Poly (vinylidene fluoride) Separators with Dual-asymmetric Structure for High-performance Lithium Ion Batteries

Hong-qing Liang; Ling-shu Wan; Zhi-kang Xu

doi:10.1007/s10118-016-1860-y

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Poly (vinylidene fluoride) Separators with Dual-asymmetric Structure for High-performance Lithium Ion Batteries

Papers | Updated：2021-05-12

- Poly (vinylidene fluoride) Separators with Dual-asymmetric Structure for High-performance Lithium Ion Batteries
- Chinese Journal of Polymer Science Vol. 34, Issue 12, Pages: 1423-1435(2016)
- Affiliations：
  
  a.MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China
  b.Key Laboratory of Adsorption and Separation Materials & Technologies of Zhejiang Province, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China
- Author bio：
  
  Zhi-kang Xu (徐志康), E-mail:xuzk@zju.edu.cn
- Funds：
- DOI：10.1007/s10118-016-1860-y
  CLC：
- Received：25 July 2016，
  
  Revised：2016-9-13，
  
  Accepted：13 September 2016，
  
  Published：2016-12
- Accepted：
Scan QR Code
Hong-qing Liang, Ling-shu Wan, Zhi-kang Xu. Poly (vinylidene fluoride) Separators with Dual-asymmetric Structure for High-performance Lithium Ion Batteries[J]. Chinese Journal of Polymer Science, 2016, 34(12): 1423-1435.
DOI：

Hong-qing Liang, Ling-shu Wan, Zhi-kang Xu. Poly (vinylidene fluoride) Separators with Dual-asymmetric Structure for High-performance Lithium Ion Batteries[J]. Chinese Journal of Polymer Science, 2016, 34(12): 1423-1435. DOI： 10.1007/s10118-016-1860-y.

摘要

Abstract

Dual-asymmetric poly (vinylidene fluoride) (PVDF) separators have been fabricated by thermally induced phase separation with dimethyl sulfone (DMSO2) and glycerol as mixed diluents. The separators have a porous bulk with large interconnected pores (~1.0 μm) and two surfaces with small pores (~30 nm). This dual-asymmetric porous structure endows the separators with higher electrolyte uptake amount and rapider uptake rate

as well as better electrolyte retention ability than the commercialized Celgard 2400. The separators even maintain their dimensional stability up to 160℃

at which temperature the surface pores close up

leading to a dramatic decrease of air permeability. The electrolyte filled separators also show high ion conductivity (1.72 mS·cm

-1

) at room temperature. Lithium iron phosphate (LiFePO

)/lithium (Li) cells using these separators display superior discharge capacity and better rate performance as compared with those from the commercialized ones. The results provide new insight into the design and development of separators for high-performance lithium ion batteries with enhanced safety.

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references

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