School of Materials Science and Engineering and Tianjin Key Laboratory of Composite and Functional Materials, Tianjin University, Tianjin 300072, China
- Author bio：
  
  Li-xia Ren, E-mail:lxren@tju.edu.cn
- Funds：
- DOI：10.1007/s10118-017-1873-1
  CLC：
- Received：12 August 2016，
  
  Revised：2016-9-9，
  
  Accepted：12 September 2016，
  
  Published：2017-01
- Accepted：
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Ji-xing Yang, Li-xia Ren, Yue-sheng Li. Ring-opening Metathesis Polymerization of Cis-5-norbornene-endo-2,3-dicarboxylic Anhydride Derivatives Using the Grubbs Third Generation Catalyst[J]. Chinese Journal of Polymer Science, 2017, 35(1): 36-45. DOI: 10.1007/s10118-017-1873-1.
DOI：

Ji-xing Yang, Li-xia Ren, Yue-sheng Li. Ring-opening Metathesis Polymerization of Cis-5-norbornene-endo-2,3-dicarboxylic Anhydride Derivatives Using the Grubbs Third Generation Catalyst[J]. Chinese Journal of Polymer Science, 2017, 35(1): 36-45. DOI: 10.1007/s10118-017-1873-1. DOI：

摘要

Abstract

A series of

cis

-5-norbornene-

endo

-2

3-dicarboxylic anhydride (NDCA

M1) derivatives (M2-M4) with different types of nonpolar substituted groups were synthesized and characterized by

C-NMR and mass spectrometry (MS). Ring-opening metathesis polymerization (ROMP) of these monomers using the Grubbs third generation catalyst (G3) generated high molecular weight polymers with much improved solubility compared with the NDCA's homopolymer. It was found that the solubility of these polymers increased with increased substituent's steric hindrance. The living polymerization of NDCA derivative containing the bulkiest substituent (M4) catalyzed by G3 in tetrahydrofuran was confirmed by the kinetic studies with low polydispersity indices (PDI) (

1.30). By using sequential ROMP

well-defined diblock copolymers containing anhydride groups were synthesized.

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Ring-opening Metathesis Polymerization of Cis-5-norbornene-endo-2,3-dicarboxylic Anhydride Derivatives Using the Grubbs Third Generation Catalyst

DOI：10.1007/s10118-017-1873-1

摘要

Abstract

关键词

Keywords

references