Tuning Thermal Gelling Behavior of <italic style="font-style: italic">N</italic>-isopropylacrylamide Based Copolymer through Introducing Cucurbit[8]uril Ternary Complex on Side-chain

Ma Hai-li; Chen Hao; Hou Sheng-zhen; Tan Ye-bang

doi:10.1007/s10118-016-1837-x

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Tuning Thermal Gelling Behavior of N-isopropylacrylamide Based Copolymer through Introducing Cucurbit[8]uril Ternary Complex on Side-chain

PAPERS | Updated：2021-05-12

- Tuning Thermal Gelling Behavior of N-isopropylacrylamide Based Copolymer through Introducing Cucurbit[8]uril Ternary Complex on Side-chain
- Chinese Journal of Polymer Science Vol. 34, Issue 10, Pages: 1251-1260(2016)
- Affiliations：
  
  School of Chemistry and Engineering, Shandong University, Jinan 250100, China
- Author bio：
  
  Ye-bang Tan (谭业邦), E-mail: ybtan@sdu.edu.cn
- Funds：
- DOI：10.1007/s10118-016-1837-x
  CLC：
- Received：11 April 2016，
  
  Revised：2016-5-14，
  
  Accepted：19 May 2016，
  
  Published：05 October 2016
- Accepted：
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Ma Hai-li, Chen Hao, Hou Sheng-zhen, et al. Tuning Thermal Gelling Behavior of N-isopropylacrylamide Based Copolymer through Introducing Cucurbit[8]uril Ternary Complex on Side-chain[J]. Chinese Journal of Polymer Science, 2016, 34(10): 1251-1260. DOI: 10.1007/s10118-016-1837-x.
DOI：

Ma Hai-li, Chen Hao, Hou Sheng-zhen, et al. Tuning Thermal Gelling Behavior of N-isopropylacrylamide Based Copolymer through Introducing Cucurbit[8]uril Ternary Complex on Side-chain[J]. Chinese Journal of Polymer Science, 2016, 34(10): 1251-1260. DOI: 10.1007/s10118-016-1837-x. DOI：

摘要

Abstract

Thermo-gelation polymers have attracted increasing attention over decades. However

rare facile tuning method of sol-gel transition temperature restricted the wider application. Preceding study indicated that supramolecular interactions demonstrated a powerful means to control the structure and property of polymeric materials. Here we designed an

-isopropylacrylamide (NIPAM) based thermo-sensitive copolymer with naphthyl (Np) on its side chain. Positive-charged side-chain ternary complex was formed with cucurbit[8]uril (CB[8]

) and methylviologen (MV

)

via

CB[8]-enhanced intermolecular charge-transfer (CT) interaction. Introducing the ternary complex CB[8]

/MV

/Np on side-chain altered microstructure of macromolecular chains and led to a strong tendency for thermo gelation. Altering content of CB[8] and MV

changed content of the positive-charged side-chain ternary complex and varied gelation temperature. Therefore

introducing supramolecular interaction endowed the hydrogel with tunable gelation property.

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Tuning Thermal Gelling Behavior of N-isopropylacrylamide Based Copolymer through Introducing Cucurbit[8]uril Ternary Complex on Side-chain

DOI：10.1007/s10118-016-1837-x

摘要

Abstract

关键词

Keywords

references