Fluorinated Polyimide/POSS Hybrid Polymers with High Solubility and Low Dielectric Constant

Chen-yi Wang; Wen-tao Chen; Chang Xu; Xiao-yan Zhao; Jian Li

doi:10.1007/s10118-016-1845-x

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Fluorinated Polyimide/POSS Hybrid Polymers with High Solubility and Low Dielectric Constant

PAPERS | Updated：2021-05-12

- Fluorinated Polyimide/POSS Hybrid Polymers with High Solubility and Low Dielectric Constant
- Chinese Journal of Polymer Science Vol. 34, Issue 11, Pages: 1363-1372(2016)
- Affiliations：
  
  a.School of Materials Science and Engineering, Changzhou University, Changzhou 213164, China
  b.State Key Laboratory of Electrical Insulation and Power Equipment, Xi'an Jiaotong University, Xi'an 710049, China
- Author bio：
  
  Chen-yi Wang(汪称意),E-mail:wangcy@cczu.edu.cn
  Xiao-yan Zhao(赵晓燕),E-mail:zhaoxiaoyan@cczu.edu.cn
- Funds：
- DOI：10.1007/s10118-016-1845-x
  CLC：
- Received：22 May 2016，
  
  Revised：2016-6-9，
  
  Accepted：13 June 2016，
  
  Published：2016-11
- Accepted：
Scan QR Code
Chen-yi Wang, Wen-tao Chen, Chang Xu, et al. Fluorinated Polyimide/POSS Hybrid Polymers with High Solubility and Low Dielectric Constant[J]. Chinese Journal of Polymer Science, 2016, 34(11): 1363-1372.
DOI：

Chen-yi Wang, Wen-tao Chen, Chang Xu, et al. Fluorinated Polyimide/POSS Hybrid Polymers with High Solubility and Low Dielectric Constant[J]. Chinese Journal of Polymer Science, 2016, 34(11): 1363-1372. DOI： 10.1007/s10118-016-1845-x.

摘要

Abstract

A series of fluorinated polyimide/POSS hybrid polymers (FPI-4-FPI-16) were prepared

via

a facile synthetic route using 2

2'-bis(trifluoromethyl)benzidine

4'-oxydiphthalic dianhydride and monofunctional POSS as starting materials. The hybrid polymers showed excellent solubility and film formation ability. Flexible and robust hybrid films could be conveniently obtained

via

solution-casting. The hybrid films demonstrated low dielectric constants and high thermal stability. Their dielectric constants were in the range of 2.47-2.92 at 1 MHz measured for their capacitance

and were tunable and decreased with an increase of POSS content. Their 10% weight loss temperatures were in the range of 539-591℃ and the weight residual at 800℃ ranged from 48% to 53% in nitrogen atmosphere. These hybrid films also possessed good mechanical properties and hydrophobic characteristics. This work could provide a potential strategy for the preparation of fluorinated polyimide/POSS hybrid polymers.

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