How Temperatures Affect the Number of Dislocations in Polymer Single Crystals

Xiao Liu; Qian-shi Wei; Li-guo Chai; Jian-jun Zhou; Hong Huo; Da-dong Yan; Shou-ke Yan; Jun Xu; Lin Li

doi:10.1007/s10118-017-1872-2

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How Temperatures Affect the Number of Dislocations in Polymer Single Crystals

PAPERS | Updated：2021-02-18

- How Temperatures Affect the Number of Dislocations in Polymer Single Crystals
- Chinese Journal of Polymer Science Vol. 35, Issue 1, Pages: 78-86(2017)
- Affiliations：
  
  a.Beijing Key Laboratory of Energy Conversion and Storage Materials, College of Chemistry, Beijing Normal University, Beijing 100875, China
  b.Department of Physics, Beijing Normal University, Beijing 100875, China
  c.State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
  d.Advanced Materials Laboratory, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China
- Author bio：
  
  Jian-jun Zhou, E-mail:pla_zjj@bnu.edu.cn
  Lin Li, E-mail:lilinll@bnu.edu.cn
- Funds：
- DOI：10.1007/s10118-017-1872-2
  CLC：
- Received：20 June 2016，
  
  Revised：2016-8-5，
  
  Accepted：15 August 2016，
  
  Published：2017-01
- Accepted：
Scan QR Code
Xiao Liu, Qian-shi Wei, Li-guo Chai, et al. How Temperatures Affect the Number of Dislocations in Polymer Single Crystals[J]. Chinese Journal of Polymer Science, 2017, 35(1): 78-86.
DOI：

Xiao Liu, Qian-shi Wei, Li-guo Chai, et al. How Temperatures Affect the Number of Dislocations in Polymer Single Crystals[J]. Chinese Journal of Polymer Science, 2017, 35(1): 78-86. DOI： 10.1007/s10118-017-1872-2.

摘要

Abstract

The influence of crystallization temperature (

) on the number of spiral growths on poly(butylene succinate) (PBS) single crystals

obtained by self-seeding method

was systematically studied. The studies show that the statistical average number of spiral growths formed on the PBS single crystals decays exponentially with respect to the

. Inspired by BCF (Bruton

Cabrera and Frank) theory and L-H (Lauritzen and Hoffman) theory

a thermodynamic model has been proposed

in which the origin of spiral growth was treated as a nucleation process. The model suggests that the nucleation rate of spiral growth depends on the inverse square of super-cooling degree

which predicted the density of spiral growth formed on lamellae

and was consistent with the experiments very well.

关键词

Keywords

references

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