Synthesis, Characterization and Thermal Stability of Novel Carborane-Containing Epoxy Novolacs

Han Guo; Yang Zhen; Yang Xiao-xue; Zhang Xiao-a; Jiang Sheng-ling; Lu Ya-fei

doi:10.1007/s10118-016-1832-2

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Synthesis, Characterization and Thermal Stability of Novel Carborane-Containing Epoxy Novolacs

PAPERS | Updated：2021-05-12

- Synthesis, Characterization and Thermal Stability of Novel Carborane-Containing Epoxy Novolacs
- Chinese Journal of Polymer Science Vol. 34, Issue 9, Pages: 1103-1116(2016)
- Affiliations：
  
  Key Laboratory of Carbon Fiber and Functional Polymers of Ministry of Education, College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China
- Author bio：
  
  Xiao-a Zhang(张孝阿),E-mail:zhangxiaoa1982@163.com
- Funds：
- DOI：10.1007/s10118-016-1832-2
  CLC：
- Received：23 March 2016，
  
  Revised：2016-4-16，
  
  Accepted：16 April 2016，
  
  Published：05 October 2016
- Accepted：
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Han Guo, Yang Zhen, Yang Xiao-xue, et al. Synthesis, Characterization and Thermal Stability of Novel Carborane-Containing Epoxy Novolacs[J]. Chinese Journal of Polymer Science, 2016, 34(9): 1103-1116.
DOI：

Han Guo, Yang Zhen, Yang Xiao-xue, et al. Synthesis, Characterization and Thermal Stability of Novel Carborane-Containing Epoxy Novolacs[J]. Chinese Journal of Polymer Science, 2016, 34(9): 1103-1116. DOI： 10.1007/s10118-016-1832-2.

摘要

Abstract

Carborane bisphenol novolacs (

and

) were synthesized in the presence of acid catalyst from carborane bisphenols (

and

) and formaldehyde. Further epoxidization of carborane bisphenol novolacs with epichlorohydrin gave carborane bisphenol epoxy novolacs (

and

). The molecular weight and epoxy value of obtained resins were determined using the molecular weight of their precursors. The epoxy values of

and

were 0.48 and 0.52 respectively

higher than the maximum theoretical epoxy value (0.45) of difunctional carborane bisphenol epoxy resins. FTIR and NMR were utilized to characterize

and

. The curing behaviors were also studied by DSC and the optimized curing conditions were obtained. TGA analysis indicated that carborane moiety could shield its adjacent organic structures against initial decomposition. On the other hand

B―H on carborane cage could react with oxygen to form a three-dimensional network linked by B―O―B and B―C bonds

which further blocked the movement of formed radicals and thus the degradation process was inhibited.

关键词

Keywords

references

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