Enhancing Dielectric and Mechanical Behaviors of Hybrid Polymer Nanocomposites Based on Polystyrene, Polyaniline and Carbon Nanotubes Coated with Polyaniline

Tanveer ul Haq Zia; Ahmad Nawaz Khan; Majid Hussain; Ibrar Hassan; Iftikhar Hussain Gul

doi:10.1007/s10118-016-1867-4

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Enhancing Dielectric and Mechanical Behaviors of Hybrid Polymer Nanocomposites Based on Polystyrene, Polyaniline and Carbon Nanotubes Coated with Polyaniline

Papers | Updated：2021-05-12

- Enhancing Dielectric and Mechanical Behaviors of Hybrid Polymer Nanocomposites Based on Polystyrene, Polyaniline and Carbon Nanotubes Coated with Polyaniline
- Chinese Journal of Polymer Science Vol. 34, Issue 12, Pages: 1500-1509(2016)
- Affiliations：
  
  Department of Materials Engineering, School of Chemical and Materials Engineering, National University of Sciences and Technology, H-12, Islamabad, Pakistan
- Author bio：
  
  Ahmad Nawaz Khan, E-mail:ahmad.nawaz@scme.nust.edu.pk
- Funds：
- DOI：10.1007/s10118-016-1867-4
  CLC：
- Received：28 June 2016，
  
  Revised：2016-8-12，
  
  Accepted：15 September 2016，
  
  Published：2016-12
- Accepted：
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Tanveer ul Haq Zia, Ahmad Nawaz Khan, Majid Hussain, et al. Enhancing Dielectric and Mechanical Behaviors of Hybrid Polymer Nanocomposites Based on Polystyrene, Polyaniline and Carbon Nanotubes Coated with Polyaniline[J]. Chinese Journal of Polymer Science, 2016, 34(12): 1500-1509.
DOI：

Tanveer ul Haq Zia, Ahmad Nawaz Khan, Majid Hussain, et al. Enhancing Dielectric and Mechanical Behaviors of Hybrid Polymer Nanocomposites Based on Polystyrene, Polyaniline and Carbon Nanotubes Coated with Polyaniline[J]. Chinese Journal of Polymer Science, 2016, 34(12): 1500-1509. DOI： 10.1007/s10118-016-1867-4.

摘要

Abstract

The dielectric and mechanical properties of hybrid polymer nanocomposites of polystyrene/polyaniline/carbon nanotubes coated with polyaniline (

CNTs) have been investigated using impedance analyzer and extensometer. The blends of PS/PANI formed the heterogeneous phase separated morphology in which

CNTs are dispersed uniformly. The incorporation of a small amount of

CNTs into the blend of PS/PANI has remarkably increased the dielectric properties. Similarly

the AC conductivity of PS/PANI is also increased five orders of magnitude from 1.6×10

-10

to 2.0×10

-5

S·cm

-1

in the hybrid nanocomposites. Such behavior of hybrid nanocomposites is owing to the interfacial polarization occurring due to the presence of multicomponent domains with varying conductivity character of the phases from insulative PS to poor conductor PANI to highly conductive CNTs. Meanwhile

the tensile modulus and tensile strength are also enhanced significantly up to 55% and 160%

respectively

without much loss of ductility for three phase hybrid nanocomposites as compared to the neat PS. Thereby

the hybrid nanocomposites of PS/PANI/

CNTs become stiffer

stronger and tougher as compared to the neat systems.

关键词

Keywords

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