Synergistic Effect of Nucleation and Compatibilization on the Polylactide and Poly(butylene adipate-<italic style="font-style: italic">co</italic>-terephthalate) Blend Films

Phetwarotai Worasak; Tanrattanakul Varaporn; Phusunti Neeranuch

doi:10.1007/s10118-016-1834-0

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Synergistic Effect of Nucleation and Compatibilization on the Polylactide and Poly(butylene adipate-co-terephthalate) Blend Films

PAPERS | Updated：2021-05-12

- Synergistic Effect of Nucleation and Compatibilization on the Polylactide and Poly(butylene adipate-co-terephthalate) Blend Films
- Chinese Journal of Polymer Science Vol. 34, Issue 9, Pages: 1129-1140(2016)
- Affiliations：
  
  a. Department of Materials Science and Technology, Faculty of Science, Prince of Songkla University, Hatyai, Songkhla 90112, Thailand
  b. Bioplastic Research Unit, Department of Materials Science and Technology, Faculty of Science, Prince of Songkla University, Hatyai, Songkhla 90112, Thailand
  c. Department of Chemistry, Faculty of Science, Prince of Songkla University, Hatyai, Songkhla 90112, Thailand
- Author bio：
  
  Worasak Phetwarotai,E-mail:w.phetwarotai@hotmail.com,worasak.ph@psu.ac.th
- Funds：
- DOI：10.1007/s10118-016-1834-0
  CLC：
- Received：13 March 2016，
  
  Revised：2016-4-19，
  
  Accepted：19 April 2016，
  
  Published：05 October 2016
- Accepted：
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Phetwarotai Worasak, Tanrattanakul Varaporn, Phusunti Neeranuch. Synergistic Effect of Nucleation and Compatibilization on the Polylactide and Poly(butylene adipate-co-terephthalate) Blend Films[J]. Chinese Journal of Polymer Science, 2016, 34(9): 1129-1140. DOI: 10.1007/s10118-016-1834-0.
DOI：

Phetwarotai Worasak, Tanrattanakul Varaporn, Phusunti Neeranuch. Synergistic Effect of Nucleation and Compatibilization on the Polylactide and Poly(butylene adipate-co-terephthalate) Blend Films[J]. Chinese Journal of Polymer Science, 2016, 34(9): 1129-1140. DOI: 10.1007/s10118-016-1834-0. DOI：

摘要

Abstract

Polylactide (PLA) films blended with 10 wt% poly(butylene adipate-

-terephthalate) (PBAT) were prepared by using a twin screw extruder in the presence of the nucleating agent of titanium dioxide (TiO

) and the compatibilizers of toluene diisocyanate (TDI) and PLA-grafted-maleic anhydride (PLA-

-MA). The synergistic effect of the nucleation and compatibilization on the properties and crystallization behavior of the PLA/PBAT (PLB) films was explored. The results showed that the addition of TiO

significantly enhanced the tensile strength and the impact tensile resistance of the PLB films while slightly decreased its thermal stability. In addition

the compatibilizers of TDI and PLA-

-MA in the system not only affected the crystallinity and cold crystallization process of the PLB films

but also increased the mechanical properties of them due to the improvement of the interfacial interaction between PLA and PBAT revealed by the morphological measurement. The synergistic effects of the nucleating agent and the compatibilizer afforded the blend films with increased tensile strength and impact tensile toughness

improved cold crystallization property and

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Synergistic Effect of Nucleation and Compatibilization on the Polylactide and Poly(butylene adipate-co-terephthalate) Blend Films

DOI：10.1007/s10118-016-1834-0

摘要

Abstract

关键词

Keywords

references