The Doubly Thermo-responsive Triblock Copolymer Nanoparticles Prepared through Seeded RAFT Polymerization

Quan-long Li; Lei Li; Hong-song Wang; Rui Wang; Wei Wang; Yong-jing Jiang; Qian Tian; Jia-ping Liu

doi:10.1007/s10118-016-1859-4

Your Location：

Home >

Browse articles >

The Doubly Thermo-responsive Triblock Copolymer Nanoparticles Prepared through Seeded RAFT Polymerization

PAPERS | Updated：2021-02-18

- The Doubly Thermo-responsive Triblock Copolymer Nanoparticles Prepared through Seeded RAFT Polymerization
- Chinese Journal of Polymer Science Vol. 35, Issue 1, Pages: 66-77(2017)
- Affiliations：
  
  a.State Key Laboratory of High Performance Civil Engineering Materials, Jiangsu Research Institute of Building Science, Nanjing 210008, China
  b.Jiangsu Sobute New Materials Co., Ltd., Nanjing 211103, China
  c.College of Materials Science and Engineering, Southeast University, Nanjing 211189, China
- Author bio：
  
  Qian Tian, E-mail:tianqian@cnjsjk.cn
  Jia-ping Liu, E-mail:liujiaping@cnjsjk.cn
- Funds：
- DOI：10.1007/s10118-016-1859-4
  CLC：
- Received：05 June 2016，
  
  Revised：2016-7-14，
  
  Accepted：15 July 2016，
  
  Published：2017-01
- Accepted：
Scan QR Code
Quan-long Li, Lei Li, Hong-song Wang, et al. The Doubly Thermo-responsive Triblock Copolymer Nanoparticles Prepared through Seeded RAFT Polymerization[J]. Chinese Journal of Polymer Science, 2017, 35(1): 66-77.
DOI：

Quan-long Li, Lei Li, Hong-song Wang, et al. The Doubly Thermo-responsive Triblock Copolymer Nanoparticles Prepared through Seeded RAFT Polymerization[J]. Chinese Journal of Polymer Science, 2017, 35(1): 66-77. DOI： 10.1007/s10118-016-1859-4.

摘要

Abstract

The doubly thermo-responsive triblock copolymer nanoparticles of polystyrene-block-poly(

-isopropylacrylamide)-block-poly[

-(dimethylamino) ethyl methacrylate] (PS-

-PNIPAM-

-PDMAEMA) are successfully prepared through the seeded RAFT polymerization

in situ

by using the PS-

-PNIPAM-TTC diblock copolymer nanoparticles as the seed. The seeded RAFT polymerization undergoes a pseudo-first-order kinetics procedure

and the molecular weight increases with the monomer conversion linearly. The hydrodynamic diameter (

) of the triblock copolymer nanoparticles increases with the extension of the PDMAEMA block. In addition

the double thermo-response behavior of the PS-

-PNIPAM-

-PDMAEMA nanoparticles is detected by turbidity analysis

temperature-dependent

H-NMR analysis

and DLS analysis. The seeded RAFT polymerization is believed as a valid method to prepare triblock copolymer nanoparticles containing two thermo-responsive blocks.

关键词

Keywords

references

D. Roy, , W.L.A. Brooks, , B.S. Sumerlin, . . Chem. Soc. Rev. , 2013 . 42 7214 DOI: 10.1039/c3cs35499g http://doi.org/10.1039/c3cs35499g .

V. Aseyev, , H. Tenhu, , F.M. Winnik, . . Adv. Polym. Sci. , 2011 . 242 29 .

Q. Li, , C. Gao, , S. Li, , F. Huo, , W. Zhang, . . Polym. Chem. , 2014 . 5 2961 DOI: 10.1039/c3py01699d http://doi.org/10.1039/c3py01699d .

Q. Li, , F. Huo, , Y. Cui, , C. Gao, , S. Li, , W.J. Zhang, , Sci. Polym. . . Part A:Polym. Chem. , 2014 . 52 2266 DOI: 10.1002/pola.v52.16 http://doi.org/10.1002/pola.v52.16 .

Q. Li, , X. He, , Y. Cui, , P. Shi, , S. Li, , W. Zhang, . . Polym. Chem. , 2015 . 6 70 DOI: 10.1039/C4PY00998C http://doi.org/10.1039/C4PY00998C .

Y. Su, , Q. Li, , S. Li, , M. Dan, , F. Huo, , W. Zhang, . . Polymer , 2014 . 55 1955 DOI: 10.1016/j.polymer.2014.02.060 http://doi.org/10.1016/j.polymer.2014.02.060 .

L.T.T. Trinh, , H.M.L. Lambermont-Thijs, , U.S. Schubert, , R. Hoogenboom, , A. Kjøniksen, . . Macromolecules , 2012 . 45 4337 DOI: 10.1021/ma300570j http://doi.org/10.1021/ma300570j .

C. Pietsch, , U. Mansfeld, , C. Guerrero-Sanchez, , S. Hoeppener, , A. Vollrath, , M. Wagner, , R. Hoogenboom, , S. Saubern, , S.H. Thang, , C.R. Becer, , J. Chiefari, , U.S. Schubert, . . Macromolecules , 2012 . 45 9292 DOI: 10.1021/ma301867h http://doi.org/10.1021/ma301867h .

H. Tian, , J. Yan, , D. Wang, , C. Gu, , Y. You, , X. Chen, . . Macromol. Rapid Commun. , 2011 . 32 660 DOI: 10.1002/marc.v32.8 http://doi.org/10.1002/marc.v32.8 .

J. Weiss, , A. Laschewsky, . . Macromolecules , 2012 . 45 4158 DOI: 10.1021/ma300285y http://doi.org/10.1021/ma300285y .

J. Xu, , S. Luo, , W. Shi, , S. Liu, . . Langmuir , 2006 . 22 989 DOI: 10.1021/la0522707 http://doi.org/10.1021/la0522707 .

F.D. Jochum, , P.J. Roth, , D. Kessler, , P. Theato, . . Biomacromolecules , 2010 . 11 2432 DOI: 10.1021/bm1006085 http://doi.org/10.1021/bm1006085 .

S. Reinicke, , J. Schmelz, , A. Lapp, , M. Karg, , T. Hellweg, , H. Schmalz, . . Soft Matter , 2009 . 5 2648 .

F. Wang, , J. Du, . . Chem. Commun. , 2015 . 51 11198 DOI: 10.1039/C5CC02641E http://doi.org/10.1039/C5CC02641E .

J. Kim, , K. Suh, . . J. Indust. Eng. Chem. , 2008 . 14 1 DOI: 10.1016/j.jiec.2007.06.001 http://doi.org/10.1016/j.jiec.2007.06.001 .

T. Fujibayashi, , M. Okubo, . . Langmuir , 2007 . 23 7958 DOI: 10.1021/la7007842 http://doi.org/10.1021/la7007842 .

C. Tang, , C. Zhang, , J. Liu, , X. Qu, , J. Li, , Z. Yang, . . Macromolecules , 2010 . 43 5114 DOI: 10.1021/ma100437t http://doi.org/10.1021/ma100437t .

O.H. Gonçalves, , J.M. Asua, , Araújo, P.H.H. de , R.A.F. Machado, . . Macromolecules , 2008 . 41 6960 DOI: 10.1021/ma800693m http://doi.org/10.1021/ma800693m .

Q. Li, , L. Li, , W. Wang, , X. Zhang, , S. Li, , Q. Tian, , J. Liu, . . RSC Adv. , 2016 . 6 45305 DOI: 10.1039/C6RA08725F http://doi.org/10.1039/C6RA08725F .

G. Moad, , Y.K. Chong, , A. Postma, , E. Rizzardo, , S.H. Thang, . . Polymer , 2005 . 46 8458 DOI: 10.1016/j.polymer.2004.12.061 http://doi.org/10.1016/j.polymer.2004.12.061 .

A.P. Narrainen, , S. Pascual, , D., J. Polym. Sci. Haddleton, . . Part A:Polym. Chem. , 2002 . 40 439 DOI: 10.1002/(ISSN)1099-0518 http://doi.org/10.1002/(ISSN)1099-0518 .

Brouwer, H. De , M.A.J. Schellekens, , B. Klumperman, , M.J. Monteiro, , A.L., J. Polym. Sci. German, . . Part A:Polym. Chem. , 2000 . 38 3596 DOI: 10.1002/(ISSN)1099-0518 http://doi.org/10.1002/(ISSN)1099-0518 .

F. Huo, , S. Li, , Q. Li, , Y. Qu, , W. Zhang, . . Macromolecules , 2014 . 47 2340 DOI: 10.1021/ma5002386 http://doi.org/10.1021/ma5002386 .

A.B. Lowe, , C.L. McCormick, . . Prog. Polym. Sci. , 2007 . 32 283 DOI: 10.1016/j.progpolymsci.2006.11.003 http://doi.org/10.1016/j.progpolymsci.2006.11.003 .

B. Fang, , A. Walther, , A. Wolf, , Y. Xu, , J. Yuan, , A.H.E. Müller, . . Angew. Chem. Int. Ed. , 2009 . 48 2877 DOI: 10.1002/anie.200806051 http://doi.org/10.1002/anie.200806051 .

S. Li, , X. He, , Q. Li, , P. Shi, , W. Zhang, . . ACS Macro Lett. , 2014 . 3 916 DOI: 10.1021/mz500466x http://doi.org/10.1021/mz500466x .

X. He, , Q. Li, , P. Shi, , Y. Cui, , S. Li, , W. Zhang, . . Polym. Chem. , 2014 . 5 7090 DOI: 10.1039/C4PY01077A http://doi.org/10.1039/C4PY01077A .

A.H. Gröschel, , F.H. Schacher, , H. Schmalz, , O.V. Borisov, , E.B. Zhulina, , A. Walther, , A.H.E. Müller, . . Nat. Commun. , 2014 . 3 710 .

A.H. Gröschel, , A. Walther, , T.I. Löbling, , J. Schmelz, , A. Hanisch, , H. Schmalz, , A.H.E. Müller, . . J. Am. Chem. Soc. , 2012 . 134 13850 DOI: 10.1021/ja305903u http://doi.org/10.1021/ja305903u .

Z. Li, , E. Kesselman, , Y. Talmon, , M.A. Hillmyer, , T.P. Lodge, . . Science , 2004 . 306 98 DOI: 10.1126/science.1103350 http://doi.org/10.1126/science.1103350 .

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

In Situ Synthesis of Block Copolymer Nano-assemblies by Polymerization-induced Self-assembly under Heterogeneous Condition

THERMO-RESPONSIVE BLOCK COPOLYMERS BASED ON LINEAR-TYPE POLY(ETHYLENE GLYCOL): TUNABLE LCST WITHIN THE PHYSIOLOGICAL RANGE

Topology-regulated Co-assembly of Single Chain Polymer Nanoparticles and Block Copolymers into Hierarchical Micelle@Vesicle Composite Structures

Accelerating Field-based Simulations of Block Copolymers by Exploring Symmetry of Chain Architectures

Special Topic: Chirality in Polymers

Related Author

Sheng-li Chen

Peng-fei Shi

Wang-qing Zhang

Guo-liang Yue

Qian-ling Cui

Yu-xi Zhang

Er-jian Wang

Fei-peng Wu

Related Institution

Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University

Key Laboratory of Functional Polymer Materials of the Ministry of Education, Institute of Polymer Chemistry, Nankai University

Graduate School of Chinese Academy of Sciences

Technical Institute of Physics and Chemistry, Chinese Academy of Sciences

School of Chemistry and Materials Science, Anhui Normal University

⁰