Investigation of Cationic Soapless P(St-<italic style="font-style: italic">co</italic>-DMAEMA) Latex and Its Electrostatic Adsorption of Laponite

Shen Jie; Xu Jing; Hu Yang; Sun Jian-wu; Li Ling-xiao; Kan Cheng-you

doi:10.1007/s10118-016-1829-x

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Investigation of Cationic Soapless P(St-co-DMAEMA) Latex and Its Electrostatic Adsorption of Laponite

PAPERS | Updated：2021-05-12

- Investigation of Cationic Soapless P(St-co-DMAEMA) Latex and Its Electrostatic Adsorption of Laponite
- Chinese Journal of Polymer Science Vol. 34, Issue 10, Pages: 1240-1250(2016)
- Affiliations：
  
  Department of Chemical Engineering, Key Laboratory of Advanced Materials of Ministry of Education, Tsinghua University, Beijing 100084, China
- Author bio：
  
  Cheng-you Kan (阚成友), E-mail: kancy@mail.tsinghua.edu.cn
- Funds：
- DOI：10.1007/s10118-016-1829-x
  CLC：
- Received：06 April 2016，
  
  Revised：2016-4-29，
  
  Accepted：01 May 2016，
  
  Published：25 February 2016
- Accepted：
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Shen Jie, Xu Jing, Hu Yang, et al. Investigation of Cationic Soapless P(St-co-DMAEMA) Latex and Its Electrostatic Adsorption of Laponite[J]. Chinese Journal of Polymer Science, 2016, 34(10): 1240-1250. DOI: 10.1007/s10118-016-1829-x.
DOI：

Shen Jie, Xu Jing, Hu Yang, et al. Investigation of Cationic Soapless P(St-co-DMAEMA) Latex and Its Electrostatic Adsorption of Laponite[J]. Chinese Journal of Polymer Science, 2016, 34(10): 1240-1250. DOI: 10.1007/s10118-016-1829-x. DOI：

摘要

Abstract

Cationic poly(styrene-

-dimethylaminoethyl methacrylate) (P(St-

-DMAEMA)) latexes were prepared in the absence of surfactant by using 2

2'-azobis (2-methylpropionamidine) dihydrochloride (AIBA) as the initiator. The effects of the AIBA concentration

HCl/DMAEMA molar ratio and DMAEMA amount on the emulsion polymerization and the latex properties were investigated. The particle morphology and size

the zeta potential and the amino distribution of the P(St-

-DMAEMA) latexes were characterized by transmission electron microscope (TEM)

dynamic light scattering (DLS) and conductometric titration

respectively. Results showed that the emulsion polymerization performed smoothly with high monomer conversion and narrow particle size distribution under the optimized conditions with AIBA concentration of 1 wt%

HCl/DMAEMA molar ratio of 1.2 and DMAEMA content of 5 wt%. The diameter of the dried latex particles decreased and the density of amino groups on the particle surfaces increased with increasing the DMAEMA content. The zeta potential of the P(St-

-DMAEMA) latexes was pH-dependent and the zero point was around at pH 7.2. A facile method was developed to fabricate P(St-

-DMAEMA)/laponite hybrid nanoparticles

via

electrostatic adsorption

in which the loading capacity of laponite platelets reached 17.7 wt%

and the resultant hybrid nanoparticles showed good thermal stability.

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⁰

Investigation of Cationic Soapless P(St-co-DMAEMA) Latex and Its Electrostatic Adsorption of Laponite

DOI：10.1007/s10118-016-1829-x

摘要

Abstract

关键词

Keywords

references