Multiple Endothermic Peaks Resulted from Different Crystal Structures in an Isomorphous Copolymer Poly (3-hydroxybutyrate-<italic style="font-style: italic">co</italic>-3-hydroxyvalerate)

You Lv; Hao Zhu; Min-fang An; Hao-jun Xu; Li Zhang; Zong-bao Wang

doi:10.1007/s10118-016-1866-5

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Multiple Endothermic Peaks Resulted from Different Crystal Structures in an Isomorphous Copolymer Poly (3-hydroxybutyrate-co-3-hydroxyvalerate)

Papers | Updated：2021-05-12

- Multiple Endothermic Peaks Resulted from Different Crystal Structures in an Isomorphous Copolymer Poly (3-hydroxybutyrate-co-3-hydroxyvalerate)
- Chinese Journal of Polymer Science Vol. 34, Issue 12, Pages: 1510-1522(2016)
- Affiliations：
  
  Ningbo Key Laboratory of Specialty Polymers, Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, China
- Author bio：
  
  Zong-bao Wang(王宗宝), E-mail:wangzongbao@nbu.edu.cn
- Funds：
- DOI：10.1007/s10118-016-1866-5
  CLC：
- Received：05 May 2016，
  
  Revised：2016-5-31，
  
  Accepted：06 June 2016，
  
  Published：2016-12
- Accepted：
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You Lv, Hao Zhu, Min-fang An, et al. Multiple Endothermic Peaks Resulted from Different Crystal Structures in an Isomorphous Copolymer Poly (3-hydroxybutyrate-co-3-hydroxyvalerate)[J]. Chinese Journal of Polymer Science, 2016, 34(12): 1510-1522. DOI: 10.1007/s10118-016-1866-5.
DOI：

You Lv, Hao Zhu, Min-fang An, et al. Multiple Endothermic Peaks Resulted from Different Crystal Structures in an Isomorphous Copolymer Poly (3-hydroxybutyrate-co-3-hydroxyvalerate)[J]. Chinese Journal of Polymer Science, 2016, 34(12): 1510-1522. DOI: 10.1007/s10118-016-1866-5. DOI：

摘要

Abstract

The multiple endothermic peaks of poly (3-hydroxybutyrate-

-3-hydroxyvalerate) (P (HB-

-HV)) in differential scanning calorimetry (DSC) results

as one representative phenomenon of polymer with unique cocrystallization behavior

were generally considered as the results of melting/recrystallization. In this study

wide angle X-ray diffraction (WAXD) and small angle X-ray scattering (SAXS) experiments were conducted to analyze the phenomena of multiple endothermic peaks in DSC results. The results of these analyses indicated that the multiple endotherms were mainly caused by different lamellae structures. For P (HB-

-HV) with lower HV content

it was comprised of two structures of HV total exclusion and HV partial inclusion in the crystal lamellae. For P (HB-

-HV) with higher HV content

it was also comprised of two structures of HV total inclusion and HV partial inclusion in the crystal lamellae. However

only structure with HV partial inclusion in the crystal lamellae remained existing after first melting peak for all samples.

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references

P.J. Flory . . Trans. Faraday Soc. , 1955 . 51 848 DOI: 10.1039/tf9555100848 http://doi.org/10.1039/tf9555100848 .

J.O. William , H.M. Robert , L.B. Terry . . Macromolecules , 1991 . 24 6435 DOI: 10.1021/ma00024a010 http://doi.org/10.1021/ma00024a010 .

I.C. Sanchez , R.K. Eby . . Macromolecules , 1973 . 77 353 http://onlinelibrary.wiley.com/resolve/reference/ADS?id=1975MaMol...8..638S http://onlinelibrary.wiley.com/resolve/reference/ADS?id=1975MaMol...8..638S , .

I.C. Sanchez , R.K. Eby . . Macromolecules , 1975 . 8 638 DOI: 10.1021/ma60047a012 http://doi.org/10.1021/ma60047a012 .

Y. Naoko , S. Miwa , Y. Yoshio . . Macromolecules , 2001 . 34 8953 DOI: 10.1021/ma0113071 http://doi.org/10.1021/ma0113071 .

G. Allerga , I.W. Bassi . . Adv. Polym. Sci. , 1969 . 6 549 http://dx.doi.org/10.1007/BFb0051143 http://dx.doi.org/10.1007/BFb0051143 , .

Y. Naoko , A. Akeshi , I. Yoshio . . Macromolecules , 2004 . 37 3770 DOI: 10.1021/ma049858p http://doi.org/10.1021/ma049858p .

K. Naoko , I. Yoshio , Y. Yasuhiko , C. Riichirô , D. Yoshiharu . . Macromolecules , 1990 . 23 1313 DOI: 10.1021/ma00207a015 http://doi.org/10.1021/ma00207a015 .

H.G. Schlegel , G. Gottschalk , R.V. Bastha . . Nature , 1961 . 191 463 DOI: 10.1038/191463a0 http://doi.org/10.1038/191463a0 .

D.G. Lundgren , R. Alper , C. Schanaitman , R.H. Marchessault . . J. Bacteriol. , 1965 . 89 245 http://onlinelibrary.wiley.com/resolve/reference/ADS?id=1975MaMol...8..638S http://onlinelibrary.wiley.com/resolve/reference/ADS?id=1975MaMol...8..638S , .

Holmes, P.A., Wright, L.F. and Collins, S.H., 1982, Eur. Pat. Appl, 0052459

Holmes, P.A., Wright, L.F. and Collins, S.H., 1983, Eur. Pat. Appl, 0069497

J. Cornibert , R.H. Marchessault . . J. Mol. Biol. , 1972 . 71 735 DOI: 10.1016/S0022-2836(72)80035-4 http://doi.org/10.1016/S0022-2836(72)80035-4 .

M. Yokouchi , Y. Chatani , H. Tadokoro , K. Teranishi , H. Tani . . Polymer , 1973 . 14 267 DOI: 10.1016/0032-3861(73)90087-6 http://doi.org/10.1016/0032-3861(73)90087-6 .

M. Yokouchi , Y. Chatani , H. Tadokoro , H. Tani . . Polym. J. , 1974 . 6 248 DOI: 10.1295/polymj.6.248 http://doi.org/10.1295/polymj.6.248 .

H. Mitomo , N. Morishita , Y. Doi . . Macromolecules , 1993 . 26 5809 DOI: 10.1021/ma00073a041 http://doi.org/10.1021/ma00073a041 .

S. Yamada , L. Wang , N. Asakawa , N. Yoshie , Y. Inoue . . Macromolecules , 2001 . 34 4659 DOI: 10.1021/ma002120x http://doi.org/10.1021/ma002120x .

K. Naoko , Y. Yasuhiko , I. Yoshio , R. Chûjô , D. Yoshiharu . . Macromolecules , 1989 . 22 1676 DOI: 10.1021/ma00194a030 http://doi.org/10.1021/ma00194a030 .

Y. Naoko , M. Hiroyuki , S. Hidenori , I. Yoshio . . Macromolecules , 1995 . 28 6516 DOI: 10.1021/ma00123a018 http://doi.org/10.1021/ma00123a018 .

H. Mitomo , P.J. Barham , A. Keller . . Polym. J. , 1987 . 19 1241 DOI: 10.1295/polymj.19.1241 http://doi.org/10.1295/polymj.19.1241 .

H. Mitomo , P.J. Barham , A. Keller . . Seni-Gakkaishi , 1986 . 42 T589 DOI: 10.2115/fiber.42.11_T589 http://doi.org/10.2115/fiber.42.11_T589 .

S.J. Organ , P.J. Barham . . J. Mater. Sci. , 1991 . 26 1368 DOI: 10.1007/BF00544479 http://doi.org/10.1007/BF00544479 .

R.J. Rule , J.J. Liggat . . Polymer , 1995 . 36 3831 DOI: 10.1016/0032-3861(95)99777-R http://doi.org/10.1016/0032-3861(95)99777-R .

P.A. Holmes . . Phys. Technol. , 1985 . 16 32 DOI: 10.1088/0305-4624/16/1/305 http://doi.org/10.1088/0305-4624/16/1/305 .

Y. Doi , A. Tamaki , M. Kunioka , K. Soga . . Appl. Microbiol. Biotechnol. , 1988 . 28 330 DOI: 10.1007/BF00268190 http://doi.org/10.1007/BF00268190 .

C.G. Vonk , G. Kortleve , Z.Z. Koll . . Polymer , 1967 . 220 19 DOI: 10.1007/BF02086052 http://doi.org/10.1007/BF02086052 .

C.G. Vonk . . J. Appl. Cryst. , 1971 . 4 340 DOI: 10.1107/S0021889871007179 http://doi.org/10.1107/S0021889871007179 .

G.R. Strobl , M.J. Schneider . . J. Polym. Sci., Polym. Phys. Ed. , 1980 . 18 1343 DOI: 10.1002/pol.1980.180180614 http://doi.org/10.1002/pol.1980.180180614 .

Y. Inoue , N. Kamiya , Y. Yamamoto , R. Chûjô , D. Yoshiharu . . Macromolecules , 1989 . 22 3800 DOI: 10.1021/ma00199a051 http://doi.org/10.1021/ma00199a051 .

M.S. Cuesta , J.M. Salazar , P.A. Barker , P.J. Barham . . J. Mater. Sci. , 1992 . 27 5335 DOI: 10.1007/BF02403840 http://doi.org/10.1007/BF02403840 .

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Multiple Endothermic Peaks Resulted from Different Crystal Structures in an Isomorphous Copolymer Poly (3-hydroxybutyrate-co-3-hydroxyvalerate)

DOI：10.1007/s10118-016-1866-5

摘要

Abstract

关键词

Keywords

references