A Facile Way to Large-scale Production of Few-layered Graphene <italic style="font-style: italic">via</italic> Planetary Ball Mill

Deng Sha; Qi Xiao-dong; Zhu Yan-ling; Zhou Hong-ju; Chen Feng; Fu Qiang

doi:10.1007/s10118-016-1836-y

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A Facile Way to Large-scale Production of Few-layered Graphene via Planetary Ball Mill

PAPERS | Updated：2021-05-12

- A Facile Way to Large-scale Production of Few-layered Graphene via Planetary Ball Mill
- Chinese Journal of Polymer Science Vol. 34, Issue 10, Pages: 1270-1280(2016)
- Affiliations：
  
  College of Polymer Science and Engineering, State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu 610065, China
- Author bio：
  
  Qiang Fu (傅强), E-mail: qiangfu@scu.edu.cn
- Funds：
- DOI：10.1007/s10118-016-1836-y
  CLC：
- Received：23 May 2016，
  
  Revised：2016-6-10，
  
  Accepted：13 June 2016，
  
  Published：25 February 2016
- Accepted：
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Deng Sha, Qi Xiao-dong, Zhu Yan-ling, et al. A Facile Way to Large-scale Production of Few-layered Graphene via Planetary Ball Mill[J]. Chinese Journal of Polymer Science, 2016, 34(10): 1270-1280. DOI: 10.1007/s10118-016-1836-y.
DOI：

Deng Sha, Qi Xiao-dong, Zhu Yan-ling, et al. A Facile Way to Large-scale Production of Few-layered Graphene via Planetary Ball Mill[J]. Chinese Journal of Polymer Science, 2016, 34(10): 1270-1280. DOI: 10.1007/s10118-016-1836-y. DOI：

摘要

Abstract

In the field of polymer/graphene nanocomposites

massive production and commercial availability of graphene are essential. Exfoliation of graphite to obtain graphene is one of the most promising ways to large-scale production at extremely low cost. In this work we illustrate a facile strategy for mass production of few-layered (≤ 10) graphene (FLG)

via

the newly explored ball milling. The achieved FLG concentration was determined by UV/Vis spectroscopy. The formation of FLG was proved by measuring the flake thickness by atomic force microscopy (AFM). Further Raman spectral studies indicated that the crystal structure of exfoliated flakes was preserved satisfactorily during this shear-force dominating process. To increase the maximum concentration obtainable

it's critical to make a good parameter assessment.

N-

methylpyrrolidone (NMP) was used as a dispersing medium and the effect of milling parameters was systematically and quantitatively investigated

thus providing a criterion to optimize the milling process. We established the optimal values for solvent volume and initial weight of graphite. As for milling time

the production of FLG was enhanced with continuous milling according to the power law

but not linearly with increasing milling time. Moreover

the possible mechanism involved in milling process was also explored. Our work provides a simple method for graphite exfoliation and has great potential for improving thermal and electrical conductivity of polymer composites in the fields of engineering.

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A Facile Way to Large-scale Production of Few-layered Graphene via Planetary Ball Mill

DOI：10.1007/s10118-016-1836-y

摘要

Abstract

关键词

Keywords

references