AO-resistant Properties of Polyimide Fibers Containing Phosphorous Groups in Main Chains

Yong Zhao; Guo-min Li; Xue-min Dai; Fang-fang Liu; Zhi-xin Dong; Xue-peng Qiu

doi:10.1007/s10118-016-1864-7

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AO-resistant Properties of Polyimide Fibers Containing Phosphorous Groups in Main Chains

Papers | Updated：2021-05-12

- AO-resistant Properties of Polyimide Fibers Containing Phosphorous Groups in Main Chains
- Chinese Journal of Polymer Science Vol. 34, Issue 12, Pages: 1469-1478(2016)
- Affiliations：
  
  a.Polymer Composites Engineering Laboratory, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
  b.University of Chinese Academy of Sciences, Beijing 100049, China
- Author bio：
  
  Zhi-xin Dong (董志鑫), E-mail:zxdong@ciac.ac.cn
  Xue-peng Qiu (邱雪鹏), E-mail:xp_q@ciac.ac.cn
- Funds：
- DOI：10.1007/s10118-016-1864-7
  CLC：
- Received：23 June 2016，
  
  Revised：2016-8-29，
  
  Accepted：30 August 2016，
  
  Published：2016-12
- Accepted：
Scan QR Code
Yong Zhao, Guo-min Li, Xue-min Dai, et al. AO-resistant Properties of Polyimide Fibers Containing Phosphorous Groups in Main Chains[J]. Chinese Journal of Polymer Science, 2016, 34(12): 1469-1478.
DOI：

Yong Zhao, Guo-min Li, Xue-min Dai, et al. AO-resistant Properties of Polyimide Fibers Containing Phosphorous Groups in Main Chains[J]. Chinese Journal of Polymer Science, 2016, 34(12): 1469-1478. DOI： 10.1007/s10118-016-1864-7.

摘要

Abstract

A series of polyimide fibers containing phosphorus element derived from (3-aminophenyl) methyl phosphine oxide (DAMPO) diamine was exposed to an artificial atomic oxygen environment which simulated the space environment in low earth orbit (LEO). The mass loss

surface morphology

chemical composition

and mechanical properties of the fibers before and after atomic oxygen (AO) exposure were compared in detail with a blank sample. Results showed that the phosphor-containing fibers demonstrated lower mass change and less tensile strength reduction. SEM results showed that the fibers with phosphorous element had relatively dense surface after AO exposure. Meanwhile

XPS results indicated that a passivated phosphate layer

which could protect the following under-layer from attacking by AO

was formed on the surface of the fibers. These results indicated that the incorporation of diamine (DAMPO) into the main chains could protect the fibers for avoiding further erosion from AO exposure. Hence

the phosphor-containing PI fibers exhibits potential application in space fields.

关键词

Keywords

references

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