Polymerization of 1,3-Butadiene Catalyzed by Cobalt(II)and Nickel(II) Complexes Bearing Pyridine-2-imidate Ligands

Liu Heng; Yang Shi-ze; Wang Feng; Bai Chen-xi; Hu Yan-ming; Zhang Xue-quan

doi:10.1007/s10118-016-1825-1

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Polymerization of 1,3-Butadiene Catalyzed by Cobalt(II)and Nickel(II) Complexes Bearing Pyridine-2-imidate Ligands

PAPERS | Updated：2021-05-12

- Polymerization of 1,3-Butadiene Catalyzed by Cobalt(II)and Nickel(II) Complexes Bearing Pyridine-2-imidate Ligands
- Chinese Journal of Polymer Science Vol. 34, Issue 9, Pages: 1060-1069(2016)
- Affiliations：
  
  a. Key Laboratory of Synthetic Rubber, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
  b. Panjin Northern Asphalt Co., Ltd, Norinco Group, Panjin 124000, China
- Author bio：
  
  Yan-ming Hu(胡雁鸣),E-mail:ymhu@ciac.ac.cn
  Xue-quan Zhang(张学全),E-mail:xqzhang@ciac.ac.cn
- Funds：
- DOI：10.1007/s10118-016-1825-1
  CLC：
- Received：26 March 2016，
  
  Revised：2016-4-29，
  
  Accepted：29 April 2016，
  
  Published：05 October 2016
- Accepted：
Scan QR Code
Liu Heng, Yang Shi-ze, Wang Feng, et al. Polymerization of 1,3-Butadiene Catalyzed by Cobalt(II)and Nickel(II) Complexes Bearing Pyridine-2-imidate Ligands[J]. Chinese Journal of Polymer Science, 2016, 34(9): 1060-1069.
DOI：

Liu Heng, Yang Shi-ze, Wang Feng, et al. Polymerization of 1,3-Butadiene Catalyzed by Cobalt(II)and Nickel(II) Complexes Bearing Pyridine-2-imidate Ligands[J]. Chinese Journal of Polymer Science, 2016, 34(9): 1060-1069. DOI： 10.1007/s10118-016-1825-1.

摘要

Abstract

Cobalt and nickel complexes (

and

respectively) supported by 2-imidate-pyridine ligands were synthesized and used for 1

3-butadiene polymerization. The complexes were characterized by IR and element analysis

and complex

was further characterized by single-crystal X-ray diffraction. The solid state structure of complex

displayed a distorted tetrahedral geometry. Upon activation with ethylaluminum sesquichloride (EASC)

all the complexes showed high activities toward 1

3-butadiene polymerization. The cobalt complexes produced polymers with high

cis

-1

4 contents and high molecular weights

while the nickel complexes displayed low

cis

-1

4 selectivity and the resulting polymers had low molecular weights. The catalytic activities of the complexes highly depended on the ligand structure. With the increment of polymerization temperature

the

cis

-1

4 content and the molecular weight of the resulting polymer decreased.

关键词

Keywords

references

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