Amino Acids Functionalized Graphene Oxide for Enhanced Hydrophilicity and Antifouling Property of Poly(vinylidene fluoride) Membranes

Jian-hua Li; Shuang-shuang Wang; De-bin Zhang; Xing-xing Ni; Qi-qing Zhang

doi:10.1007/s10118-016-1808-2

Your Location：

Home >

Browse articles >

Amino Acids Functionalized Graphene Oxide for Enhanced Hydrophilicity and Antifouling Property of Poly(vinylidene fluoride) Membranes

PAPERS | Updated：2021-05-12

- Amino Acids Functionalized Graphene Oxide for Enhanced Hydrophilicity and Antifouling Property of Poly(vinylidene fluoride) Membranes
- Chinese Journal of Polymer Science Vol. 34, Issue 7, Pages: 805-819(2016)
- Affiliations：
  
  Institute of Biomedical and Pharmaceutical Technology, Fuzhou University, Fuzhou 350001, China
- Author bio：
  
  Jian-hua Li (李建华), E-mail: jhli_2005@163.com
  Qi-qing Zhang (张其清), E-mail: zhangqiq@126.com
- Funds：
- DOI：10.1007/s10118-016-1808-2
  CLC：
- Received：16 December 2015，
  
  Revised：2016-3-9，
  
  Accepted：18 March 2016，
  
  Published：2016-07
- Accepted：
Scan QR Code
Jian-hua Li, Shuang-shuang Wang, De-bin Zhang, et al. Amino Acids Functionalized Graphene Oxide for Enhanced Hydrophilicity and Antifouling Property of Poly(vinylidene fluoride) Membranes[J]. Chinese Journal of Polymer Science, 2016, 34(7): 805-819.
DOI：

Jian-hua Li, Shuang-shuang Wang, De-bin Zhang, et al. Amino Acids Functionalized Graphene Oxide for Enhanced Hydrophilicity and Antifouling Property of Poly(vinylidene fluoride) Membranes[J]. Chinese Journal of Polymer Science, 2016, 34(7): 805-819. DOI： 10.1007/s10118-016-1808-2.

摘要

Abstract

Herein

functionalized graphene oxide (GO) was prepared by the covalent functionalization with amino acids (lysine

glycine

glutamic acid and tyrosine) in this study. Zeta potential results demonstrated that covalent functionalization of GO with amino acids was favourable for their homogeneous dispersion in water and organic solvents. Based on the higher absolute value of zeta potential and the better dipersion stability of GO-lysine

the PVDF/GO-lysine hybrid membranes were then prepared

via

the phase inversion induced by immersion precipitation technique. SEM images showed a better pore diameter and porosity distribution on the PVDF/GO-lysine membrane surface. The zeta potential absolute value of the PVDF/GO-lysine membrane surface was higher than that of the virgin PVDF membrane. Furthermore

the PVDF/GO-lysine membranes surface exhibited good hydrophilicity. The water flux of PVDF/GO-lysine membranes can reach two times of that of the virgin PVDF membrane. And the BSA adsorbed amount on PVDF/GO-lysine surface was decreased to 0.82 mg/cm

for PVDF/GO-lysine-8% membrane. Filtration experiment results indicated that the fouling resistance was significantly improved for the PVDF/GO-lysine membranes. As a result

lysine functionalized GO will provide a promising method to fabricate graphene oxide based hybrid membranes with effective antifouling property and hydrophilicity.

关键词

Keywords

references

J.H. Li , X.S. Shao , Q. Zhou , M.Z. Li , Q.Q. Zhang . Appl. Surf. Sci. , 2013 . 265 663 .

S.K. Mahdie , V. Vahid . Ind. Eng. Chem. Res. , 2014 . 53 13370 .

J. Liu , X. Shen , Y.P. Zhao , L. Chen . Ind. Eng. Chem. Res. , 2013 . 52 18392 .

K. Chia-Hung , G.J. Chen , T. Yawo-Kuo , Y.C. Liu , S. Chwen-Jen . Ind. Eng. Chem. Res. , 2012 . 51 5141 .

J.H. Wang , Y.H. Zhang , Y.Y. Xu , B.K. Zhu . Chinese J. Polym. Sci. , 2014 . 32 ( 2 ): 143 .

N. Lee , G. Amy , J.P. Croué , H. Buisson . Water Res. , 2004 . 38 4511 .

Z.W. Xu , J.G. Zhang , M.J. Shan , Y.L. Li , B.D. Li , J.R. Niu . J. Membr. Sci. , 2014 . 458 1 .

A. Nabe , E. Staude , G. Belfort . J. Membr. Sci. , 1997 . 133 57 .

A. Schulze , M.F. Maitz , R. Zimmermann , B. Marquardt , M. Fischer , C. Werner , M. Wenta , I. Thomas . RSC Adv. , 2013 . 3 22518 .

J.Q. Meng , C.L. Chen , L.P. Huang , Q.Y. Du , Y.F. Zhang . Appl. Surf. Sci. , 2011 . 257 6282 .

T. Yuan , J.Q. Meng , T.Y. Hao , Z.H. Wang , Y.F. Zhang . ACS Appl. Mater. Interfaces , 2015 . 7 14896 .

J. Yuan , J.Q. Meng , Y.L. Kang , Q.Y. Du , Y.F. Zhang . Appl. Surf. Sci. , 2012 . 258 2856 .

Q. Sun , Y.F. Zhang , C.L. Chen , X.Z. Guo , J.Q. Meng . Chinese J. Polym. Sci. , 2014 . 32 ( 7 ): 880 .

A.K. Singh , P. Singh , S. Mishra , V.K. Shahi . J. Mater. Chem. , 2012 . 22 1834 .

S. Majeed , D. Fierro , K. Buhr , J. Wind , B. Du , A. Boschetti-de-Fierro , V. Abetz . J. Membr. Sci. , 2012 . 403-404 101 .

Y. Sui , Z.N. Wang , X.L. Gao , C.J. Gao . J. Membr. Sci. , 2012 . 413-414 38 .

A. Venault. , Y.H. Liu , J.R. Wu , H.S. Yang , Y. Chang , J.Y. Lai , P. Aimar . J. Membr. Sci. , 2014 . 450 340 .

M.Y. Wu , S.J. Meng , Q. Wang , W. Huang , X.C. Dong . ACS Appl Mater Inter. , 2015 . 7 21089 .

S.J. Xia , M.Z. Ni . J. Membr. Sci. , 2015 . 473 54 .

K.T. Cao , Z.Y. Jiang , J. Zhao , C.H. Zhao , C.Y. Gao , F.S. Pan , B.Y. Wang , X.Z. Cao , J. Yang . J. Membr. Sci. , 2014 . 469 272 .

Y.W. Zhu , S. Murali , W.W. Cai , X.S. Li , J.W. Suk , R.P. Jeffrey , S. R. Rodney . Adv. Mater. , 2010 . 22 3906 .

B. Konkena , S. Vasudevan . Langmuir. , 2012 . 28 12432 .

B. Konkena , S. Vasudevan . J. Phys. Chem. C. , 2015 . 119 6356 .

C.H. Loh , R. Wang . J. Membr. Sci. , 2013 . 446 492 .

M. Birkner , M. Ulbricht . J. Membr. Sci. , 2015 . 494 57 .

R. Yang , E. Goktekin , K. G. Karen . Langmuir. , 2015 . 31 11895 .

X.B. Duan , S. L. Randy . Biomaterial. , 2002 . 23 1197 .

Q. Shi , Y.L. Su , W.J. Chen , J.M. Peng , L.Y. Nie , L. Zhang , Z.Y. Jiang . J. Membr. Sci. , 2011 . 366 398 .

J. Wang , Y. Yao , B. Ji , W. Huang , Y.F. Zhou , D.Y. Yan . Chinese J. Polym. Sci. , 2011 . 29 ( 2 ): 241 .

A. Jayalakshmi , S. Rajesh , D. Mohan . Appl. Surf. Sci. , 2012 . 258 9770 .

J.F. Lapointe , S.E. Gauthier , Y. Pouliot , C. Bouchard . J. Membr. Sci. , 2005 . 261 36 .

K.D. Dinh , K. Euij . Nanoscale Re Lett. , 2015 . 10 6 .

C.M. Daniela , V.K. Dmitry , M.B. Jacob , S. Alexander , Z.Z. Sun , S. Alexander , B.A. Lawrence , W. Lu , M.T. James . ACS Nano. , 2010 . 8 4806 .

H.Y. Liu , J. Cheng , F.J. Chen , F.P. Hou , D.C. Bai , P.X. Xi , Z.Z. Zeng . ACS Appl. Mater. Interfaces. , 2014 . 6 3132 .

T. Kuilla , S. Bhadra , D. Yao , N.H. Kim , S. Bose , J.H. Lee . Prog. Polym. Sci. , 2010 . 35 1350 .

J. Callejas Fernández , F.J. de las Nieves , R. Martínez García , R. Hidalgo-Alvarez . Colloids Surf. , 1991 . 61 123 .

J.Y. Kong , M.C. Choi , G.Y. Kim , J.J. Park , M. Selvaraj , M. Han , C.S. Ha . Eur. Polym. J. , 2012 . 48 1394 .

O.C. Compton , D.A. Dikin , K.W. Putz , L.C. Brinson , S.T. Nguyen . Adv. Mater. , 2010 . 22 892 .

Y. Yang , T. Liu . Appl. Surf. Sci. , 2011 . 257 8950 .

V.H. Luan , H.N. Tien , S.H. Hur . J. Colloid Interface Sci. , 2015 . 6 437 .

V.H. Luan , H.N. Tien , L.T. Hoa , N.T.M. Hien , E.S. Oh , J. Chung . J. Mater. Chemistry A. , 2013 . 1 208 .

J.F. Hester , P. Banerjee , Y.Y. Won , A. Akthakul , M.H. Acar , A.M. Mayes. . Macromolecules. , 2002 . 35 7652 .

Z. Wang , H. Yu , J. Xia , F. Zhang , F. Li , Y. Xia , Y. Li . Desalination. , 2012 . 299 50 .

Q. Shi , Y.L. Su , W.J. Chen , J.M. Peng , L.Y. Nie , L. Zhang , Z.Y. Jiang . J. Membr. Sci. , 2011 . 366 398 .

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

SURFACE MODIFICATION OF PVDF POROUS MEMBRANES

Synergistic Bioinspired Interface and Segregated Graphene Oxide Networks Enabling Enhanced Mechanical Strength and Chemical Resistance in Natural Rubber Latex Composites

An Excellent Biobased Copolymerization Monomer Module: Synthesis of Biobased Copolymers with Excellent Heat Resistance and Hydrophilic Properties

End-group and Side-chain Dual-engineering of Selenium-fused Acceptors for 20.08% Efficiency Polymer Solar Cells with Low Energy Loss

Energy Storage Performance of Supercapacitors with Polyelectrolyte Surface Coatings: Effects of Dielectric Contrast

Related Author

Jian-hua Li

Jing Miao

Xi-sheng Shao

You-yi Xu

Qi-qing Zhang

Xiao-Da Pan

Yun-Kui Song

Chong-Zhi Sun

Related Institution

Institute of Biomedical and Pharmaceutical Technology & College of Chemistry and Chemical Engineering, Fuzhou University

Institute of Polymer Science, Key Laboratory of Macromolecule Synthesis and Functionalization, (Ministry of Education), Zhejiang University

School of Materials Science and Engineering, Beijing University of Chemical Technology

State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology

Hubei Key Laboratory for New Textile Materials and Applications, College of Materials Science and Engineering, Wuhan Textile University

⁰