Mechanical Properties of Polyimide/Multi-walled Carbon Nanotube Composite Fibers

Zhi-xin Dong; Tao Feng; Chao Zheng; Guo-min Li; Fang-fang Liu; Xue-peng Qiu

doi:10.1007/s10118-016-1841-1

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Mechanical Properties of Polyimide/Multi-walled Carbon Nanotube Composite Fibers

PAPERS | Updated：2021-05-12

- Mechanical Properties of Polyimide/Multi-walled Carbon Nanotube Composite Fibers
- Chinese Journal of Polymer Science Vol. 34, Issue 11, Pages: 1386-1395(2016)
- Affiliations：
  
  a.Polymer Composites Engineering Laboratory, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
  b.Academy of Space Electronic Information Technology, Xi'an 710100, China
- Author bio：
  
  Xue-peng Qiu(邱雪鹏),E-mail:xp_q@ciac.ac.cn
- Funds：
- DOI：10.1007/s10118-016-1841-1
  CLC：
- Received：03 May 2016，
  
  Revised：2016-6-14，
  
  Accepted：06 July 2016，
  
  Published：2016-11
- Accepted：
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Zhi-xin Dong, Tao Feng, Chao Zheng, et al. Mechanical Properties of Polyimide/Multi-walled Carbon Nanotube Composite Fibers[J]. Chinese Journal of Polymer Science, 2016, 34(11): 1386-1395.
DOI：

Zhi-xin Dong, Tao Feng, Chao Zheng, et al. Mechanical Properties of Polyimide/Multi-walled Carbon Nanotube Composite Fibers[J]. Chinese Journal of Polymer Science, 2016, 34(11): 1386-1395. DOI： 10.1007/s10118-016-1841-1.

摘要

Abstract

A series of polyimide (PI)/multi-walled carbon nanotube (MWCNT) composite fibers were prepared by copolymerizing a mixture of monomers and carboxylic-functionalized MWCNTs

followed by dry-jet wet spinning

thermal imidization

and hot-drawing process. The content of the carboxylic groups of MWCNTs significantly increased when treated with mixed acid

whereas their length decreased with treatment time. Both the carboxylic content and length of MWCNTs influenced the mechanical properties of the composite fibers. Fiber added with 0.1 wt% MWCNTs treated for 4 h exhibited the best mechanical properties

i.e

1.4 GPa tensile strength and 14.30% elongation at break

which were 51% and 32% higher than those of pure PI fibers

respectively. These results indicated that a suitable MWCNT content strengthened and toughened the resultant PI composite fibers

simultaneously. Moreover

raising draw ratio resulted in the increase of tensile strength and tensile modulus of the composite fibers.

关键词

Keywords

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