A Facile and Highly Efficient Protocol for Synthesis of Poly(ether sulfone)s in Ionic Liquid/Zwitterion

Jing Wang; Ying Wu; Zheng-ping Liu

doi:10.1007/s10118-016-1818-0

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A Facile and Highly Efficient Protocol for Synthesis of Poly(ether sulfone)s in Ionic Liquid/Zwitterion

PAPERS | Updated：2021-05-12

- A Facile and Highly Efficient Protocol for Synthesis of Poly(ether sulfone)s in Ionic Liquid/Zwitterion
- Chinese Journal of Polymer Science Vol. 34, Issue 8, Pages: 981-990(2016)
- Affiliations：
  
  Institute of Polymer Chemistry and Physics of College of Chemistry, BNU Key Lab of Environmentally Friendly and Functional Polymer Materials, Beijing Key Laboratory of Energy Conversion and Storage Materials, Beijing Normal University, Beijing 100875, China
- Author bio：
  
  Ying Wu (武英), E-mail: 11112014099@bnu.edu.cn
  Zheng-ping Liu (刘正平), E-mail: lzp@bnu.edu.cn
- Funds：
- DOI：10.1007/s10118-016-1818-0
  CLC：
- Received：02 February 2016，
  
  Revised：2016-3-24，
  
  Accepted：29 March 2016，
  
  Published：2016-08
- Accepted：
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Jing Wang, Ying Wu, Zheng-ping Liu. A Facile and Highly Efficient Protocol for Synthesis of Poly(ether sulfone)s in Ionic Liquid/Zwitterion[J]. Chinese Journal of Polymer Science, 2016, 34(8): 981-990.
DOI：

Jing Wang, Ying Wu, Zheng-ping Liu. A Facile and Highly Efficient Protocol for Synthesis of Poly(ether sulfone)s in Ionic Liquid/Zwitterion[J]. Chinese Journal of Polymer Science, 2016, 34(8): 981-990. DOI： 10.1007/s10118-016-1818-0.

摘要

Abstract

A benign approach for efficient preparation of poly(ether sulfone) (PES) (

inh

=0.10-0.31 dL·g

-1

) has been presented by using ionic liquid (IL)/zwitterion (ZI) as reaction medium. It has been found that the interaction between 4

4'-dihydroxydiphenylsulfone (Bisphenol-S) and ZI at elevated temperatures results in efficient reduction of dehydration time

which is confirmed by TGA curves

melting point of the mixture and FTIR spectra. Furthermore

no agglomeration is observed at dehydration stage

which is attributed to the high solubility of Bisphenol-S dipotassium salt in IL/ZI. This also makes the polymerization temperature (150℃) much lower than a conventional method (220-300℃). In order to demonstrate the efficiency of IL/ZI as reaction medium

the polymerization was also performed in sulfolane under the same reaction condition as that in IL/ZI.

关键词

Keywords

references

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