Towards Efficient Electromagnetic Interference Shielding Performance for Polyethylene Composites by Structuring Segregated Carbon Black/Graphite Networks

Cheng-hua Cui; Ding-xiang Yan; Huan Pang; Li-chuan Jia; Yu Bao; Xin Jiang; Zhong-ming Li

doi:10.1007/s10118-016-1849-6

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Towards Efficient Electromagnetic Interference Shielding Performance for Polyethylene Composites by Structuring Segregated Carbon Black/Graphite Networks

Papers | Updated：2021-05-12

- Towards Efficient Electromagnetic Interference Shielding Performance for Polyethylene Composites by Structuring Segregated Carbon Black/Graphite Networks
- Chinese Journal of Polymer Science Vol. 34, Issue 12, Pages: 1490-1499(2016)
- Affiliations：
  
  College of Polymer Science and Engineering, State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu 610065, China
- Author bio：
  
  Ding-xiang Yan (鄢定祥), E-mail:yandingxiang@scu.edu.cn
- Funds：
- DOI：10.1007/s10118-016-1849-6
  CLC：
- Received：16 June 2016，
  
  Revised：2016-7-21，
  
  Accepted：25 July 2016，
  
  Published：2016-12
- Accepted：
Scan QR Code
Cheng-hua Cui, Ding-xiang Yan, Huan Pang, et al. Towards Efficient Electromagnetic Interference Shielding Performance for Polyethylene Composites by Structuring Segregated Carbon Black/Graphite Networks[J]. Chinese Journal of Polymer Science, 2016, 34(12): 1490-1499.
DOI：

Cheng-hua Cui, Ding-xiang Yan, Huan Pang, et al. Towards Efficient Electromagnetic Interference Shielding Performance for Polyethylene Composites by Structuring Segregated Carbon Black/Graphite Networks[J]. Chinese Journal of Polymer Science, 2016, 34(12): 1490-1499. DOI： 10.1007/s10118-016-1849-6.

摘要

Abstract

An electromagnetic interference (EMI) shielding composite based on ultrahigh molecular weight polyethylene (UHMWPE) loaded with economical graphite-carbon black (CB) hybrid fillers was prepared

via

a green and facile methodology

i.e.

high-speed mechanical mixing combined with hot compression thus avoiding the assistance of the intensive ultrasound dispersion in volatile organic solvents. In this composite

the graphite-CB hybrid fillers were selectively distributed in the interfacial regions of UHMWPE domains resulting a typical segregated structure. Thanks to the specific morphology of segregated conductive networks along with the synergetic effect of large-sized graphite flakes and small-sized CB nanoparticles

a low filler loading of 7.7 vol% (15 wt%) yielded the graphite-CB/UHMWPE composites with a satisfactory electrical conductivity of 33.9 S/m and a superior shielding effectiveness of 40.2 dB

manifesting the comparable value of the pricey large-aspect-ratio carbon nanofillers (

e.g.

carbon nanotubes and graphene nanosheets) based polymer composites. More interestingly

with the addition of 15 wt% graphite-CB (1/3

W/W

) hybrid fillers

the tensile strength and elongation at break of the composite reached 25.3 MPa and 126%

respectively; with a remarkable increase of 58.1% and 2420% over the conventional segregated graphite/UHMWPE composites. The mechanical reinforcement could be attributed to the favor of the small-sized CB particles in the polymer molecular diffusion between UHMWPE domains which in turn provided a stronger interfacial adhesion. This work provides a facile

green and affordable strategy to obtain the polymer composites with high electrical conductivity

efficient EMI shielding

and balanced mechanical performance.

关键词

Keywords

references

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