A Robust and Soluble Nanopolymer Based on Molecular Grid-based Nanomonomer

Quan-you Feng; Ye-long Han; Meng-na Yu; Bin Li; Ying Wei; Ling-hai Xie; Wei Huang

doi:10.1007/s10118-016-1856-7

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A Robust and Soluble Nanopolymer Based on Molecular Grid-based Nanomonomer

PAPERS | Updated：2021-02-18

- A Robust and Soluble Nanopolymer Based on Molecular Grid-based Nanomonomer
- Chinese Journal of Polymer Science Vol. 35, Issue 1, Pages: 87-97(2017)
- Affiliations：
  
  a.Center for Molecular Systems and Organic Devices(CMSOD), Key Laboratory for Organic Electronics and Information Displays & Institute of Advanced Materials(IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials(SICAM), Nanjing University of Posts & Telecommunications, Nanjing 210023, China
  b.Key Laboratory of Flexible Electronics(KLOFE) & Institute of Advanced Materials(IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials(SICAM), Nanjing Tech University(NanjingTech), Nanjing 211816, China
- Author bio：
  
  Ling-hai Xie, E-mail:iamlhxie@njupt.edu.cn
  Wei Huang, E-mail:iamwhuang@njupt.edu.cn
- Funds：
- DOI：10.1007/s10118-016-1856-7
  CLC：
- Received：16 May 2016，
  
  Revised：2016-6-22，
  
  Accepted：23 June 2016，
  
  Published：2017-01
- Accepted：
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Quan-you Feng, Ye-long Han, Meng-na Yu, et al. A Robust and Soluble Nanopolymer Based on Molecular Grid-based Nanomonomer[J]. Chinese Journal of Polymer Science, 2017, 35(1): 87-97.
DOI：

Quan-you Feng, Ye-long Han, Meng-na Yu, et al. A Robust and Soluble Nanopolymer Based on Molecular Grid-based Nanomonomer[J]. Chinese Journal of Polymer Science, 2017, 35(1): 87-97. DOI： 10.1007/s10118-016-1856-7.

摘要

Abstract

Shape persistent conformations reduce the complexity of polymer materials. Herein

we propose a concept on the nanopolymer that is a nanoscale polymer chain with the repeat units of nanomonomers. In this article

a soluble organic nanopolymer of wide bandgap semiconductors was synthesized by the Yamamoto polymerization of nanogrid monomer as the repeat units with the rectangle size of ~1.7 nm×1.2 nm. The alkyl side chain substituent at 9-position of fluorenes guarantees the polygrid with excellent solubility. Tetrafluorenes in the conjugation-interrupted backbones of polygrid acts as the active light-emitting centers without obvious green band in the fluorescence spectra of the films after 10 h annealing at 180℃

indicating this nanopolymer exhibits excellent spectral stability. Such soluble nanopolymers will be the fifth-generation of macromolecular materials with a potential character of overall performance improvement.

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references

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