Bisperylene Bisimide Based Conjugated Polymer as Electron Acceptor for Polymer-Polymer Solar Cellsh

Fan Yang; Cheng Li; Gui-tao Feng; Xu-dong Jiang; An-dong Zhang; Wei-wei Li

doi:10.1007/s10118-017-1870-4

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Bisperylene Bisimide Based Conjugated Polymer as Electron Acceptor for Polymer-Polymer Solar Cellsh

Papers | Updated：2021-02-18

- Bisperylene Bisimide Based Conjugated Polymer as Electron Acceptor for Polymer-Polymer Solar Cellsh
- Chinese Journal of Polymer Science Vol. 35, Issue 2, Pages: 239-248(2017)
- Affiliations：
  
  Beijing National Laboratory for Molecular Sciences, Chinese Academy of Sciences Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
- Author bio：
  
  Cheng Li (李诚), E-mail:licheng1987@iccas.ac.cn
  Wei-wei Li (李韦伟), E-mail:liweiwei@iccas.ac.cn
- Funds：
- DOI：10.1007/s10118-017-1870-4
  CLC：
- Received：18 August 2016，
  
  Revised：2016-9-7，
  
  Accepted：12 September 2016，
  
  Published：2017-02
- Accepted：
Scan QR Code
Fan Yang, Cheng Li, Gui-tao Feng, et al. Bisperylene Bisimide Based Conjugated Polymer as Electron Acceptor for Polymer-Polymer Solar Cellsh[J]. Chinese Journal of Polymer Science, 2017, 35(2): 239-248.
DOI：

Fan Yang, Cheng Li, Gui-tao Feng, et al. Bisperylene Bisimide Based Conjugated Polymer as Electron Acceptor for Polymer-Polymer Solar Cellsh[J]. Chinese Journal of Polymer Science, 2017, 35(2): 239-248. DOI： 10.1007/s10118-017-1870-4.

摘要

Abstract

Perylene bisimide (PBI) unit has been widely used to design conjugated materials

which can be used as electron acceptor in organic solar cells due to its strong electron-deficient ability. In this work

a conjugated polymer based on PBI dimer as monomer was designed

synthesized

and compared to the conjugated polymer containing single PBI as repeating units. The two conjugated polymers were found to have similar molecular weight

absorption spectra and energy levels. Density functional theory calculation revealed that the PBI dimer-based polymer exhibited highly twisted conjugated backbone due to the large dihedral angle between the two PBI units. The PBI-based polymers as electron acceptor were applied into polymer-polymer solar cells

in which PBI dimer-based polymer solar cells were found to show a high short circuit current density (

=11.2 mA·cm

-2

) and a high power conversion efficiency (PCE) of 4.5%. In comparison

the solar cells based on PBI-based polymer acceptor only provided a

of 7.2 mA·cm

-2

and PCE of 2.5%. The significantly enhanced PCE in PBI dimer-based solar cells was attributed to the mixed phase in blended thin films

as revealed by atom force microscopy. This study demonstrates that PBI dimer can be used to design polymer acceptors for high performance polymer-polymer solar cells.

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references

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