Phase Transition Temperature Controllable Poly(acrylamide-<italic style="font-style: italic">co-</italic>acrylic acid) Nanocomposite Physical Hydrogels with High Strength

Zhang Li-qin; Chen Li-wen; Zhong Ming; Shi Fu-kuan; Liu Xiao-ying; Xie Xu-ming

doi:10.1007/s10118-016-1848-7

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Phase Transition Temperature Controllable Poly(acrylamide-co-acrylic acid) Nanocomposite Physical Hydrogels with High Strength

PAPERS | Updated：2021-05-12

- Phase Transition Temperature Controllable Poly(acrylamide-co-acrylic acid) Nanocomposite Physical Hydrogels with High Strength
- Chinese Journal of Polymer Science Vol. 34, Issue 10, Pages: 1261-1269(2016)
- Affiliations：
  
  Laboratory of Advanced Materials (MOE), Department of Chemical Engineering, Tsinghua University, Beijing 100084, China
- Author bio：
  
  Xu-ming Xie (谢续明), E-mail: xxm-dce@mail.tsinghua.edu.cn
- Funds：
- DOI：10.1007/s10118-016-1848-7
  CLC：
- Received：11 April 2016，
  
  Revised：2016-5-21，
  
  Accepted：28 May 2016，
  
  Published：25 February 2016
- Accepted：
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Zhang Li-qin, Chen Li-wen, Zhong Ming, et al. Phase Transition Temperature Controllable Poly(acrylamide-co-acrylic acid) Nanocomposite Physical Hydrogels with High Strength[J]. Chinese Journal of Polymer Science, 2016, 34(10): 1261-1269. DOI: 10.1007/s10118-016-1848-7.
DOI：

Zhang Li-qin, Chen Li-wen, Zhong Ming, et al. Phase Transition Temperature Controllable Poly(acrylamide-co-acrylic acid) Nanocomposite Physical Hydrogels with High Strength[J]. Chinese Journal of Polymer Science, 2016, 34(10): 1261-1269. DOI: 10.1007/s10118-016-1848-7. DOI：

摘要

Abstract

Poly(acrylamide

-co-

acrylic acid) nanocomposite physical (P(AAm

-co-

AAc)NCP) hydrogels have been prepared through the

in situ

free radical solution polymerization based on a “single network

dual cross-linkings” strategy. The P(AAm

-co-

AAc) NCP hydrogels are composed of nanobrushes of P(AAm

-co-

AAc) chains grafted on the surface of vinyl-hybrid silica nanoparticles (VSNPs). In the hydrogel system

the VSNPs act as the “analogous chemical cross-linking points” once the hydrogen bonds formed between the P(AAm

-co-

AAc) chains of the nanobrushes

thus leading to the fabrication of high-strength P(AAm

-co-

AAc) NCP hydrogels. Compared with conventional thermosensitive P(AAm

-co-

AAc) hydrogels

the P(AAm

-co-

AAc) NCP hydrogels have a broader range of phase transition temperature

which can be adjusted by altering the monomer ratio

the VSNPs concentration

the addition of urea and

-dimethylacrylamide (DMAAm). At the same time

the mechanical properties of the P(AAm

-co-

AAc) NCP hydrogels have been improved significantly by the introduction of VSNPs. Furthermore

both the phase transition and the tensile strength of the P(AAm

-co-

AAc) NCP hydrogels are largely influenced when Fe

ions are introduced as the ionic crosslinkers into the hydrogel networks.

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Phase Transition Temperature Controllable Poly(acrylamide-co-acrylic acid) Nanocomposite Physical Hydrogels with High Strength

DOI：10.1007/s10118-016-1848-7

摘要

Abstract

关键词

Keywords

references