Synthesis of Star Polymeric Ionic Liquids and Use as the Stabilizers for High Internal Phase Emulsions

Qi-jing Chen; Ze-sheng An

doi:10.1007/s10118-016-1858-5

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Synthesis of Star Polymeric Ionic Liquids and Use as the Stabilizers for High Internal Phase Emulsions

PAPERS | Updated：2021-02-18

- Synthesis of Star Polymeric Ionic Liquids and Use as the Stabilizers for High Internal Phase Emulsions
- Chinese Journal of Polymer Science Vol. 35, Issue 1, Pages: 54-65(2017)
- Affiliations：
  
  Institute of Nanochemistry and Nanobiology, College of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China
- Author bio：
  
  Ze-sheng An, E-mail:an.zesheng@shu.edu.cn
- Funds：
- DOI：10.1007/s10118-016-1858-5
  CLC：
- Received：12 June 2016，
  
  Revised：2016-6-29，
  
  Accepted：30 June 2016，
  
  Published：2017-01
- Accepted：
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Qi-jing Chen, Ze-sheng An. Synthesis of Star Polymeric Ionic Liquids and Use as the Stabilizers for High Internal Phase Emulsions[J]. Chinese Journal of Polymer Science, 2017, 35(1): 54-65.
DOI：

Qi-jing Chen, Ze-sheng An. Synthesis of Star Polymeric Ionic Liquids and Use as the Stabilizers for High Internal Phase Emulsions[J]. Chinese Journal of Polymer Science, 2017, 35(1): 54-65. DOI： 10.1007/s10118-016-1858-5.

摘要

Abstract

A series of well-defined core cross-linked star (CCS) polymeric ionic liquids (PILs) were synthesized

via

a three-step approach. First

the styrenic imidazole-based CCS polymer (S-PVBnIm) was prepared by the RAFT-mediated heterogeneous polymerization in a water/ethanol solution

followed by the quaternization of S-PVBnIm with bromoalkanes and anion exchange. The CCS polymers were characterized by gel permeation chromatography (GPC)

nuclear magnetic resonance (NMR) spectroscopy

Fourier transform infrared spectroscopy (FTIR)

thermal gravimetric analysis (TGA)

and differential scanning calorimetry (DSC). The obtained CCS polymers were used as the effective emulsifiers for oil-in-water high internal phase emulsions (HIPEs). Multiple oils with different polarity including

-dodecane

undecanol

toluene and octanol were emulsified using 0.5 wt% S-PVBnIm aqueous solution under the acidic condition to form HIPEs with long-term stabilities. The excellent emulsification properties of CCS PILs were demonstrated by HIPE formation for a variety of oils. The properties of HIPEs in terms of emulsion type and oil droplet size were characterized by the confocal laser scanning microscopy (CLSM). The intriguing capability of CCS PILs to stabilize HIPEs of various oils holds great potentials for the practical applications.

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Keywords

references

N.R. Cameron, , D.C. Sherrington, . . Adv. Polym. Sci. , 1996 . 126 163 DOI: 10.1007/3-540-60484-7 http://doi.org/10.1007/3-540-60484-7 .

Y. Chen, , N. Ballard, , F. Gayet, , S.A.F. Bon, . . Chem. Commun. , 2012 . 48 1117 DOI: 10.1039/C2CC16670D http://doi.org/10.1039/C2CC16670D .

H. Zhang, , A.I. Cooper, . . Soft Matter , 2005 . 1 ( 2 ): 107 DOI: 10.1039/b502551f http://doi.org/10.1039/b502551f .

J.M. Williams, . . Langmuir , 1991 . 7 ( 7 ): 1370 DOI: 10.1021/la00055a014 http://doi.org/10.1021/la00055a014 .

A. Barbetta, , N.R. Cameron, . . Macromolecules , 2004 . 37 ( 9 ): 3202 DOI: 10.1021/ma035944y http://doi.org/10.1021/ma035944y .

N.R. Cameron, , A. Barbettaa, . . J. Mater. Chem. , 2000 . 10 ( 11 ): 2466 DOI: 10.1039/b003596n http://doi.org/10.1039/b003596n .

S. Fujii, , Y. Cai, , J.V.M. Weaver, , S.P. Armes, . . J. Am. Chem. Soc. , 2005 . 127 ( 20 ): 7304 DOI: 10.1021/ja050049a http://doi.org/10.1021/ja050049a .

D. Dupin, , S.P. Armes, , C. Connan, , P. Reeve, , S.M. Baxter, . . Langmuir , 2007 . 23 ( 13 ): 6903 DOI: 10.1021/la063170j http://doi.org/10.1021/la063170j .

A.J. Morse, , D. Dupin, , K.L. Thompson, , S.P. Armes, , K. Ouzineb, , P. Mills, , R. Swart, . . Langmuir , 2012 . 28 ( 32 ): 11733 DOI: 10.1021/la301936k http://doi.org/10.1021/la301936k .

I. Akartuna, , A.R. Studart, , E. Tervoort, , L.J. Gauckler, . . Adv. Mater. , 2008 . 20 ( 24 ): 4714 DOI: 10.1002/adma.v20:24 http://doi.org/10.1002/adma.v20:24 .

A. Menner, , V. Ikem, , M. Salgueiro, , M.S.P. Shafferb, , A. Bismarck, . . Chem. Commun. , 2007 . 41 4274 .

V.O. Ikem, , A. Menner, , A. Bismarck, . . Angew. Chem. Int. Ed. , 2008 . 47 ( 43 ): 8277 DOI: 10.1002/anie.v47:43 http://doi.org/10.1002/anie.v47:43 .

Z. Li, , T. Ming, , J. Wang, , T. Ngai, . . Angew. Chem. , 2009 . 48 ( 45 ): 8490 DOI: 10.1002/anie.v48:45 http://doi.org/10.1002/anie.v48:45 .

G. Sun, , Z. Li, , T. Ngai, . . Angew. Chem. , 2010 . 49 ( 12 ): 2163 DOI: 10.1002/anie.v49:12 http://doi.org/10.1002/anie.v49:12 .

H. Gao, . . Macromol. Rapid Commun. , 2012 . 33 ( 9 ): 722 DOI: 10.1002/marc.201200005 http://doi.org/10.1002/marc.201200005 .

A. Blencowe, , J. Tan, , T. Goh, , G.G. Qiao, . . Polymer , 2009 . 50 ( 1 ): 5 DOI: 10.1016/j.polymer.2008.09.049 http://doi.org/10.1016/j.polymer.2008.09.049 .

M. Zhang, , H. Liu, , W. Shao, , C. Ye, , Y. Zhao, . . Macromolecules , 2012 . 45 ( 23 ): 9312 DOI: 10.1021/ma301973v http://doi.org/10.1021/ma301973v .

S. Ito, , R. Goseki, , S. Senda, , A. Hirao, . . Macromolecules , 2012 . 45 ( 12 ): 4997 DOI: 10.1021/ma300699m http://doi.org/10.1021/ma300699m .

K. Fukae, , T. Terashima, , M. Sawamoto, . . Macromolecules , 2012 . 45 ( 8 ): 3377 DOI: 10.1021/ma300266k http://doi.org/10.1021/ma300266k .

H. Zhang, , J. He, , C. Zhang, , Z. Ju, , J. Li, , Y. Yang, . . Macromolecules , 2012 . 45 ( 2 ): 828 DOI: 10.1021/ma2024039 http://doi.org/10.1021/ma2024039 .

Z. Dong, , X. Liu, , H. Liu, , Y. Li, . . Macromolecules , 2010 . 43 ( 19 ): 7985 DOI: 10.1021/ma1014275 http://doi.org/10.1021/ma1014275 .

X. Jiang, , Y. Chen, , F. Xi, . . Macromolecules , 2010 . 43 ( 17 ): 7056 DOI: 10.1021/ma101460n http://doi.org/10.1021/ma101460n .

M. Hu, , Y. Shen, , L. Zhang, , L. Qiu, . . Biomacromolecules , 2016 . 17 ( 3 ): 1026 DOI: 10.1021/acs.biomac.5b01676 http://doi.org/10.1021/acs.biomac.5b01676 .

Y. Li, , H. Yu, , Y. Qian, , J. Hu, , S. Liu, . . Adv. Mater. , 2014 . 26 ( 39 ): 6734 DOI: 10.1002/adma.v26.39 http://doi.org/10.1002/adma.v26.39 .

T. Liu, , Y. Zhang, , S. Liu, . . Chinese J. Polym. Sci. , 2013 . 31 ( 6 ): 924 DOI: 10.1007/s10118-013-1281-0 http://doi.org/10.1007/s10118-013-1281-0 .

W. Cao, , J. Zhou, , Y. Wang, , L. Zhu, . . Biomacromolecules , 2010 . 11 ( 12 ): 3680 DOI: 10.1021/bm101154r http://doi.org/10.1021/bm101154r .

S.J. Kim, , D.M. Ramsey, , C. Boyer, , T.P. Davis, , S.R. McAlpine, . . ACS Med. Chem. Lett. , 2013 . 4 ( 10 ): 915 DOI: 10.1021/ml400082b http://doi.org/10.1021/ml400082b .

J.M. Ren, , Q. Fu, , A. Blencowe, , G.G. Qiao, . . ACS Macro Lett. , 2012 . 1 ( 6 ): 681 DOI: 10.1021/mz300169m http://doi.org/10.1021/mz300169m .

J. Ferreira, , J. Syrett, , M. Whittaker, , D. Haddleton, , T.P. Davis, , C. Boyer, . . Polym. Chem. , 2011 . 2 ( 8 ): 1671 DOI: 10.1039/c1py00102g http://doi.org/10.1039/c1py00102g .

T.G. McKenzie, , E.H.H. Wong, , Q. Fu, , A. Sulistio, , D.E. Dunstan, , G.G. Qiao, . . ACS Macro Lett. , 2015 . 4 ( 9 ): 1012 DOI: 10.1021/acsmacrolett.5b00530 http://doi.org/10.1021/acsmacrolett.5b00530 .

Q. Qiu, , G. Liu, , Z. An, . . Chem. Commun. , 2011 . 47 ( 47 ): 12685 DOI: 10.1039/c1cc15679a http://doi.org/10.1039/c1cc15679a .

C. Zhang, , M. Miao, , X. Cao, , Z. An, . . Polym. Chem. , 2012 . 3 ( 9 ): 2656 DOI: 10.1039/c2py20442h http://doi.org/10.1039/c2py20442h .

X. Shi, , W. Zhou, , Q. Qiu, , Z. An, . . Chem. Commun. , 2012 . 48 ( 59 ): 7389 DOI: 10.1039/c2cc33812b http://doi.org/10.1039/c2cc33812b .

X. Shi, , M. Miao, , Z. An, . . Polym. Chem. , 2013 . 4 ( 6 ): 1950 DOI: 10.1039/c3py21120g http://doi.org/10.1039/c3py21120g .

X. Cao, , C. Zhang, , S. Wu, , Z. An, . . Polym. Chem. , 2014 . 5 ( 14 ): 4277 DOI: 10.1039/c4py00135d http://doi.org/10.1039/c4py00135d .

L. Hou, , Q. Chen, , Z. An, , P. Wu, . . Soft Matter , 2016 . 12 ( 8 ): 2473 DOI: 10.1039/C5SM03054D http://doi.org/10.1039/C5SM03054D .

Q. Chen, , X. Cao, , H. Liu, , W. Zhou, , L. Qin, , Z. An, . . Polym. Chem. , 2013 . 4 ( 15 ): 4092 DOI: 10.1039/c3py00488k http://doi.org/10.1039/c3py00488k .

Q. Chen, , X. Cao, , Y. Xu, , Z. An, . . Macromol. Rapid Commun. , 2013 . 34 ( 19 ): 1507 DOI: 10.1002/marc.v34.19 http://doi.org/10.1002/marc.v34.19 .

Q. Chen, , Y. Xu, , X. Cao, , L. Qin, , Z. An, . . Polym. Chem. , 2014 . 5 ( 1 ): 175 DOI: 10.1039/C3PY00942D http://doi.org/10.1039/C3PY00942D .

Q. Chen, , X. Deng, , Z. An, . . Macromol. Rapid Commun. , 2014 . 35 ( 12 ): 1148 DOI: 10.1002/marc.201400085 http://doi.org/10.1002/marc.201400085 .

J.M. Lu, , F. Yan, , J. Texter, . . Prog. Polym. Sci. , 2009 . 34 ( 5 ): 431 DOI: 10.1016/j.progpolymsci.2008.12.001 http://doi.org/10.1016/j.progpolymsci.2008.12.001 .

D. Mecerreyes, . . Prog. Polym. Sci. , 2011 . 36 ( 12 ): 1629 DOI: 10.1016/j.progpolymsci.2011.05.007 http://doi.org/10.1016/j.progpolymsci.2011.05.007 .

M.D. Green, , J.H. Choi, , K.I. Winey, , T.E. Long, . . Macromolecules , 2012 . 45 ( 11 ): 4749 DOI: 10.1021/ma300185b http://doi.org/10.1021/ma300185b .

T. Seki, , J.D. Grunwaldt, , A. Baiker, . . J. Phys. Chem. B , 2009 . 113 ( 1 ): 114 DOI: 10.1021/jp800424d http://doi.org/10.1021/jp800424d .

R. Holomb, , A. Martinelli, , I. Albinsson, , J.C. Lassègues, , P. Johansson, , P. Jacobsson, . . J. Raman Spectrosc. , 2008 . 39 ( 7 ): 793 DOI: 10.1002/jrs.v39:7 http://doi.org/10.1002/jrs.v39:7 .

Y. Ye, , Y.A. Elabd, . . Polymer , 2011 . 52 ( 5 ): 1309 DOI: 10.1016/j.polymer.2011.01.031 http://doi.org/10.1016/j.polymer.2011.01.031 .

V. Jovanovski, , R. Marcilla, , D. Mecerreyes, . . Macromol. Rapid Commun. , 2010 . 31 ( 18 ): 1646 DOI: 10.1002/marc.201000215 http://doi.org/10.1002/marc.201000215 .

R.L. Weber, , Y. Ye, , S.M. Banik, , Y.A. Elabd, , M.A. Hickner, , M.K., J. Polym. Sci. Mahanthappa, . . Part B:Polym. Phys. , 2011 . 49 ( 18 ): 1287 DOI: 10.1002/polb.22319 http://doi.org/10.1002/polb.22319 .

A.T. Chowdhury, , S.T. Thynell, . . Thermochim. Acta , 2006 . 443 ( 2 ): 159 DOI: 10.1016/j.tca.2006.01.006 http://doi.org/10.1016/j.tca.2006.01.006 .

M.C. Kroon, , W. Buijs, , C.J. Peters, , G.J. Witkamp, . . Thermochim. Acta , 2007 . 465 ( 1-2 ): 40 DOI: 10.1016/j.tca.2007.09.003 http://doi.org/10.1016/j.tca.2007.09.003 .

H.I.S. Ohtani, , M. Kumai, . . Anal. Sci. , 2008 . 24 ( 10 ): 1335 DOI: 10.2116/analsci.24.1335 http://doi.org/10.2116/analsci.24.1335 .

A.B. McEwen, , H.L. Ngo, , K. LeCompte, , J.L. Goldman, . . J. Electrochem. Soc. , 1999 . 146 ( 5 ): 1687 DOI: 10.1149/1.1391827 http://doi.org/10.1149/1.1391827 .

C.P. Fredlake, , J.M. Crosthwaite, , D.G. Hert, , S.N.V.K. Aki, , J.F. Brennecke, . . J. Chem. Eng. Data , 2004 . 49 ( 4 ): 954 DOI: 10.1021/je034261a http://doi.org/10.1021/je034261a .

C. Liu, , S. Wang, , H. Zhou, , C. Gao, , W., J. Polym. Sci. Zhang, . . Part A:Polym. Chem. , 2016 . 54 ( 7 ): 945 DOI: 10.1002/pola.v54.7 http://doi.org/10.1002/pola.v54.7 .

X. Cao, , Z. An, . . Macromol. Rapid Commun. , 2015 . 36 ( 23 ): 2107 DOI: 10.1002/marc.201500440 http://doi.org/10.1002/marc.201500440 .

J.M. Ren, , T.G. Mckenzie, , Q. Fu, , E.H.H. Wong, , J. Xu, , Z. An, , S. Shanmugam, , T.P. Davis, , C. Boyer, . . Qiao, G.G, Chem. Rev. , 2016 . 116 ( 12 ): 6743 DOI: 10.1021/acs.chemrev.6b00008 http://doi.org/10.1021/acs.chemrev.6b00008 .

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