Analysis of Structure Transition and Compatibility of PTT/PC Blend without Transesterification

Song Qing-long; Wen Hui-ying; de Claville Christiansen Jesper; Yu Dong-hong; Chen Chun-sheng; Jiang Shi-chun

doi:10.1007/s10118-016-1820-6

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Analysis of Structure Transition and Compatibility of PTT/PC Blend without Transesterification

PAPERS | Updated：2021-05-12

- Analysis of Structure Transition and Compatibility of PTT/PC Blend without Transesterification
- Chinese Journal of Polymer Science Vol. 34, Issue 9, Pages: 1172-1182(2016)
- Affiliations：
  
  a. College of Engineering and Technology, Northeast Forestry University, Harbin 150040, China
  b. Department of Mechanical and Manufacturing Engineering, Aalborg University, DK-9220, Aalborg, Denmark
  c. Department of Biotechnology, Chemistry, and Environmental Engineering, Aalborg University, DK-9220, Aalborg, Denmark
  d. School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China
- Author bio：
  
  Hui-ying Wen(温慧颖),E-mail:hywen@nefu.edu.cn
  Shi-chun Jiang(蒋世春),E-mail:scjiang@tju.edu.cn
- Funds：
- DOI：10.1007/s10118-016-1820-6
  CLC：
- Received：02 March 2016，
  
  Revised：2016-3-31，
  
  Accepted：31 March 2016，
  
  Published：05 October 2016
- Accepted：
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Song Qing-long, Wen Hui-ying, de Claville Christiansen Jesper, et al. Analysis of Structure Transition and Compatibility of PTT/PC Blend without Transesterification[J]. Chinese Journal of Polymer Science, 2016, 34(9): 1172-1182.
DOI：

Song Qing-long, Wen Hui-ying, de Claville Christiansen Jesper, et al. Analysis of Structure Transition and Compatibility of PTT/PC Blend without Transesterification[J]. Chinese Journal of Polymer Science, 2016, 34(9): 1172-1182. DOI： 10.1007/s10118-016-1820-6.

摘要

Abstract

Poly(trimethylene terephthalate)/polycarbonate (PTT/PC) blends were prepared by solvent mixing to avoid transesterification during high temperature blending. The influences of compositions on the thermal behavior

crystallization morphology and structure of the blends were studied. FTIR results indicated that there was no COO linking to two phenyl groups on each side chain and DSC results supported no transesterification reaction. DSC curves showed that

and

increased to maximum range when PC contents were between 7 wt%-15 wt%

however

decreased constantly with the increase of PC contents. It was observed from POM that PTT spherulitic morphology and crystallization kinetics were obviously influenced by the change of PC contents. Structural evolutions during cooling were investigated by SAXS which showed

of PTT remained a constant with different PC contents and also fixed during crystallization

nevertheless

it revealed a maximum value of

for sample PTT

. It was concluded that PC chains could be permeated into not only amorphous crystallite structure but also amorphous lamellae structure and 7 wt% PC content was supposed to be the "proper" penetration amount into PTT lamellae structure which led to a maximum capacity of amorphous lamellar layer. Fringed-micelle crystal model was adopted to illustrate semi-crystalline physical structures of the blend in two kinds of component aggregation states.

关键词

Keywords

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